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学者姓名:邓辉
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The optimization of the back interface is an important means of improving the power conversion efficiency (PCE) of Cu2ZnSn(S,Se)4 (CZTSSe) solar cells. Here, a CuO sacrificial layer is introduced into the Mo/CZTSSe back interface to improve device efficiency. The insertion of the CuO sacrificial layer inhibits the formation of Sn(S,Se)2 secondary phases in the CZTSSe film. Meanwhile, the interfacial trap state (N IT) is reduced by about 22%. Furthermore, the 75 nm CuO sacrificial layer can reduce the thickness of the MoSe2 layer, leading to a 33.18 meV reduction in the back interfacial barrier. This design enhances the back interfacial transport characteristics and suppresses defects. Finally, the flexible CZTSSe solar cell achieve the efficiency of 10.57%.
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GB/T 7714 | Su, Zhenyi , Xie, Weihao , Sun, Quanzhen et al. Overcoming Back Interfacial Barrier Improves Flexible Cu2ZnSn(S,Se)4 Solar Cell Efficiency via CuO Sacrificial Layers [J]. | ACS MATERIALS LETTERS , 2025 , 7 (4) : 1329-1335 . |
MLA | Su, Zhenyi et al. "Overcoming Back Interfacial Barrier Improves Flexible Cu2ZnSn(S,Se)4 Solar Cell Efficiency via CuO Sacrificial Layers" . | ACS MATERIALS LETTERS 7 . 4 (2025) : 1329-1335 . |
APA | Su, Zhenyi , Xie, Weihao , Sun, Quanzhen , Li, Yifan , Zhong, Zhipan , Wang, Weihuang et al. Overcoming Back Interfacial Barrier Improves Flexible Cu2ZnSn(S,Se)4 Solar Cell Efficiency via CuO Sacrificial Layers . | ACS MATERIALS LETTERS , 2025 , 7 (4) , 1329-1335 . |
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2D perovskite materials are ideal candidates for indoor photovoltaic (IPV) applications due to their tunable bandgap, high absorption coefficients, and enhanced stability. However, attaining uniform crystallization and overcoming low carrier mobility remain key challenges for 2D perovskites, limiting their overall performance. In this study, a 2D perovskite light-absorbing layer is constructed using a Dion-Jacobson (DJ)-phase EDA(FA)(4)Pb5I16 (n = 5) and introduced butylammonium iodide (BAI) for interface modification, thereby creating a novel DJ/Ruddlesden-Popper (RP) dual 2D perovskite heterostructure. By adjusting the thickness of the BAI-based perovskite layer, the relationship between interfacial defect states and carrier mobility is investigated under varying indoor light intensities. The results indicate that, by achieving a balance between interfacial defect passivation and carrier transport, the optimized 2D perovskite device reaches a power conversion efficiency (PCE) of 30.30% and an open-circuit voltage (V-OC) of 936 mV under 1000 lux (3000 K LED). 2D-DJ/RP perovskite IPV exhibits a twentyfold increase in T-90 lifetime compared to 3D perovskite devices. It is the first time to systematically study 2D perovskites in IPV applications, demonstrating that rationally designed and optimized 2D perovskites hold significant potential for fabricating high-performance indoor PSCs.
Keyword :
2D perovskite solar cells 2D perovskite solar cells carrier transport carrier transport defect passivation defect passivation dual-phase 2D perovskite heterostructures dual-phase 2D perovskite heterostructures indoor photovoltaic indoor photovoltaic
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GB/T 7714 | Wang, Renjie , Wu, Jionghua , Zheng, Qiao et al. Stable and Efficient Indoor Photovoltaics Through Novel Dual-Phase 2D Perovskite Heterostructures [J]. | ADVANCED MATERIALS , 2025 . |
MLA | Wang, Renjie et al. "Stable and Efficient Indoor Photovoltaics Through Novel Dual-Phase 2D Perovskite Heterostructures" . | ADVANCED MATERIALS (2025) . |
APA | Wang, Renjie , Wu, Jionghua , Zheng, Qiao , Deng, Hui , Wang, Weihuang , Chen, Jing et al. Stable and Efficient Indoor Photovoltaics Through Novel Dual-Phase 2D Perovskite Heterostructures . | ADVANCED MATERIALS , 2025 . |
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Antimony sulfide (Sb2S3) solar cells fabricated via hydrothermal deposition have attracted widespread attention. The annealing crystallization process plays a crucial role in achieving optimal crystallinity in hydrothermal Sb2S3 thin films. Nevertheless, incomplete crystallization and the loss of sulfur at high-temperature contribute to defect recombination, constraining device performance. Herein, a two-step rapid thermal processing (RTP) annealing strategy is proposed to improve the crystal quality and efficiency of Sb2S3 solar cells. The annealing process in Ar protection with atmospheric pressure can suppress S loss caused by saturated vapor pressure. The two-step RTP annealing with the 330°C low-temperature and 370°C high-temperature process ensures high crystallinity and vertical orientations of Sb2S3 thin films, accompanied by a reduction in defect concentration from 1.01 × 1012 to 5.97 × 1011 cm−3. The Sb2S3 solar cell achieves an efficiency of 8.20% with an enhanced open circuit voltage (VOC) of 784 mV. The build-in voltage (Vbi) of 1.17 V and irradiation-dependent ideal factor (n) of 1.48 demonstrate enhanced heterojunction quality and suppressed defect recombination in the devices. The presented two-step annealing strategy and physical mechanism study will open new prospects for high-performance Sb2S3 solar cells. © Science China Press 2024.
Keyword :
defect passivation defect passivation hydrothermal hydrothermal Sb2S3 solar cells Sb2S3 solar cells two-step annealing two-step annealing
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GB/T 7714 | Deng, H. , Feng, X. , Zhu, Q. et al. 8.2%-Efficiency hydrothermal Sb2S3 thin film solar cells by two-step RTP annealing strategy; [两步快速热处理退火策略实现8.2%效率的水热法硫化锑薄膜太阳能电池] [J]. | Science China Materials , 2024 , 67 (11) : 3666-3674 . |
MLA | Deng, H. et al. "8.2%-Efficiency hydrothermal Sb2S3 thin film solar cells by two-step RTP annealing strategy; [两步快速热处理退火策略实现8.2%效率的水热法硫化锑薄膜太阳能电池]" . | Science China Materials 67 . 11 (2024) : 3666-3674 . |
APA | Deng, H. , Feng, X. , Zhu, Q. , Liu, Y. , Wang, G. , Zhang, C. et al. 8.2%-Efficiency hydrothermal Sb2S3 thin film solar cells by two-step RTP annealing strategy; [两步快速热处理退火策略实现8.2%效率的水热法硫化锑薄膜太阳能电池] . | Science China Materials , 2024 , 67 (11) , 3666-3674 . |
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Antimony sulfide (Sb2S3) photodetectors (PDs) possess extensive application prospects. Efficient carrier transport of a PD significantly affects the detectivity and response speed. Herein, we propose an all-inorganic self-powered Sb2S3 PD based on vertical TiO2 nanorods (NRs). The spray-coated 15-nm TiO2 thin film as a seed layer ensures the growth of compact vertical TiO2 nanorod arrays by the hydrothermal method. One-dimensional TiO2 nanorods facilitate photocarrier separation and transport to enhance device performance. Ultimately, the Sb2S3 PD achieves a responsivity of 0.29 A/W, a specific detectivity of 3.37 x 1012 Jones, and a response time of 7.8 mu s, showing great potential in commercial applications. (c) 2024 Optica Publishing Group. All rights, including for text and data mining (TDM), Artificial Intelligence (AI) training, and similar technologies, are reserved.
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GB/T 7714 | Kang, Yubin , Deng, Hui , Wu, Kefei et al. Self-powered Sb2S3 photodetectors with efficient carrier transport enabled by compact vertical TiO2 nanorods [J]. | OPTICS LETTERS , 2024 , 49 (22) : 6533-6536 . |
MLA | Kang, Yubin et al. "Self-powered Sb2S3 photodetectors with efficient carrier transport enabled by compact vertical TiO2 nanorods" . | OPTICS LETTERS 49 . 22 (2024) : 6533-6536 . |
APA | Kang, Yubin , Deng, Hui , Wu, Kefei , Wang, Guidong , Hong, Jinwei , Wang, Weihuang et al. Self-powered Sb2S3 photodetectors with efficient carrier transport enabled by compact vertical TiO2 nanorods . | OPTICS LETTERS , 2024 , 49 (22) , 6533-6536 . |
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基于水热法的硫化锑(Sb_3S_3)太阳能电池性能具有较大前景,利用掺杂剂、硒化、硫化等方法可以实现硫化锑太阳能电池的进一步提升。退火是水热硫化锑必不可少的过程,利用这一过程实现无定形薄膜到结晶态的转变。目前,水热法制备的硫化锑仍面临着体相缺陷制约其效率的进步,而如何提升薄膜体相结晶态还是一个难题,有关这一方面的工作还需要更多的研究。我们针对薄膜的退火进行了一些研究,研究空气、手套箱热台及Ar管式炉下的退火,对比不同退火工艺下的薄膜晶态转变及晶粒的融合生长过程,进一步分析薄膜内部缺陷的影响因素。最后,基于Ar管式炉退火的Sb_2S_3获得了最好的薄膜质量,得益于其结晶态的增强及取向的调控,优化后的器件实现了PCE 7.53%,这位于硫化锑太阳能电池的第一梯队。该结果为硫化锑缺陷态的形成过程提供了研究思路,也将促进高效Sb_2S_3太阳能电池的快速发展。
Keyword :
水热沉积 水热沉积 硫化锑薄膜 硫化锑薄膜 退火 退火
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GB/T 7714 | 冯信信 , 邓辉 , 程树英 . 水热法Sb_2S_3太阳能电池的退火工艺研究 [C] //第十一届新型太阳能材料科学与技术学术研讨会 . 2024 . |
MLA | 冯信信 et al. "水热法Sb_2S_3太阳能电池的退火工艺研究" 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
APA | 冯信信 , 邓辉 , 程树英 . 水热法Sb_2S_3太阳能电池的退火工艺研究 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
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光电探测器能够利用自身结构实现自供电,广泛应用于环境监测、光通信和航空航天等领域,由于硫化锑(Sb_2S_3)无毒、储量丰富、在可见光范围内具有良好的吸光能力,完美符合制备光电探测器的材料要求。因此,我们采用低成本的水热法合成TiO_2纳米棒阵列(NRs),通过快速热蒸发法(RTE)制备Sb_2S_3薄膜。水热法合成的TiO_2-NRs可以增加器件的并联电阻来抑制漏电流。并且可以调控RTE法制备的Sb_2S_3薄膜取向,进而减少链间电荷跳变和复合,有利于光生载流子输运,增强光电响应速度。制备的器件结构为FTO/TiO_2-NRs/Sb_2S_3/Au,可在无外加偏压情况下表现出良好的光电性能,在波长为625 nm、光功率密度为400μW/cm~2的光照条件下,器件的响应度为0.6 A/W,响应时间接近1μs。该Sb_2S_3光伏型探测器将会为光通信提供器件基础。
Keyword :
光伏型光电探测器 光伏型光电探测器 硫化锑 硫化锑 纳米棒阵列 纳米棒阵列
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GB/T 7714 | 康裕滨 , 邓辉 , 程树英 . 基于二氧化钛纳米棒阵列的硫化锑光伏型光电探测器 [C] //第十一届新型太阳能材料科学与技术学术研讨会 . 2024 . |
MLA | 康裕滨 et al. "基于二氧化钛纳米棒阵列的硫化锑光伏型光电探测器" 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
APA | 康裕滨 , 邓辉 , 程树英 . 基于二氧化钛纳米棒阵列的硫化锑光伏型光电探测器 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
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光电探测器是光通信系统中重要器件,现在以硅基为主,其蓝绿波段光的吸光系数较低,且成本高昂。硫化锑(Sb_2S_3)是一种二元化合物,且具有物相单一、无毒环保和价格低廉等,吸光吸收较大,可实现可见光探测应用于光通信领域。构建自供电的Sb_2S_3光伏探测器PDMS/glass/FTO/TiO_2/Sb_2S_3/Au。在内部实现吸收层厚度与耗尽区宽度匹配,增强电荷传输;在外部设计金字塔状的聚二甲基硅氧烷(PDMS)陷光膜,增强光吸收能力。最终,器件实现在530 nm波长下1μW/cm~2光强下响应度3.41A/W和比探测率2.84×10~(13) Jones。Sb_2S_3光伏电池可实现光电信号检测,用于实现高效的光电转换和信号的高保真传输,在可见光通信系统中具有应用前景。通过SCAPS-1D软件模拟获得了结构的最佳厚度,优化后的器件具有高性能参数,探测器获得440kHz的带宽。此外,通过设计匹配的光检测电路,成功地将由此产生的Sb_2S_3光伏型探测器集成到可见光通信系统中,实现了语音的传输。
Keyword :
光伏探测器 光伏探测器 光通信 光通信 硫化锑 硫化锑
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GB/T 7714 | 邓辉 , 程树英 , 夏勇 . 面向光通信应用的硫化锑光伏器件 [C] //第十一届新型太阳能材料科学与技术学术研讨会 . 2024 . |
MLA | 邓辉 et al. "面向光通信应用的硫化锑光伏器件" 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
APA | 邓辉 , 程树英 , 夏勇 . 面向光通信应用的硫化锑光伏器件 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
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物联网行业的发展带动室内能源消耗的提升,光伏电池在室内环境应用的需求也逐步增加。不同于传统户外太阳光照射条件,室内光源针对于人眼设计,主要波长分布在可见光范围,理论计算所得的最佳带隙为1.9 eV~([1]);同时室内环境的光照强度相较于室外弱了2-3个数量级,两者较大的光照条件差异使得老牌的诸如硅基等光伏电池在室内环境的表现并不理想。硫化锑薄膜电池的带隙为1.7 eV,与室内光伏的最佳带隙较为匹配,同时拥有较大的吸收系数(10~(5 )cm~(-1))~([2]),针对于弱光环境实现一个良好的吸光效果,是一种可应用于室内光伏的优秀材料。在常用的室内照明用台灯的照射下,基础的硫化锑薄膜电池(FTO/TiO_2/Sb_2S_3/Au)实现了1000 lux照度下超过10%的光电转换效率(AM 1.5G下5%)。对于室内光照的特定环境,再针对硫化锑薄膜电池进行带隙提升、界面改性等处理,有望实现在室内弱光环境下的更高光电转换效率~([3])。
Keyword :
室内光伏 室内光伏 带隙匹配 带隙匹配 开压改善 开压改善 硫化锑薄膜电池 硫化锑薄膜电池
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GB/T 7714 | 吴可非 , 邓辉 , 程树英 . 全无机硫化锑薄膜室内光伏电池 [C] //第十一届新型太阳能材料科学与技术学术研讨会 . 2024 . |
MLA | 吴可非 et al. "全无机硫化锑薄膜室内光伏电池" 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
APA | 吴可非 , 邓辉 , 程树英 . 全无机硫化锑薄膜室内光伏电池 第十一届新型太阳能材料科学与技术学术研讨会 . (2024) . |
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Efficient ternary organic solar cells were achieved by utilizing an ultra-narrow bandgap material, IEICO-4 F, mixed with the fullerene material PC71BM as the acceptor and PTB7-Th polymer as the donor. The different weights of IEICO-4 F were dropped into the active layer to adjust the ratio of acceptor and donor, optimizing the performance of the cells. The results showed the ternary organic solar cells with 10wt% IEICO-4 F could obtain a higher short-circuit current density resulting in the power conversion efficiency (PCE) up to 9.56%. MoO3/Ag/MoO3 as the transparent electrodes of the semitransparent organic solar cell (ST-OSCs) were prepared. The different thicknesses of Ag impacts on the performance of the ST-OSCs were investigated. The PCE of the ternary ST-OSCs was increased to 7.34% and the average visible light transmittance (AVT) was increased to 28.74% when Ag was 10 nm thickness. The ternary ST-OSCs presented both a good light transmittance and a high PCE. In addition, the light utilization efficiency of the ST-OSCs was increased to 2.1%, and the color reproduction index was improved too. The PCE and AVT of the ST-OSCs could improve simultaneously due to the appropriate ratio of the acceptor and donor as well as the optimized transparent electrodes.
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GB/T 7714 | Zheng, Qiao , Zhou, Hui , Du, Shunli et al. Efficiency and average visible light transmittance improved simultaneously of the semitransparent organic solar cells [J]. | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS , 2024 , 35 (6) . |
MLA | Zheng, Qiao et al. "Efficiency and average visible light transmittance improved simultaneously of the semitransparent organic solar cells" . | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 35 . 6 (2024) . |
APA | Zheng, Qiao , Zhou, Hui , Du, Shunli , Chen, Pengsen , Huang, Jingang , Deng, Hui et al. Efficiency and average visible light transmittance improved simultaneously of the semitransparent organic solar cells . | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS , 2024 , 35 (6) . |
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Antimony selenosulfide (Sb-2(S,Se)(3)) solar cells have achieved an efficiency of over 10.0%. However, the uncontrollable hydrothermal process makes preparing high-quality Sb-2(S,Se)(3) thin films a bottleneck for efficient Sb-2(S,Se)(3) solar cell. To address this problem, triethanolamine (TEA) additive is innovatively utilized to regulate the reaction kinetic process of Sb-2(S,Se)(3) thin films in this work. The results show that TEA chelator can realize the time-domain control of the reaction process, optimizing the Se/(S+Se) elemental distribution of Sb-2(S,Se)(3) thin film and shrinking the bandgap offset of Sb-2(S,Se)(3) thin film. Meanwhile, the (021) and (061) crystal orientation of Sb-2(S,Se)(3) thin film are enhanced and the harmful V-Se1 defects in Sb-2(S,Se)(3) solar cells are passivated. Interestingly, a uniform back surface gradient for Sb-2(S,Se)(3) thin film is formed to reduce the minority carrier recombination at the back contact, increase the photocurrent and decrease the diode current of Sb-2(S,Se)(3) solar cells. Finally, the J(sc) and FF of Sb-2(S,Se)(3) solar cells are significantly improved by 8.6% and 5.5% respectively, and the open-circuit voltage deficit of the device is reduced by 44 mV, which leads to an efficiency of 9.94% which is the highest values of Sb-2(S,Se)(3) solar cells by sodium selenosulfate system.
Keyword :
additive additive hydrothermal deposition hydrothermal deposition reaction kinetic reaction kinetic Sb-2(S, Se)(3) solar cells Sb-2(S, Se)(3) solar cells sodium selenosulfate sodium selenosulfate
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GB/T 7714 | Zhu, Qiqiang , Wang, Weihuang , Chen, Zhirong et al. Fabricating High-Efficiency Sb2(S,Se)3 Solar Cells by Novel Additive-Assisted Longitudinal Component Engineering [J]. | SMALL , 2024 . |
MLA | Zhu, Qiqiang et al. "Fabricating High-Efficiency Sb2(S,Se)3 Solar Cells by Novel Additive-Assisted Longitudinal Component Engineering" . | SMALL (2024) . |
APA | Zhu, Qiqiang , Wang, Weihuang , Chen, Zhirong , Cao, Zixiu , Wang, Weiyu , Feng, Xinxin et al. Fabricating High-Efficiency Sb2(S,Se)3 Solar Cells by Novel Additive-Assisted Longitudinal Component Engineering . | SMALL , 2024 . |
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