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学者姓名：肖龙强
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Abstract ：
Diffusion dialysis (DD) presents a highly promising and cost-efficient approach for acid recovery, yet its performance is often hindered by the acid permeability of anion exchange membranes (AEMs). To address this challenge, a one-step approach has been developed to fabricate porous AEMs. Using brominated polyphenylene oxide (BPPO) as the porous base membrane, imidazole is employed for in-situ crosslinking and cationization. This approach not only retains the inherent porosity (>63.5 %) of the base membrane but also achieves an exceptionally thin selective layer (<0.3 mu m), thereby creating abundant free space volume. Through a concurrent enhancement of ion transport sites and crosslinking density, the membrane effectively breaks acid permeability-selectivity trade-off. The optimal IPPO-20h AEM demonstrates a remarkable increase in both the acid dialysis coefficient (U-H+ = 34.1 x 10(-3) m/h) and separation factor (S-H+/(Fe)2+ = 573.8) in the HCl/FeCl2 system, with enhancements of 4- and 31-fold, respectively, compared to the commercial DF120 AEM, at 25 degrees C. This high-performance AEM, synthesized via a straightforward and mild process, offers significant potential for large-scale acid recovery applications.
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| GB/T 7714 | Shao, Haiyang , Tan, Zhengke , Cheng, Yafei et al. One-step fabrication of porous anion exchange membranes for acid recovery breaking acid permeability-selectivity trade-off [J]. | JOURNAL OF MEMBRANE SCIENCE , 2025 , 723 . |
| MLA | Shao, Haiyang et al. "One-step fabrication of porous anion exchange membranes for acid recovery breaking acid permeability-selectivity trade-off" . | JOURNAL OF MEMBRANE SCIENCE 723 (2025) . |
| APA | Shao, Haiyang , Tan, Zhengke , Cheng, Yafei , Yue, Xiang'an , Yuan, Lei , Jian, Weixiong et al. One-step fabrication of porous anion exchange membranes for acid recovery breaking acid permeability-selectivity trade-off . | JOURNAL OF MEMBRANE SCIENCE , 2025 , 723 . |
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Herein, we present the synthesis and characterization of a novel phosphorus-containing epoxy co-curing agent, ANVD, fabricated via a one-pot method utilizing vanillin, 1,5-diaminonaphthalene, and DOPO as raw materials. Structural analysis conducted through FTIR and NMR spectroscopy confirmed the composition of ANVD. Differential scanning calorimetry (DSC) results indicated ANVD has significant contribution to the curing crosslinking of DGEBA, resulting in a slightly decreased Tg value for EP/ANVD compared to EP/DOPO, albeit still notably higher. Thermogravimetric analysis (TGA) revealed a reduction in the T5% and Tmax values of EP/ANVD, yet ANVD's superior char-forming ability increased char residue mass at elevated temperatures. Combustion tests showcased the outstanding flame retardancy of EP/ANVD, with EP/ANVD-5 exhibiting a limiting oxygen index (LOI) value of 33.2 % and achieving a V-0 rating in the UL-94 test. Furthermore, EP/ANVD-5 displayed a notable decrease of 38.6 % and 32.1 % in pHRR and av-HRR, respectively, compared to pure EP, surpassing EP/DOPO with equivalent phosphorus content. Analysis of decomposition products in both condensed and gas phases revealed ANVD's role in forming dense and continuous expanded char layers during combustion, releasing phosphorus radicals and non-combustible gases, thus exhibiting dual-phase flame retardant effects. Additionally, EP/ANVD-3 exhibited enhanced mechanical properties, with tensile strength and modulus increasing from 68.5 MPa and 0.75 GPa to 76.5 MPa and 0.86 GPa, respectively, compared to pure EP. Overall, the introduction of the bio-based flame retardant ANVD presents promising opportunities for the utilization of bio-based materials in flame retardancy applications.
Keyword ：
Co-curing agent Co-curing agent Epoxy resin Epoxy resin Flame retardancy Flame retardancy Phosphaphenanthrene Phosphaphenanthrene Vanillin Vanillin
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| GB/T 7714 | Luo, Yang , Huang, Lewen , Cai, Jingyu et al. Vanillin-derived co-curing agent for enhanced flame retardancy and mechanical properties in epoxy resin [J]. | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY , 2025 , 143 : 691-703 . |
| MLA | Luo, Yang et al. "Vanillin-derived co-curing agent for enhanced flame retardancy and mechanical properties in epoxy resin" . | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 143 (2025) : 691-703 . |
| APA | Luo, Yang , Huang, Lewen , Cai, Jingyu , Jiang, Qing , Liao, Xiafeng , Zhang, Haowen et al. Vanillin-derived co-curing agent for enhanced flame retardancy and mechanical properties in epoxy resin . | JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY , 2025 , 143 , 691-703 . |
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Oil/water separation of emulsion stands as one of the most arduous and challenging aspects in oily wastewater treatment which represents a perennial trouble for humanity. Herein, positively charged hydrophobic polymer foams (PCHPFs) were fabricated by water-in-oil (W/O) high internal phase emulsion (HIPE) polymerization followed by quaternization, employing 4-vinylbenzyl chloride (VBC) and 4-tert-butylstyrene (tBS) as the comonomers. The quaternization degree of PCHPFs which can be adjusted by varying the VBC/tBS ratio has an important influence on the emulsion separation performance based on the charge demulsification mechanism. The porous morphologies of PCHPFs were revealed by SEM. The successful fabrication of PCHPFs was confirmed by FTIR and XPS. As VBC/tBS ratio increased from 0.5:1-5:1, the emulsion separation efficiency of PCHPFs first increased to a maximum of 95.9 % at 2:1 and then decreased. Additionally, the PCHPFs demonstrated robust hydrophobicity (water contact angles > 143 degrees), exceptional oil-water selectivity, remarkable oil-water separation capability, coupled with a certain absorption capacity for various oils and organic solvents (5-14 g/g). Given these advantages, PCHPFs are anticipated to emerge as an ideal solution for emulsion separation. Most importantly, the methodology for generating PCHPFs via quaternization in this research offers an innovative avenue in the design of charge demulsification materials.
Keyword ：
Charge demulsification Charge demulsification Emulsion separation Emulsion separation High internal phase emulsion High internal phase emulsion Positively charged hydrophobic polymer foams Positively charged hydrophobic polymer foams Quaternization Quaternization
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| GB/T 7714 | Xue, Jiahao , Zhao, Yulai , Cai, Jingyu et al. Positively charged hydrophobic polymer foams via high internal phase emulsion polymerization followed by quaternization for effective oil-in-water emulsion separation [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (2) . |
| MLA | Xue, Jiahao et al. "Positively charged hydrophobic polymer foams via high internal phase emulsion polymerization followed by quaternization for effective oil-in-water emulsion separation" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 13 . 2 (2025) . |
| APA | Xue, Jiahao , Zhao, Yulai , Cai, Jingyu , Lu, Zhen , Xiao, Longqiang , Hou, Linxi . Positively charged hydrophobic polymer foams via high internal phase emulsion polymerization followed by quaternization for effective oil-in-water emulsion separation . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2025 , 13 (2) . |
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Rosin, a renewable and abundant resource, has been extensively processed and chemically modified to endow it with special properties, especially in the surfactant industry. In this study, four rosin-based quaternary ammonium asymmetric gemini surfactants (RGS-2-n) with different alkyl chain lengths (n = 12, 14, 16, 18) were synthesized using a simple two-step method based on dehydroabietylamine as the raw material. The feasibility of these surfactants for cleaning purposes was comprehensively evaluated, suggesting that the surfactants own high surface activity and good cleaning performance. Furthermore, by successfully introducing the amine group of dehydroabietylamine into the hydrophilic group of the surfactants, we avoided its potential harm to the environment and water pollution. Density functional theory proves rosin-based gemini surfactants with asymmetric structure can further improve cleaning efficiency. Overall, our findings suggests that RGS-2-n surfactants are promising and sustainable candidates for cleaning electric plates, and provide new opportunities for rosin application in the electric industry. © 2024 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd
Keyword ：
Asymmetric gemini surfactants Asymmetric gemini surfactants Cleaning performance Cleaning performance Electronic components Electronic components Rosin Rosin
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| GB/T 7714 | Feng, H. , Pan, Y. , Zhang, Y. et al. Surface activity and cleaning performance of rosin-based quaternary ammonium salt type asymmetric Gemini surfactants [J]. | Chinese Journal of Chemical Engineering , 2024 , 73 : 70-80 . |
| MLA | Feng, H. et al. "Surface activity and cleaning performance of rosin-based quaternary ammonium salt type asymmetric Gemini surfactants" . | Chinese Journal of Chemical Engineering 73 (2024) : 70-80 . |
| APA | Feng, H. , Pan, Y. , Zhang, Y. , Zhang, Z. , Huang, Y. , Hou, L. et al. Surface activity and cleaning performance of rosin-based quaternary ammonium salt type asymmetric Gemini surfactants . | Chinese Journal of Chemical Engineering , 2024 , 73 , 70-80 . |
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UV-curing low dielectric materials exhibit wide applications in the field of additive manufacturing of electronic packaging, owing to their environmental protection, good thermal stability, low dielectric constant (D-k), and dielectric loss (D-f). Wherein, one-step UV curing realizes process simplification of low dielectric materials gradually sparked widespread research. In this work, a series of novel naphthalene-based low dielectric materials were prepared for one-step UV curing. The double bond conversion rate of resins exceeds 90 % in a short time and the resins perform exceptional dielectric properties (D-k < 2.8, D-f < 0.009, 110 MHz), high thermal stability (T-5% > 270 degrees C), and hydrophobicity (water contact angle > 95 degrees). Notably, 1,6-naphthalene dimethacrylate/Trihydroxymethylbutyl trimethylacrylate (1,6-NEA/TMPTA) suggests lowest dielectric performance (D-k = 2.19, D-f = 0.005) with significant thermal stability (T-g = 190 degrees C, T-5% = 367.4 degrees C) because the pi-pi conjugation of the asymmetric structure of 1,6-NEA, which allows for a greater variety of stacking patterns and increases the effective collisions between the reactive sites of the photosensitive monomer and the reactive diluent. This work has revealed the structure-activity relationship between the substituents on naphthalene derivatives and their photochemical properties, providing a novel methodology for the development of low dielectric electronic packaging materials through additive manufacturing techniques.
Keyword ：
Dielectric properties Dielectric properties Electronic packaging materials Electronic packaging materials Naphthyl isomer Naphthyl isomer UV-curing UV-curing
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| GB/T 7714 | Lian, Zehan , Lu, Zhen , Zhao, Rui et al. New type of UV cured low dielectric naphthalene resin: Structure-activity relationship of different substitution sites [J]. | PROGRESS IN ORGANIC COATINGS , 2024 , 194 . |
| MLA | Lian, Zehan et al. "New type of UV cured low dielectric naphthalene resin: Structure-activity relationship of different substitution sites" . | PROGRESS IN ORGANIC COATINGS 194 (2024) . |
| APA | Lian, Zehan , Lu, Zhen , Zhao, Rui , Xiao, Longqiang , Hou, Linxi . New type of UV cured low dielectric naphthalene resin: Structure-activity relationship of different substitution sites . | PROGRESS IN ORGANIC COATINGS , 2024 , 194 . |
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该文阐述福建省印刷电路板(PCB)领域用电子化学品产业现状，分析其发展优势及存在的主要问题，阐述福建省PCB领域用电子化学品产业发展路径及技术路线，并基于福建省PCB产业仍处于成长期，存在多方面不足的现状，围绕福建省电子化学品产业发展需求，着力解决影响产业链发展的瓶颈，提出相关对策及建议，以期助力福建省电子化学品战略性新兴产业规模与创新能力迈上新台阶。
Keyword ：
产业发展 产业发展 印刷电路板 印刷电路板 电子化学品 电子化学品 福建省 福建省
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| GB/T 7714 | 肖龙强 , 唐丹妮 , 卢振 et al. 福建省印刷电路板领域用电子化学品产业发展路径及技术路线研究 [J]. | 海峡科学 , 2024 , PageCount-页数: 6 (04) : 101-106 . |
| MLA | 肖龙强 et al. "福建省印刷电路板领域用电子化学品产业发展路径及技术路线研究" . | 海峡科学 PageCount-页数: 6 . 04 (2024) : 101-106 . |
| APA | 肖龙强 , 唐丹妮 , 卢振 , 黄昀壄 , 侯琳熙 . 福建省印刷电路板领域用电子化学品产业发展路径及技术路线研究 . | 海峡科学 , 2024 , PageCount-页数: 6 (04) , 101-106 . |
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It is a great challenge to develop thermal interface materials that enable fast heat transfer between the surface of microelectronic materials and heat sinks. In this paper, multi-walled carbon nanotube/epoxy composites (EPNH2-x) were synthesized by amidation reaction using aminated epoxy resin as matrix and carboxylated multiwalled carbon nanotubes. EP-NH2-x can reduce the interfacial thermal resistance and the promotion of phonon conduction through the chemical bonding connection between the resin and the carbon nanotubes, which will in turn improve the thermal conductivity of the composites. The thermal conductivity of EP-NH2-10 reaches 0.531 W & sdot;m- 1 & sdot;K- 1 at a and has good variable temperature cycling stability, internal elasticity and surface adhesion. This work highlights the potential application of carbon materials to improve the thermal conductivity of epoxy resins.
Keyword ：
Amidation reaction Amidation reaction Epoxy resin Epoxy resin Multi-walled carbon nanotubes Multi-walled carbon nanotubes Thermal conductivity Thermal conductivity
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| GB/T 7714 | Cai, Jingyu , Wei, Yifeng , Zhao, Hao et al. Carbon nanotubes grafting aminated epoxy resin with improved elasticity and surface adhesion for enhanced thermal management performance [J]. | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2024 , 694 . |
| MLA | Cai, Jingyu et al. "Carbon nanotubes grafting aminated epoxy resin with improved elasticity and surface adhesion for enhanced thermal management performance" . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 694 (2024) . |
| APA | Cai, Jingyu , Wei, Yifeng , Zhao, Hao , Zhang, Jian , Miao, Xiaoyu , Xiao, Longqiang et al. Carbon nanotubes grafting aminated epoxy resin with improved elasticity and surface adhesion for enhanced thermal management performance . | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS , 2024 , 694 . |
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针对苯到苯酚制备过程选择性低的问题，介绍了新型探索性实验设计，引导学生以光催化苯制苯酚作为研究对象，通过溶胶-凝胶法制备FeOOH还原氧化石墨烯复合气凝胶，并探究其在光催化苯羟基化制苯酚中的性能。本实验以实现温和条件下提高苯制苯酚选择性为目标，对于培养学生创新思维、提高创新能力与实践能力具有积极的作用。
Keyword ：
光催化 光催化 探索性实验 探索性实验 气凝胶 气凝胶 芬顿反应 芬顿反应 还原氧化石墨烯 还原氧化石墨烯
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| GB/T 7714 | 蔡静宇 , 苗晓雨 , 赵玉来 et al. FeOOH-RGO气凝胶光催化苯制备苯酚探索性教学实验设计 [J]. | 大学化学 , 2024 , 39 (04) : 169-177 . |
| MLA | 蔡静宇 et al. "FeOOH-RGO气凝胶光催化苯制备苯酚探索性教学实验设计" . | 大学化学 39 . 04 (2024) : 169-177 . |
| APA | 蔡静宇 , 苗晓雨 , 赵玉来 , 肖龙强 . FeOOH-RGO气凝胶光催化苯制备苯酚探索性教学实验设计 . | 大学化学 , 2024 , 39 (04) , 169-177 . |
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Electronic-grade isopropyl alcohol is widely utilized in the cleaning of semiconductors and microelectronic components. Removing ions like Pb2+ is crucial since the presence of impurities may cause degradation of electronics, increased failure rates, and short circuits. Membrane materials offer a number of advantages in the field of adsorption separation; however, the lack of adsorption sites results in limited adsorption capacity. In the current work, guanidino-grafted NH2-MIL-101(Fe) was incorporated into polyvinylidene fluoride (PVDF) to prepare MOF/PVDF mixed matrix membranes (NM/PVDF) for the removal of Pb2+ from isopropanol. Benefiting from the larger specific surface area and more lone electron pairs in the guanidine group, the Pb2+ adsorption capacity of the as-prepared NM/PVDF membrane was 29.4458 mg/g, which was higher than that of the NH2-MIL-101(Fe)/PVDF membrane (20.9306 mg/g) and the pure PVDF membrane (6.7324 mg/g). The NM/PVDF membrane was able to reduce the concentration of Pb2+ from 500 to 86.73 ppb. This work highlights the potential of guanidine-grafted Fe-based MOFs/PVDF membranes as adsorbents for acquisition of electronic-grade solvents.
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| GB/T 7714 | Cai, Jingyu , Shi, Junjie , Zhang, Jian et al. Preparation of Guanidine-Grafted NH2-MIL-101(Fe)/Polyvinylidene Fluoride Mixed Matrix Membranes for Adsorption of Pb2+ for Isopropanol Purification [J]. | INORGANIC CHEMISTRY , 2024 , 63 (37) : 17225-17237 . |
| MLA | Cai, Jingyu et al. "Preparation of Guanidine-Grafted NH2-MIL-101(Fe)/Polyvinylidene Fluoride Mixed Matrix Membranes for Adsorption of Pb2+ for Isopropanol Purification" . | INORGANIC CHEMISTRY 63 . 37 (2024) : 17225-17237 . |
| APA | Cai, Jingyu , Shi, Junjie , Zhang, Jian , Miao, Xiaoyu , Wang, Sen , Xiao, Longqiang et al. Preparation of Guanidine-Grafted NH2-MIL-101(Fe)/Polyvinylidene Fluoride Mixed Matrix Membranes for Adsorption of Pb2+ for Isopropanol Purification . | INORGANIC CHEMISTRY , 2024 , 63 (37) , 17225-17237 . |
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材料与化工领域的人才培养对当前社会发展具有重要的作用.结合国家工程专业学位类别调整的背景,紧扣材料工程与化学工程学科交叉点,调整专业学位硕士培养方案,全力提高材料与化工专业学位研究生创新实践能力,是新时期材料与化工专业学位研究生人才培养的发展方向.作者提出基于"企业专班"的材料与化工专业学位研究生培养模式,通过选拔生源、精选合作企业、开设企业专班,培养实践型、应用型高层次人才.从学生就业数据和学生反馈来看,取得了一定成效,具有较好的推广价值和实用意义.
Keyword ：
专业学位 专业学位 企业专班 企业专班 材料与化工 材料与化工 研究生培养 研究生培养
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| GB/T 7714 | 葛雪惠 , 肖龙强 , 杨臣 et al. 基于"企业专班"的材料与化工专业学位研究生培养模式研究 [J]. | 化工时刊 , 2024 , 38 (5) : 65-67 . |
| MLA | 葛雪惠 et al. "基于"企业专班"的材料与化工专业学位研究生培养模式研究" . | 化工时刊 38 . 5 (2024) : 65-67 . |
| APA | 葛雪惠 , 肖龙强 , 杨臣 , 侯琳熙 . 基于"企业专班"的材料与化工专业学位研究生培养模式研究 . | 化工时刊 , 2024 , 38 (5) , 65-67 . |
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