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学者姓名：林华香
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Abstract ：
H2 and O2 evolutions occur simultaneously for conventional particulate photocatalytic overall water splitting (PPOWS), leading to a significant backward reaction and the formation of an explosive H2/O2 gas mixture. This is an issue that must be addressed prior to industrialization of PPOWS. Here, a convenient, cost-effective, and scalable concept is introduced to uncouple hydrogen and oxygen production for PPOWS. Based on this idea, a three-component photocatalyst, Co(5 %)-HPCN/(rGO/Pt), is constructed, consisting of a photoresponsive chip (HPCN), a H2 evolution cocatalyst (rGO/Pt), and a cobalt complex capable of reversibly binding O2 (Co), to achieve the decoupling of PPOWS under alternating UV and visible light irradiations. The asynchronous O2 and H2 evolution strategy have considerable flexibility regarding the photocatalyst structure and light sources suitable for PPOWS.
Keyword ：
carbon nitride chips carbon nitride chips overall water splitting overall water splitting photocatalytic photocatalytic PPOWS decoupling PPOWS decoupling reaction mechanism reaction mechanism
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| GB/T 7714 | Liu, Dan , Xu, Huihui , Shen, Jinni et al. Decoupling H2 and O2 Release in Particulate Photocatalytic Overall Water Splitting Using a Reversible O2 Binder [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 , 64 (9) . |
| MLA | Liu, Dan et al. "Decoupling H2 and O2 Release in Particulate Photocatalytic Overall Water Splitting Using a Reversible O2 Binder" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 64 . 9 (2025) . |
| APA | Liu, Dan , Xu, Huihui , Shen, Jinni , Wang, Xun , Qiu, Chengwei , Lin, Huaxiang et al. Decoupling H2 and O2 Release in Particulate Photocatalytic Overall Water Splitting Using a Reversible O2 Binder . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 , 64 (9) . |
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A 2D Mn-based MOF ([Mn4(PDI)2(DMF)7(H2O)]n (MOF 1)) (H4PDI = 5,5 '-(1,3,6,8-tetraoxo-1,3,6,8-tetrahydrobenzo[lmn][3,8]phenanthroline-2,7-diyl)diisophthalic acid) was synthesized. Visible light excited Mn-PDI unit in MOF 1 oxidizes NaSO2CF3 to generate center dot CF3 radical and enables MOF 1 to exhibit activity for trifluoromethylation of (hetero)arenes under visible light. The unusual stability of MOF 1 in the trifluoromethylation reactions can be attributed to its unique structure, which prevents it from corrosion by acid byproduct. The peeling of MOF 1 to ultrathin nanosheets or partial oxidation of Mn(II) to Mn(III) in MOF 1 led to MOL 1 and NB 1 with significant improved activity for trifluoromethylation reactions, demonstrating the important role of composition and morphology of a catalyst on its performance. The light initiated trifluoromethylation reactions over these Mn-based MOFs was applied to a variety of substrates. This study provides an efficient strategy for synthesis of trifluoromethylated compounds and highlights the potential of MOFs in light initiated organic syntheses.
Keyword ：
Acid tolerance Acid tolerance CF 3 radicals CF 3 radicals Mn-based MOF Mn-based MOF Photocatalysis Photocatalysis Trifluoromethylation Trifluoromethylation
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| GB/T 7714 | Ma, Xiong-Feng , Wen, Bo , Zhang, Shaohui et al. Stable Mn(II) metal-organic framework for efficient visible light initiated trifluoromethylation reaction [J]. | JOURNAL OF CATALYSIS , 2024 , 436 . |
| MLA | Ma, Xiong-Feng et al. "Stable Mn(II) metal-organic framework for efficient visible light initiated trifluoromethylation reaction" . | JOURNAL OF CATALYSIS 436 (2024) . |
| APA | Ma, Xiong-Feng , Wen, Bo , Zhang, Shaohui , Wang, Deshun , Wang, Lele , Lin, Huaxiang et al. Stable Mn(II) metal-organic framework for efficient visible light initiated trifluoromethylation reaction . | JOURNAL OF CATALYSIS , 2024 , 436 . |
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The serious combination of abundant electrons/holes in bulk primarily hinders the efficiency in the photocatalytic reaction. It is crucial to control the spatial charge dynamics through delicately designing the crystal configuration of photocatalyst. In this work, a modified tungsten trioxide nanosheet colloid (M-WO3) was synthesized by an ion exchange method. Compared to pristine WO3 (P-WO3), the crystal lattice vibration frequency of M-WO3 increases from 2.8 meV to 4.3 meV, which effectively prohibits electron-phonon coupling and powerfully accelerates the separation and transfer of photoinduced charge carriers. Irradiated by visible-light, M-WO3 shows much higher photocatalytic bacterial inactivation performance than P-WO3. In addition, this regulation method increases the surface charges of the WO3 colloid to improve its stability, which endows this colloid photocatalyst with broad prospects in practical photocatalytic antibacterial applications. This work offers guidance to construct efficiently separated photoinduced electron/hole pairs of the colloid photocatalyst by designing its crystal structure.
Keyword ：
Colloid photocatalyst Colloid photocatalyst Colloid stability Colloid stability Crystal lattice vibration frequency Crystal lattice vibration frequency Photocatalytic disinfection Photocatalytic disinfection WO(6)octahedra distortion WO(6)octahedra distortion
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| GB/T 7714 | Qiu, Chengwei , Liu, Zhihua , Rao, Qin et al. Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity [J]. | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 678 : 1135-1147 . |
| MLA | Qiu, Chengwei et al. "Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity" . | JOURNAL OF COLLOID AND INTERFACE SCIENCE 678 (2024) : 1135-1147 . |
| APA | Qiu, Chengwei , Liu, Zhihua , Rao, Qin , Yang, Hui , He, Yuxin , Li, Dongmiao et al. Prohibiting the electron-phonon coupling effect in tungsten trioxide nanosheet colloid with enhanced photocatalytic antibacterial capacity . | JOURNAL OF COLLOID AND INTERFACE SCIENCE , 2024 , 678 , 1135-1147 . |
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Photothermal catalytic N-acetylation of aniline has been a promising strategy to synthesize amides, which combined the advantages of thermal catalysis and photocatalysis. Herein, we demonstrate a high-performance strategy to synthesize amides catalyzed by the in-situ formed first-row transition-metal (Fe, Co, Ni, Mn et al.) complexes nanodots (TMC NDs) under solar light excitation without using noble metals or strong acids. The dualfunctional nitriles substrates acted as the ligands to coordinate with transition-metal salts affording photosensitive TMC NDs with high solar-to-thermal energy conversion efficiency. Intramolecular charge transitions reduced the energy barrier of nitriles activation by weakening C---N bond and triggered near-field temperature rise via the electron-phonon scattering non-radiative pathway. The reaction system exhibited good tolerance to different functional groups, affording a series of amide derivatives. Such a dynamic coordination reaction mode and the in-situ formed TMC NDs opens new avenues toward solar-heat conversion via photon-phonon coupling in the field of chemical synthesis.
Keyword ：
Amide synthesis Amide synthesis N-acyl sources N-acyl sources Photon -phonon coupling Photon -phonon coupling Photothermal catalysis Photothermal catalysis Transition-metal complexes nanodots Transition-metal complexes nanodots
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| GB/T 7714 | Ma, Xiong-Feng , Xiao, Rui , Wei, Yingcong et al. Photothermal catalytic conversion of water and inert nitriles to amide activated by in-situ formed transition-metal-complex nanodots [J]. | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2024 , 344 . |
| MLA | Ma, Xiong-Feng et al. "Photothermal catalytic conversion of water and inert nitriles to amide activated by in-situ formed transition-metal-complex nanodots" . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY 344 (2024) . |
| APA | Ma, Xiong-Feng , Xiao, Rui , Wei, Yingcong , Zhang, Shaohui , Hu, Xiaoyi , Zhang, Ling et al. Photothermal catalytic conversion of water and inert nitriles to amide activated by in-situ formed transition-metal-complex nanodots . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2024 , 344 . |
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A AgBr-Ag2MoO4 heterojunction with high inactivation of E. coli under visible-light illumination was constructed. The crystal structure, morphology, elemental composition, and optical properties were characterized by TEM, SEM, XRD, XPS and DRS. The photocatalytic inactivation of E. coli by AgBr, Ag2MoO4, and AgBr-Ag2MoO4 was investigated. The results indicate that AgBr-Ag2MoO4 shows the best disinfection activity compared to AgBr and Ag2MoO4, with the E. coli being almost completely inactivated after illumination for 80 min. In addition, the cell structure of the bacteria is destroyed after visible-light irradiation in the presence of the catalyst. The UV absorption detection confirms that the bacterial protein leak and the concentration of nucleic acid in the solution also increase with the increase of the reaction time, indicating that the integrity of the bacterial cell membrane is damaged. The detection of ROS scavengers indicates that the reactive species (h(+), OH, e(-) and O-2(-)) play an important role in the inactivation of bacteria. The EPR tests confirm that the amount of OH is higher than that of O-2(-) during the illumination process, which is consistent with the results of the free-radical capture tests. The heterojunction of AgBr-Ag2MoO4 is beneficial for the separation of photogenerated electrons and holes during the illumination process, resulting in an improvement of the antibacterial properties.
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| GB/T 7714 | Rao, Qin , Xian, Xiao , Lin, Huaxiang et al. Construction of a AgBr-Ag2MoO4 heterojunction and its photocatalytic sterilization activity [J]. | NEW JOURNAL OF CHEMISTRY , 2023 , 47 (32) : 15151-15161 . |
| MLA | Rao, Qin et al. "Construction of a AgBr-Ag2MoO4 heterojunction and its photocatalytic sterilization activity" . | NEW JOURNAL OF CHEMISTRY 47 . 32 (2023) : 15151-15161 . |
| APA | Rao, Qin , Xian, Xiao , Lin, Huaxiang , Yuan, Rusheng , Zhang, Zizhong , Long, Jinlin et al. Construction of a AgBr-Ag2MoO4 heterojunction and its photocatalytic sterilization activity . | NEW JOURNAL OF CHEMISTRY , 2023 , 47 (32) , 15151-15161 . |
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In a novel approach that capitalized on the differential solubility product (K-sp) of ZnSe and Ag2Se, a unique ZnSe/Ag2Se binary heterostructure was efficiently synthesized in situ. ZnSe/Ag2Se exhibited excellent antimicrobial efficiency under visible light. Incorporating Ag2Se into ZnSe significantly enhanced the photoelectric performance of the catalyst, greatly accelerating the separation of the photogenerated electrons in the system. Active species removal experiments determined that O-2(-) and H2O2 played crucial roles in photocatalytic antibacterial efficiency. Further investigation into the levels of cellular membrane peroxidation, bacterial morphology, and intracellular contents concentration revealed that during the photocatalytic antimicrobial process, reactive oxygen species initially oxidize phospholipids in the cell membrane, leading to damage to the external structure of the cell and leakage of the intracellular contents, ultimately resulting in bacteria inactivation. The photocatalytic antimicrobial process of ZnSe/Ag2Se fundamentally deviates from conventional methods, offering new insights into efficient disinfection and photocatalytic antimicrobial mechanisms.
Keyword ：
antibacterial mechanism antibacterial mechanism binary heterojunction binary heterojunction photocatalysis photocatalysis photocatalytic disinfection photocatalytic disinfection ZnSe ZnSe
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| GB/T 7714 | Wang, Qian , Wang, Qin , Yuan, Rusheng et al. Facile Preparation of the ZnSe/Ag2Se Binary Heterojunction for Photocatalytic Antibacterial Efficiency [J]. | ACS APPLIED MATERIALS & INTERFACES , 2023 , 15 (43) : 50155-50165 . |
| MLA | Wang, Qian et al. "Facile Preparation of the ZnSe/Ag2Se Binary Heterojunction for Photocatalytic Antibacterial Efficiency" . | ACS APPLIED MATERIALS & INTERFACES 15 . 43 (2023) : 50155-50165 . |
| APA | Wang, Qian , Wang, Qin , Yuan, Rusheng , Zhang, Zizhong , Long, Jinlin , Lin, Huaxiang . Facile Preparation of the ZnSe/Ag2Se Binary Heterojunction for Photocatalytic Antibacterial Efficiency . | ACS APPLIED MATERIALS & INTERFACES , 2023 , 15 (43) , 50155-50165 . |
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本发明公开了一种具有海胆球形貌的复合光催化剂材料及其制备方法和应用，该复合光催化剂是通过在乙醇热过程中，W18O49材料在2H/3C‑SiC纳米球表面生长从而得到具有海胆球形貌的SiC‑W18O49复合材料。该复合光催化剂制备原料价廉易得，制备方案便捷可行，并且与单一组分的W18O49材料和2H/3C‑SiC材料相比，光催化还原二氧化碳性能显著增强。
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| GB/T 7714 | 张子重 , 柳勇志 , 王绪绪 et al. 一种具有海胆球形貌的复合光催化剂材料及其制备方法和应用 : CN202210788518.0[P]. | 2022-07-06 00:00:00 . |
| MLA | 张子重 et al. "一种具有海胆球形貌的复合光催化剂材料及其制备方法和应用" : CN202210788518.0. | 2022-07-06 00:00:00 . |
| APA | 张子重 , 柳勇志 , 王绪绪 , 龙金林 , 林华香 , 沈锦妮 et al. 一种具有海胆球形貌的复合光催化剂材料及其制备方法和应用 : CN202210788518.0. | 2022-07-06 00:00:00 . |
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本发明公开了一种含稀土元素的硫化物光催化剂及其制备方法和应用，采用简单的水热法或溶剂热法制备含稀土元素的硫化物催化剂，并将其应用于光催化CO2还原体系中。本发明的制备方法简单易行、温和低能耗。制得的催化剂具有显著提高光催化CO2还原性能，且产物选择性高的优点，在光催化领域具有较广泛的应用前景，同时也为新型光催化剂的制备提供了新的思路。
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| GB/T 7714 | 丁正新 , 王文静 , 何春娴 et al. 一种含稀土元素的硫化物光催化剂及其制备方法和应用 : CN202210039689.3[P]. | 2022-01-14 00:00:00 . |
| MLA | 丁正新 et al. "一种含稀土元素的硫化物光催化剂及其制备方法和应用" : CN202210039689.3. | 2022-01-14 00:00:00 . |
| APA | 丁正新 , 王文静 , 何春娴 , 魏芬 , 韩世同 , 龙金林 et al. 一种含稀土元素的硫化物光催化剂及其制备方法和应用 : CN202210039689.3. | 2022-01-14 00:00:00 . |
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Iodine(i) doped ZnO nanoarray films (ZnO/I-X) were prepared on a silicon wafer by the in situ growth method. The structure and morphology of the samples were tested by XRD, SEM, DRS. The hydrophobic properties were characterized by the water contact angle on the surface. The results show that the doped iodine extended the light absorption range of the ZnO nanofilm and the nanoarray film (ZnO/I-X) are super hydrophobic. The antimicrobial activity of iodine(i)-doped ZnO nanofilms towards E. coli under visible light illumination is much higher than that of the ZnO film. In addition, ZnO/I-3 exhibits the best antimicrobial activity.
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| GB/T 7714 | Xiao, Yingxin , Han, Shitong , Xi, Hailing et al. Super-hydrophobic and photocatalytic antimicrobial activity of iodine-doped ZnO nanoarray films [J]. | NEW JOURNAL OF CHEMISTRY , 2022 , 46 (7) : 3140-3145 . |
| MLA | Xiao, Yingxin et al. "Super-hydrophobic and photocatalytic antimicrobial activity of iodine-doped ZnO nanoarray films" . | NEW JOURNAL OF CHEMISTRY 46 . 7 (2022) : 3140-3145 . |
| APA | Xiao, Yingxin , Han, Shitong , Xi, Hailing , Jin, Yubo , Lin, Huaxiang , Yuan, Rusheng et al. Super-hydrophobic and photocatalytic antimicrobial activity of iodine-doped ZnO nanoarray films . | NEW JOURNAL OF CHEMISTRY , 2022 , 46 (7) , 3140-3145 . |
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Tailoring the surficial chemical environment of two-dimensional materials by organic modification is an effective way to optimize their catalytic behaviors. Herein, we present a dynamic coordination approach to improve the photocatalytic performance of ultrathin Co2CO3(OH)(2) nanosheets (u-CoCH) in NIR light (lambda > 780 nm) driven carbonylation reaction by using the reacting substrates (diamines) as the ligands. The coordination of diamines with surface Co2+ ions form a binuclear complex at the crystallographic planes of u-CoCH. The as-formed complexes can reduce the energy barrier of carbonylation reaction by weaking the N-H bond of the substrate on u-CoCH, and afford enhanced light response as well as the prolonged photogenerated electron lifetime. Together with the successful synthesis of a series of important structural motifs in pharmaceuticals and bioactive agents, the promoted photosynthesis reaction mode via in-situ formed surface complexes offers a model toward full-spectrum-solar-energy conversion in the field of chemical synthesis.
Keyword ：
Binuclear complex Binuclear complex Carbonylation Carbonylation NIR light excitation NIR light excitation Photocatalysis Photocatalysis Ultrathin Co2CO3(OH)(2) nanosheets Ultrathin Co2CO3(OH)(2) nanosheets
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| GB/T 7714 | Wei, Yingcong , Zha, Wenying , Wang, Lele et al. In-situ Formed Surface Complexes Promoting NIR-Light-Driven Carbonylation of Diamine with CO on Ultrathin Co2CO3(OH)(2) Nanosheets [J]. | APPLIED CATALYSIS B-ENVIRONMENTAL , 2022 , 306 . |
| MLA | Wei, Yingcong et al. "In-situ Formed Surface Complexes Promoting NIR-Light-Driven Carbonylation of Diamine with CO on Ultrathin Co2CO3(OH)(2) Nanosheets" . | APPLIED CATALYSIS B-ENVIRONMENTAL 306 (2022) . |
| APA | Wei, Yingcong , Zha, Wenying , Wang, Lele , Ma, Xiongfeng , Zhang, Shaohui , Sa, Rongjian et al. In-situ Formed Surface Complexes Promoting NIR-Light-Driven Carbonylation of Diamine with CO on Ultrathin Co2CO3(OH)(2) Nanosheets . | APPLIED CATALYSIS B-ENVIRONMENTAL , 2022 , 306 . |
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