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学者姓名：黄剑东
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Abstract ：
Photodynamic immunotherapy (PIT) has emerged as a promising approach for efficient eradication of primary tumors and inhibition of tumor metastasis. However, most of photosensitizers (PSs) for PIT exhibit notable oxygen dependence. Herein, a concept emphasizing on transition from molecular PSs into semiconductor-like photocatalysts is proposed, which converts the PSs from type II photoreaction to efficient type I photoreaction. Detailed mechanism studies reveal that the nanostructured phthalocyanine aggregate (NanoNMe) generates radical ion pairs through a photoinduced symmetry breaking charge separation process, achieving charge separation through a self-substrate approach and leading to exceptional photocatalytic charge transfer activity. Additionally, a reformed phthalocyanine aggregate (NanoNMO) is fabricated to improve the stability in physiological environments. NanoNMO showcases significant photocytotoxicities under both normoxic and hypoxic conditions and exhibits remarkable tumor targeting ability. Notably, the NanoNMO-based photodynamic therapy and PD-1 checkpoint inhibitor-based immunotherapy synergistically triggers the infiltration of cytotoxic T lymphocytes into the tumor sites of female mice, leading to the effective inhibition of breast tumor growth.
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| GB/T 7714 | Liu, Hao , Li, Ziqing , Zhang, Xiaojun et al. Phthalocyanine aggregates as semiconductor-like photocatalysts for hypoxic-tumor photodynamic immunotherapy [J]. | NATURE COMMUNICATIONS , 2025 , 16 (1) . |
| MLA | Liu, Hao et al. "Phthalocyanine aggregates as semiconductor-like photocatalysts for hypoxic-tumor photodynamic immunotherapy" . | NATURE COMMUNICATIONS 16 . 1 (2025) . |
| APA | Liu, Hao , Li, Ziqing , Zhang, Xiaojun , Xu, Yihui , Tang, Guoyan , Wang, Zhaoxin et al. Phthalocyanine aggregates as semiconductor-like photocatalysts for hypoxic-tumor photodynamic immunotherapy . | NATURE COMMUNICATIONS , 2025 , 16 (1) . |
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The weakness of visible and near-infrared light penetration depth limits the application of photodynamic therapy (PDT) in deep-seated tumors. Based on the high penetrability of X-rays, X-ray-induced PDT (X-PDT) is a promising new method for treating deep-seated tumors. However, it requires the development of suitable X-ray-induced sensitizers that could employ X-ray energy to produce reactive oxygen species (ROS) efficiently. In this study, a novel X-ray-induced sensitizer (NanoSRF) was developed through a microemulsion method, in which copper iodine cluster compound Cu2I2(tpp)2(2,5-dm-pz) (CIP) and rose bengal (RB) worked as scintillator and photosensitizer, respectively. CIP was synthesized by a simple mechanical grinding method, and subsequently folic acid (FA)-modified albumin was introduced to enable its alliance with RB. NanoSRF exhibited excellent dispersion stability and generated a large amount of ROS under X-ray irradiation. The results of in vitro studies demonstrated its high selectivity for FA receptor-positive cancer cells. Following systemic administration, NanoSRF accumulated in H22 tumors of xenograft-bearing mice, and X-ray irradiation (5.46 Gy) induced a significant inhibition rate of 96.7% in tumor growth. This study pioneers the use of copper iodide cluster as a scintillator in X-PDT, presenting new possibilities for designing scintillators with exceptional X-ray absorption and efficient X-PDT capabilities. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic). (sic)(sic)X(sic)(sic)(sic)(sic)(sic)(sic)(sic), X(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)Cu2I2(tpp)2(2,5-dm-pz) (CIP), (sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(RB)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)CIP(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)X(sic)(sic)(sic)(sic)(sic)(NanoSRF), (sic)(sic)(sic) (sic)(sic)CIP(sic)(sic)(sic)(sic), RB(sic)(sic)(sic)(sic). NanoSRF(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic) (sic)(sic)X(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)ROS. (sic)(sic)(sic)(sic)(sic)(sic), NanoSRF(sic)(sic)(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic), NanoSRF(sic)(sic)(sic)(sic)(sic)(sic)H22 (sic)(sic)(sic)(sic)(sic), (sic)X(sic)(sic)(sic)(sic)(5.46 Gy)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) 96.7%. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)X-PDT, (sic)(sic)(sic)(sic)(sic) (sic)(sic)X(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)X-PDT(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).
Keyword ：
copper iodine cluster copper iodine cluster nanoparticle nanoparticle target target tumor tumor X-ray-induced photodynamic therapy X-ray-induced photodynamic therapy
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| GB/T 7714 | Xie, Wei , Chen, Junyun , Zhang, Yuxin et al. Copper iodine cluster nanoparticles for tumor-targeted X-ray-induced photodynamic therapy [J]. | SCIENCE CHINA-MATERIALS , 2024 , 67 (10) : 3358-3367 . |
| MLA | Xie, Wei et al. "Copper iodine cluster nanoparticles for tumor-targeted X-ray-induced photodynamic therapy" . | SCIENCE CHINA-MATERIALS 67 . 10 (2024) : 3358-3367 . |
| APA | Xie, Wei , Chen, Junyun , Zhang, Yuxin , Zheng, Biyuan , Li, Xingshu , Huang, Jian-Dong . Copper iodine cluster nanoparticles for tumor-targeted X-ray-induced photodynamic therapy . | SCIENCE CHINA-MATERIALS , 2024 , 67 (10) , 3358-3367 . |
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Development of metal-organic framework (MOF) films is of great importance to expand their applications. Herein, we report a facile and universal method of liquid-phase epitaxial (LPE) layer by layer (LBL) brushing approach for fabricating MOF films on various substrates in a high-throughput fashion. This MOF films preparation method offers a great prospective to cost-effectively construct films with short preparation time and little reagent consumption. Moreover, this LBL brushing approach has been implemented successfully to assemble various MOF films, including HKUST-1, zeolitic imidazolate framework-8 (ZIF-8), Cu(bdc), and Cu2(L)2P (L = bdc, ndc, and cam; P = dabco and bipy). Afterwards, the classic MOF HKUST-1 and ZIF-8 films were grown on sensor chip electrode and porous fiber support for good volatile organic compounds (VOCs) selective sensing and water purification applications. This study demonstrates that this LBL brushing preparation method can be employed to synthesize various MOF films with a variety of characteristics to realize their sensing and separation applications.
Keyword ：
film film layer by layer fabrication layer by layer fabrication metal-organic framework metal-organic framework porous materials porous materials
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| GB/T 7714 | Chang, Li-Mei , Zhai, Rui , Ma, Zhi-Zhou et al. Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films [J]. | NANO RESEARCH , 2024 , 17 (6) : 5698-5704 . |
| MLA | Chang, Li-Mei et al. "Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films" . | NANO RESEARCH 17 . 6 (2024) : 5698-5704 . |
| APA | Chang, Li-Mei , Zhai, Rui , Ma, Zhi-Zhou , Huang, Jian-Dong , Gu, Zhi-Gang , Zhang, Jian . Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films . | NANO RESEARCH , 2024 , 17 (6) , 5698-5704 . |
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Photo-responsive synergetic therapeutics achieved significant attraction in cancer theranostic due to the versatile characteristics of nanomaterials. There have been substantial efforts in developing the simplest nano-design with exceptional synergistic properties and multifunctionalities. In this work, biocompatible Ti2C MXene nano bipyramids (MNBPs) were synthesized by hydrothermal method with dual functionalities of photothermal and photodynamic therapies. The MNBPs shape was obtained from two-dimensional (2D) Ti2C nanosheets by controlling the temperature of the reaction mixture. The structure of these Ti2C MNBPs was characterized by a high-resolution transmission electron microscope, scanning electron microscope, atomic force microscope, X-ray photoelectron spectroscopy, and X-ray diffraction. The Ti2C NBPs have shown exceptional photothermal properties with increased temperature to 72.3 degree celsius under 808 nm laser irradiation. The designed nano bipyramids demonstrated excellent cellular uptake and biocompatibility. The Ti2C NBP has established a remarkable photothermal therapy (PTT) effect against 4T1 breast cancer cells. Moreover, Ti2C NBPs showed a profound response to UV light (6 mW/cm(2)) and produced reactive oxygen species, making them useful for photodynamic therapy (PDT). These in-vitro studies pave a new path to tune the properties of photo-responsive MXene nanosheets, indicating a potential use in biomedical applications.
Keyword ：
breast cancer breast cancer Nano bipyramids Nano bipyramids photodynamic therapy photodynamic therapy Photo-responsive nanomaterials Photo-responsive nanomaterials photothermal therapy photothermal therapy Ti2C Ti2C
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| GB/T 7714 | Ali, Israt , Chang, Li-Mei , Farheen, Jabeen et al. Facile Synthesis of Novel Ti2C Nano Bipyramids for Photothermal and Photodynamic Therapy of Breast Cancer [J]. | CHEMPLUSCHEM , 2024 , 89 (5) . |
| MLA | Ali, Israt et al. "Facile Synthesis of Novel Ti2C Nano Bipyramids for Photothermal and Photodynamic Therapy of Breast Cancer" . | CHEMPLUSCHEM 89 . 5 (2024) . |
| APA | Ali, Israt , Chang, Li-Mei , Farheen, Jabeen , Huang, Jiandong , Gu, Zhi-Gang . Facile Synthesis of Novel Ti2C Nano Bipyramids for Photothermal and Photodynamic Therapy of Breast Cancer . | CHEMPLUSCHEM , 2024 , 89 (5) . |
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Coassemblies with tailored functions, such as drug loading, tissue targeting and releasing, therapeutic and/or imaging purposes, and so on, have been widely studied and applied in biomedicine. De novo design of these coassemblies hinges on an integrated approach involving synergy between various design strategies, ranging from structure screening of combinations of "phthalocyanine-chemotherapeutic drug" molecules for molecular scaffolds, exploration of related fabrication principles to verification of intended activity of specific designs. Here, we propose an integrated approach combining computation and experiments to design from scratch coassembled nanoparticles. This nanocoassembly, termed NanoPC here, consists of phthalocyanine-based scaffolds hosting chemotherapeutic drugs, aimed at hypersensitive chemotherapy guided by photoimaging for targeting tumors. Our design starts from the selection of phthalocyanine derivatives that are not aggregation-prone, followed by computational screening of coassembled molecules covering various categories of chemotherapy drugs. To facilitate an efficient and accurate assessment of coassembly capabilities, we utilize small systems as surrogates to enable free-energy calculations at all-atom levels facilitated with enhanced sampling and statistical mechanics for efficient and accurate evaluation of coassembly ability. The final top NanoPC candidate, comprised of phthalocyanine PcL and cytarabine (CYT), can greatly increase the fluorescence intensity ratio of tumor/liver by 21.5 times and achieve higher antitumor efficiency in a pH-dependent manner. Therefore, the designing approach proposed here has a potential pattern, which can provide ideas and references for the design and development of coassembled nanodrugs with tailored functions and applications in biomedicine.
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| GB/T 7714 | Li, Dong , Huang, Siyong , Ge, Jianlin et al. Molecular Design of Phthalocyanine-Based Drug Coassembly with Tailored Function [J]. | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (49) : 33461-33474 . |
| MLA | Li, Dong et al. "Molecular Design of Phthalocyanine-Based Drug Coassembly with Tailored Function" . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146 . 49 (2024) : 33461-33474 . |
| APA | Li, Dong , Huang, Siyong , Ge, Jianlin , Zhuang, Ziqi , Zheng, Longyi , Jiang, Lai et al. Molecular Design of Phthalocyanine-Based Drug Coassembly with Tailored Function . | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY , 2024 , 146 (49) , 33461-33474 . |
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The development of a simple drug formulation capable of achieving both activatable type I photoreaction and tumor-responsive release of immunomodulator is crucial for advancing photodynamic immunotherapy (PDIT). Herein, we present a nanostructured photosensitizer (NP5) that is activated by the acidic tumor microenvironment to produce type I reactive oxygen species (ROS) under light irradiation and release the immunomodulator demethylcantharidin (DMC) for PDIT. The NP5 is formed by self-assembly of a versatile phthalocyanine molecule which is composed of DMC and phthalocyanine linked via a pH-responsive amide bond. NP5 produces minimal ROS under light irradiation at the condition of pH 7.4. However, NP5 can release DMC at the condition of pH 6.5 and concurrently trigger type I photoreactions. The results of in vivo experiments indicate that NP5-mediated PDIT induce the increase of cytotoxic T lymphocytes and decrease of regulatory T lymphocytes, which can effectively inhibit the bilateral tumor growth. This work is anticipated to serve as a reference for the development of innovative agents for precise PDIT of hypoxic tumors.
Keyword ：
Activatable photosensitizer Activatable photosensitizer Demethylcantharidin Demethylcantharidin Photodynamic immunotherapy Photodynamic immunotherapy Phthalocyanine Phthalocyanine Type I Type I
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| GB/T 7714 | Zhang, Ling , Que, Rong-Bin , Ke, Ting-Ting et al. A tumor-pH-responsive phthalocyanine as activatable type I photosensitizer for improved photodynamic immunotherapy [J]. | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY , 2024 , 261 . |
| MLA | Zhang, Ling et al. "A tumor-pH-responsive phthalocyanine as activatable type I photosensitizer for improved photodynamic immunotherapy" . | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY 261 (2024) . |
| APA | Zhang, Ling , Que, Rong-Bin , Ke, Ting-Ting , Wang, Chao , Xie, Wei , Sun, Hong-Jie et al. A tumor-pH-responsive phthalocyanine as activatable type I photosensitizer for improved photodynamic immunotherapy . | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY , 2024 , 261 . |
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With a view to developing highly efficient photosensitizers for photodynamic therapy, herein, we prepared a series of tetra-substituted zinc(II) phthalocyanine analogues (ZPOP, ZPSP, ZPNP, and ZPNPM) modified with O-, S-, and N-bridging substituents, respectively. Compared to O- and S-bridging analogues, the N-bridging phthalocyanines showed eminent red-shifted Q band absorption (750-780 nm) and excellent reactive oxygen species (ROS) generation ability (Phi Delta = 0.90-0.97), due to the HOMO destabilization, as well as the smaller Delta EST. To improve the hydrophility and biocompatibility, we further prepared two N-bridging zinc(II) phthalocyanines (ZPN1 and ZPN2) modified with morpholine and N,N-dimethylamine moieties, respectively, along with their quaternized counterparts (QZPN1 and QZPN2). These compounds exhibited NIR-absorbing Q bands at 774-777 nm and efficient ROS generation ability in aqueous solutions, especially formulated with 1 % Cremophor EL (Cel). In vitro studies indicated that ZPN2 exhibited the highest photodynamic activity against HepG2 cells (IC50 = 0.44 +/- 0.02 mu M), because of superior cellular uptake and moderate ROS generation ability. Moreover, ZPN2 could selectively accumulate and retain in tumor tissue of H22 tumor-bearing mice. The work presents a new strategy for the development of NIR-absorbing photosensitizers.
Keyword ：
N -bridging phthalocyanine N -bridging phthalocyanine Near-infrared Near-infrared Photodynamic therapy Photodynamic therapy Reactive oxygen species Reactive oxygen species
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| GB/T 7714 | Ke, Mei-Rong , Wang, Chao , He, Qinxue et al. N-bridging tetra-substituted zinc(II) phthalocyanines with Q-band absorption up to 780 nm and eminent photosensitizing activities for photodynamic therapy [J]. | DYES AND PIGMENTS , 2024 , 227 . |
| MLA | Ke, Mei-Rong et al. "N-bridging tetra-substituted zinc(II) phthalocyanines with Q-band absorption up to 780 nm and eminent photosensitizing activities for photodynamic therapy" . | DYES AND PIGMENTS 227 (2024) . |
| APA | Ke, Mei-Rong , Wang, Chao , He, Qinxue , Que, Rongbin , Wei, Ying , Zheng, Bi-Yuan et al. N-bridging tetra-substituted zinc(II) phthalocyanines with Q-band absorption up to 780 nm and eminent photosensitizing activities for photodynamic therapy . | DYES AND PIGMENTS , 2024 , 227 . |
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Phthalocyanines (Pcs) are considered promising in cancer phototherapy. However, their maximum absorption wavelengths are only around 700 nm, which cannot allow deep tissue penetration and leads to poor therapeutic efficacy. To expand their clinical application, significantly shifting their absorption to longer wavelengths is urgently required. Dye J-aggregates exhibit a redshifted absorption relative to its monomer. However, Pc Jaggregates with enormous-redshifted and intense absorption is rarely reported, and little is known about the relationships between Pc structure and J-aggregation. Herein, such Pc J-aggregates are ingeniously conceived. With a yeast beta-D-glucan-ursodeoxycholic acid conjugate as a potential tumor-associated macrophages (TAMs)targeting carrier and 1-(4-carboxyethylphenoxy) zinc (II) phthalocyanine (Pc1) as a model, Pc1 J-aggregate nanoparticle (NanoPc1) is obtained via ultrasonication-aided emulsification-solvent evaporation technique. NanoPc1 displays strong absorption at 830 nm, with a 156 nm redshift. Further investigation on another twentyfour Pcs demonstrates that unsubstituted zinc (II) or magnesium (II) Pc and hydrophobic mono-substituted zinc (II) or magnesium (II) Pcs with mono-substituted phenoxy or phenylthio or naphthoxy as a substituent can readily form desired Pc J-aggregates with significant redshifts (140-165 nm). The other Pcs fail to form expected J-aggregates probably due to absence of central metals, steric hindrance on central metals (atoms), forming axial coordination on central metals, disorder tendency during self-assembly or hydrophilicity. The theoretical calculation indicates that Pc1 in its J-aggregates exhibits a spiral-like arrangement, and the reduction in the energy gap between HOMO and LUMO and variation of intermolecular it-it interaction caused by J-aggregate formation are responsible for the huge redshift. Additionally, using NanoPc1 as an exemplar, such Pc J-aggregate nanoparticles are substantiated to afford TAMs-targeted and efficient tri-modal imaging and photothermal therapy in a H22 mouse model.
Keyword ：
J -aggregate J -aggregate Large redshift Large redshift Multimodal phototheranostics Multimodal phototheranostics Phthalocyanine Phthalocyanine Yeast glucan Yeast glucan
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| GB/T 7714 | Tang, Fengxiang , Yu, Haodong , Huang, Yanzong et al. Phthalocyanine J-aggregate nanoparticles with enormous-redshifted and intense absorption: Potential structure-J-aggregation relationships and application in tumor-associated macrophages-targeted phototheranostics [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 496 . |
| MLA | Tang, Fengxiang et al. "Phthalocyanine J-aggregate nanoparticles with enormous-redshifted and intense absorption: Potential structure-J-aggregation relationships and application in tumor-associated macrophages-targeted phototheranostics" . | CHEMICAL ENGINEERING JOURNAL 496 (2024) . |
| APA | Tang, Fengxiang , Yu, Haodong , Huang, Yanzong , Zhao, Xue , Chen, Zixuan , Ma, Honglin et al. Phthalocyanine J-aggregate nanoparticles with enormous-redshifted and intense absorption: Potential structure-J-aggregation relationships and application in tumor-associated macrophages-targeted phototheranostics . | CHEMICAL ENGINEERING JOURNAL , 2024 , 496 . |
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Development of metal-organic framework(MOF)films is of great importance to expand their applications.Herein,we report a facile and universal method of liquid-phase epitaxial(LPE)layer by layer(LBL)brushing approach for fabricating MOF films on various substrates in a high-throughput fashion.This MOF films preparation method offers a great prospective to cost-effectively construct films with short preparation time and little reagent consumption.Moreover,this LBL brushing approach has been implemented successfully to assemble various MOF films,including HKUST-1,zeolitic imidazolate framework-8(ZIF-8),Cu(bdc),and Cu2(L)2P(L=bdc,ndc,and cam;P=dabco and bipy).Afterwards,the classic MOF HKUST-1 and ZIF-8 films were grown on sensor chip electrode and porous fiber support for good volatile organic compounds(VOCs)selective sensing and water purification applications.This study demonstrates that this LBL brushing preparation method can be employed to synthesize various MOF films with a variety of characteristics to realize their sensing and separation applications.
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| GB/T 7714 | Li-Mei Chang , Rui Zhai , Zhi-Zhou Ma et al. Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films [J]. | 纳米研究（英文版） , 2024 , 17 (6) : 5698-5704 . |
| MLA | Li-Mei Chang et al. "Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films" . | 纳米研究（英文版） 17 . 6 (2024) : 5698-5704 . |
| APA | Li-Mei Chang , Rui Zhai , Zhi-Zhou Ma , Jian-Dong Huang , Zhi-Gang Gu , Jian Zhang . Liquid-phase epitaxial layer by layer brushing fabrication of metal-organic frameworks films . | 纳米研究（英文版） , 2024 , 17 (6) , 5698-5704 . |
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Only rarely have polyoxometalates been found to form core-shell nanoclusters. Here, we succeeded in isolating a series of rare giant and all-inorganic core-shell cobalt polyoxoniobates (Co-PONbs) with diverse shapes, nuclearities and original topologies, including 50-nuclearity {Co12Nb38O132}, 54-nuclearity {Co20Nb34O128}, 62-nuclearity {Co26Nb36O140} and 87-nuclearity {Co33Nb54O188}. They are the largest Co-PONbs and also the polyoxometalates containing the greatest number of Co ions and the largest cobalt clusters known thus far. These molecular Co-PONbs have intriguing and atomically precise core-shell architectures comprising unique cobalt oxide cores and niobate oxide shells. In particular, the encapsulated cobalt oxide cores with different nuclearities have identical compositions, structures and mixed-valence Co3+/Co2+ states as the different sized Co-O moieties of the bulk cubic-spinel Co3O4, suggesting that they can serve as various molecular models of the cubic-spinel Co3O4. The successful construction of the series of the Co-PONbs reveals a feasible and versatile synthetic method for making rare core-shell heterometallic PONbs. Further, these new-type core-shell bimetal species are promising cluster molecular catalysts for visible-light-driven CO2 reduction.
Keyword ：
CO2 Reduction CO2 Reduction Cobalt Cobalt Core-Shell Core-Shell High-Nuclearity High-Nuclearity Polyoxoniobate Polyoxoniobate
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| GB/T 7714 | Guo, Zheng-Wei , Lin, Ling-Hui , Ye, Jian-Ping et al. Core-Shell-Type All-Inorganic Heterometallic Nanoclusters: Record High-Nuclearity Cobalt Polyoxoniobates for Visible-Light-Driven Photocatalytic CO2 Reduction [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2023 , 62 (26) . |
| MLA | Guo, Zheng-Wei et al. "Core-Shell-Type All-Inorganic Heterometallic Nanoclusters: Record High-Nuclearity Cobalt Polyoxoniobates for Visible-Light-Driven Photocatalytic CO2 Reduction" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 62 . 26 (2023) . |
| APA | Guo, Zheng-Wei , Lin, Ling-Hui , Ye, Jian-Ping , Chen, Yi , Li, Xin-Xiong , Lin, Sen et al. Core-Shell-Type All-Inorganic Heterometallic Nanoclusters: Record High-Nuclearity Cobalt Polyoxoniobates for Visible-Light-Driven Photocatalytic CO2 Reduction . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2023 , 62 (26) . |
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