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学者姓名：叶克印
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Abstract ：
Alternating current electrolysis has emerged as a promising technique for addressing challenging redox reactions that are otherwise difficult or impossible for direct current electrolysis. Under mild and transition-metal-free reaction conditions, a general electrochemical denitrative cyclization of nitroarenes was developed to access various cyclic sulfone-containing derivatives of biological significance. The key to success lies in the facile manipulation of multiple redox events upon rapid alternating polarity switching to enhance the selectivity and efficiency.
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| GB/T 7714 | Zhu, Shuang-Jun , Lin, Yi-Chao , Yuan, Guo-Cai et al. Electrochemical Denitrative Cyclization Driven by Alternating Polarity [J]. | ORGANIC LETTERS , 2025 , 27 (5) : 1186-1191 . |
| MLA | Zhu, Shuang-Jun et al. "Electrochemical Denitrative Cyclization Driven by Alternating Polarity" . | ORGANIC LETTERS 27 . 5 (2025) : 1186-1191 . |
| APA | Zhu, Shuang-Jun , Lin, Yi-Chao , Yuan, Guo-Cai , He, Xinglei , Yu, Chunlong , Ye, Ke-Yin . Electrochemical Denitrative Cyclization Driven by Alternating Polarity . | ORGANIC LETTERS , 2025 , 27 (5) , 1186-1191 . |
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In most Suzuki-Miyaura carbon-carbon cross-coupling reactions, the borabicyclo[3.3.1]nonane scaffold (9-BBN) only serves as an auxiliary facilitating the transmetalation step and thus is transformed into by-products. There are rare examples where the 9-BBN derivatives serve as the potentially diverse C8 building blocks in cross-coupling reactions. Herein, we report a cobalt-catalyzed migratory carbon- carbon cross-coupling reaction of the in situ formed 9-BBN ate complexes to afford diverse aryl- and alkyl-functionalized cyclooctenes. Preliminary mechanistic studies suggest the oxidation-induced cis- bicyclo[3.3.0]oct-1-ylborane is the key intermediate in this migratory cross-coupling reaction, which promotes the development of other diverse migratory cross-coupling of borate complexes. (c) 2025 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
Keyword ：
Borate Borate Cobalt Cobalt Cross-coupling Cross-coupling Cyclooctene Cyclooctene Rearrangement Rearrangement
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| GB/T 7714 | Guo, Peng , Dong, Shicheng , Zhang, Xiang-Gui et al. Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates [J]. | CHINESE CHEMICAL LETTERS , 2025 , 36 (4) . |
| MLA | Guo, Peng et al. "Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates" . | CHINESE CHEMICAL LETTERS 36 . 4 (2025) . |
| APA | Guo, Peng , Dong, Shicheng , Zhang, Xiang-Gui , Yang, Bing-Bin , Zhu, Jun , Ye, Ke-Yin . Cobalt-catalyzed migratory carbon-carbon cross-coupling of borabicyclo[3.3.1]nonane (9-BBN) borates . | CHINESE CHEMICAL LETTERS , 2025 , 36 (4) . |
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Well-defined metal-organic frameworks (MOFs) provide an attractive platform for catalysis. Understanding the intrinsic structure-activity relationship of MOFs helps guide the design of novel catalysts. In this work, a new three-dimensional (3D) MnII(salen)-based MOF (1) with strong adsorption capacity and high selectivity for CO2 was synthesized. Through sequential demetallization and remetallization, the flexible tailoring of the metal centers was realized to obtain a series of remetallized MOFs (r1 M ; M = Mn, Co, Cu, Ni, V). Among them, r1 Co was proved to be the most active catalyst for the cycloaddition of CO2 and epoxides. Mechanistic studies reveal that r1 Co displays a high CO2 affinity and Lewis acidity. In addition, kinetic studies suggest that r1 Co has a lower activation energy than the original MOF (1) and demetallized MOF (d1). Remarkably, r1 Co could be reused five times without affecting its catalytic activity.
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| GB/T 7714 | Yu, Chunlong , He, Xinglei , Gong, Chenxu et al. Tailoring of Unsaturated Metal Sites in Metal-Organic Frameworks to Promote the Conversion of CO2 into High-Value-Added Products [J]. | INORGANIC CHEMISTRY , 2025 , 64 (14) : 6977-6986 . |
| MLA | Yu, Chunlong et al. "Tailoring of Unsaturated Metal Sites in Metal-Organic Frameworks to Promote the Conversion of CO2 into High-Value-Added Products" . | INORGANIC CHEMISTRY 64 . 14 (2025) : 6977-6986 . |
| APA | Yu, Chunlong , He, Xinglei , Gong, Chenxu , Li, Jingheng , Ye, Ke-Yin . Tailoring of Unsaturated Metal Sites in Metal-Organic Frameworks to Promote the Conversion of CO2 into High-Value-Added Products . | INORGANIC CHEMISTRY , 2025 , 64 (14) , 6977-6986 . |
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Efficient synthetic methods are urgently needed to produce graphene nanoribbons (GNRs) with diverse structures and functions. Precise control over the topological edges of GNRs is also crucial for achieving diverse molecular topologies and desirable electro-optical properties. This study demonstrates a highly efficient "shotgun" synthesis of thiophene-backbone arcuate GNRs, offering a significant advantage over tedious iterative synthesis. This method utilizes a one-pot, three component Suzuki-Miyaura coupling for the precursor, followed by a Scholl reaction for cyclization. The resulting arcuate GNRs have sulfur atoms embedded in the carbon backbone with a combined armchair, cove, and fjord edge structure. This multi-edge architecture is further modified by high-yield oxidation of the electron-rich sulfur atoms to electron-deficient sulfones, enabling precise regulation of the GNRs' electronic properties. These arcuate GNRs with diverse edge structures, heteroatom doping and precise lengths open exciting avenues for their application in optoelectronic devices.
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| GB/T 7714 | Zhang, Ruiying , Chen, Xinyu , Zhu, Lingyun et al. Thiophene-backbone arcuate graphene nanoribbons: shotgun synthesis and length dependent properties [J]. | CHEMICAL SCIENCE , 2025 . |
| MLA | Zhang, Ruiying et al. "Thiophene-backbone arcuate graphene nanoribbons: shotgun synthesis and length dependent properties" . | CHEMICAL SCIENCE (2025) . |
| APA | Zhang, Ruiying , Chen, Xinyu , Zhu, Lingyun , Huang, Yanxia , Zhai, Zi'ang , Wang, Qiang et al. Thiophene-backbone arcuate graphene nanoribbons: shotgun synthesis and length dependent properties . | CHEMICAL SCIENCE , 2025 . |
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Abstract ：
研究生教育是高等教育的最高层次,是衡量一个国家高等教育竞争力的关键标志,是拔尖创新人才自主培养的主渠道.为了提高人才培养质量,在"以学生为中心,注重科学思维培养,注重科研能力培养以及注重国际视野培养"的教学思想指导下,针对有机结构分析课程教学过程中存在的难点问题,从"教学理念的国际化、教学内容的国际化、教学团队的国际化、教学方法的国际化"等方面进行创新教学实践,取得了一系列成果,有效地提升了学生的科研水平,对于创新型人才的培养起到了积极的推动作用.
Keyword ：
国际化视野 国际化视野 学生为中心 学生为中心 有机结构分析 有机结构分析 研究生教学 研究生教学
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| GB/T 7714 | 袁耀锋 , 叶克印 , 徐春发 et al. 在研究生课程的教学中注重国际视野的培养 [J]. | 大学化学 , 2024 , 39 (6) : 145-150 . |
| MLA | 袁耀锋 et al. "在研究生课程的教学中注重国际视野的培养" . | 大学化学 39 . 6 (2024) : 145-150 . |
| APA | 袁耀锋 , 叶克印 , 徐春发 , 晏宏 , 李远明 . 在研究生课程的教学中注重国际视野的培养 . | 大学化学 , 2024 , 39 (6) , 145-150 . |
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Conventional approaches to unsymmetric disiloxanes involve the condensation of silanol with hydroxy-, chloro-, or alkoxysilanes, which suffers from several limitations such as limited substrate scope, the requisite use of stoichiometric bases, expensive transition-metal catalysts, and typically unsatisfactory product selectivity. Herein, we report a dehydrative cobalt catalysis for unsymmetric disiloxane from two different silanols, which features a low loading of the earth-abundant cobalt catalyst, easy operation, good functional combinability, and gram-scale preparation. Notably, this approach also enables the facile preparation of unsymmetric polysiloxanes. A highly selective and scalable dehydrative approach for the synthesis of unsymmetric disiloxanes and polysiloxanes is reported using Earth-abundant cobalt catalyst under an air atmosphere.
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| GB/T 7714 | Yang, Bing-Bin , Guo, Peng , He, Xinglei et al. Cobalt-catalyzed dehydrative approach for the synthesis of unsymmetric disiloxanes and polysiloxanes [J]. | ORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (15) : 4125-4130 . |
| MLA | Yang, Bing-Bin et al. "Cobalt-catalyzed dehydrative approach for the synthesis of unsymmetric disiloxanes and polysiloxanes" . | ORGANIC CHEMISTRY FRONTIERS 11 . 15 (2024) : 4125-4130 . |
| APA | Yang, Bing-Bin , Guo, Peng , He, Xinglei , Ye, Ke-Yin . Cobalt-catalyzed dehydrative approach for the synthesis of unsymmetric disiloxanes and polysiloxanes . | ORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (15) , 4125-4130 . |
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Herein, we reported the straightforward synthesis of thiomethylnaphthalenes via the reaction of propargyl alcohols with dimethyl sulfoxide/thionyl chloride (DMSO/SOCl2), which also provided easy access to deuterated thiomethyl and other thioalkyl scaffolds when deuterated dimethyl sulfoxide and dialkyl sulfoxides were used, respectively. In addition, the thiomethyl group can be readily derivatized to the corresponding sulfoxide, sulfone, and sulfoximine of interesting photophysical properties.
Keyword ：
Cyclization Cyclization Propargyl alcohols Propargyl alcohols Solvatochromism Solvatochromism Thiomethylnaphthalenes Thiomethylnaphthalenes Transition-metal-free Transition-metal-free
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| GB/T 7714 | Wang, Zhihua , Liang, Wang-Fu , He, Xinglei et al. DMSO/SOCl2-Mediated Synthesis of Thiomethylnaphthalenes from Propargyl Alcohols [J]. | ADVANCED SYNTHESIS & CATALYSIS , 2024 , 367 (3) . |
| MLA | Wang, Zhihua et al. "DMSO/SOCl2-Mediated Synthesis of Thiomethylnaphthalenes from Propargyl Alcohols" . | ADVANCED SYNTHESIS & CATALYSIS 367 . 3 (2024) . |
| APA | Wang, Zhihua , Liang, Wang-Fu , He, Xinglei , Li, Jingheng , Ye, Ke-Yin . DMSO/SOCl2-Mediated Synthesis of Thiomethylnaphthalenes from Propargyl Alcohols . | ADVANCED SYNTHESIS & CATALYSIS , 2024 , 367 (3) . |
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Abstract ：
We would like to take this opportunity to thank all of Organic Chemistry Frontiers' reviewers for helping to preserve quality and integrity in chemical science literature. We would also like to highlight the Outstanding Reviewers for Organic Chemistry Frontiers in 2023.
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| GB/T 7714 | Bi, Xihe , D'Elia, Valerio , Gu, Zhenhua et al. Outstanding Reviewers for Organic Chemistry Frontiers in 2023 [J]. | ORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (15) : 4068-4069 . |
| MLA | Bi, Xihe et al. "Outstanding Reviewers for Organic Chemistry Frontiers in 2023" . | ORGANIC CHEMISTRY FRONTIERS 11 . 15 (2024) : 4068-4069 . |
| APA | Bi, Xihe , D'Elia, Valerio , Gu, Zhenhua , Hato, Yoshio , Kikuchi, Jun , Koh, Ming Joo et al. Outstanding Reviewers for Organic Chemistry Frontiers in 2023 . | ORGANIC CHEMISTRY FRONTIERS , 2024 , 11 (15) , 4068-4069 . |
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Diamines play important roles in synthetic organic chemistry and thus facilitate life and materials sciences. Herein we report a cobalt-catalyzed ring opening, nucleophilic amination of aziridines and azetidines with N-fluorosulfonamides toward a wide range of 1,2- and 1,3-diamine derivatives in moderate to good yields under mild conditions. A cobalt-catalyzed ring opening, nucleophilic amination of aziridines and azetidines with N-fluorosulfonamides has been established toward a wide range of 1,2- and 1,3-diamine derivatives in moderate to good yields under mild conditions.
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| GB/T 7714 | Cheng, Ling-Chao , Wang, Zhihua , He, Xinglei et al. Cobalt-catalyzed amination of aziridines and azetidines toward 1,2-and 1,3-diamines [J]. | ORGANIC & BIOMOLECULAR CHEMISTRY , 2024 , 22 (13) : 2554-2557 . |
| MLA | Cheng, Ling-Chao et al. "Cobalt-catalyzed amination of aziridines and azetidines toward 1,2-and 1,3-diamines" . | ORGANIC & BIOMOLECULAR CHEMISTRY 22 . 13 (2024) : 2554-2557 . |
| APA | Cheng, Ling-Chao , Wang, Zhihua , He, Xinglei , Liang, Wangfu , Ye, Ke-Yin . Cobalt-catalyzed amination of aziridines and azetidines toward 1,2-and 1,3-diamines . | ORGANIC & BIOMOLECULAR CHEMISTRY , 2024 , 22 (13) , 2554-2557 . |
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We present here a catalytic enantioconvergent amination of alcohols for efficient access to chiral C2- and C3-substituted benzomorpholines. The racemic amino alcohol substrates of different substitution patterns, which are readily available from a common precursor, can be converted to the enantioenriched heterocycles in a highly atom- and step-economical fashion. In particular, an unprecedented asymmetric amination of racemic primary alcohols via dynamic kinetic resolution is achieved under cooperative iridium/iron catalysis, resulting in highly enantioen-riched C2-substituted benzomorpholines that aredifficult to access otherwise.
Keyword ：
atom economy atom economy divergent synthesis divergent synthesis dynamic kinetic resolution dynamic kinetic resolution enantiocon-vergent heterocycle synthesis enantiocon-vergent heterocycle synthesis redox-neutral catalysis redox-neutral catalysis substituted benzomorpholines substituted benzomorpholines
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| GB/T 7714 | Gao, Yaru , Hong, Guorong , Zhang, Lei et al. Asymmetric Amination of Primary Alcohols via Dynamic Kinetic Resolution: Enantioconvergent Access to Chiral Benzomorpholines [J]. | CCS CHEMISTRY , 2024 . |
| MLA | Gao, Yaru et al. "Asymmetric Amination of Primary Alcohols via Dynamic Kinetic Resolution: Enantioconvergent Access to Chiral Benzomorpholines" . | CCS CHEMISTRY (2024) . |
| APA | Gao, Yaru , Hong, Guorong , Zhang, Lei , Ye, Ke-Yin , Cheng, Jiajia , Yang, Bin-Miao et al. Asymmetric Amination of Primary Alcohols via Dynamic Kinetic Resolution: Enantioconvergent Access to Chiral Benzomorpholines . | CCS CHEMISTRY , 2024 . |
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