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author:

Han, Jun-Fa (Han, Jun-Fa.) [1] | Guo, Peng (Guo, Peng.) [2] | Zhang, Xiang-Gui (Zhang, Xiang-Gui.) [3] | Liao, Jia-Bin (Liao, Jia-Bin.) [4] | Ye, Ke-Yin (Ye, Ke-Yin.) [5] (Scholars:叶克印)

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Abstract:

Unlike many other state-of-the-art transition-metal-catalyzed allylic substitutions, cobalt-catalyzed allylic substitution has received much less attention from synthetic chemists for a long time despite the fact that cobalt is an earth-abundant, low-cost and thus much more sustainable option as either a reagent or a catalyst in organic synthesis. Recently, there has been an upsurge in the use of cobalt catalysis in allylic functionalization reactions, including allylic substitution, nucleophilic allylation, and Heck-type allylic functionalization, to construct synthetically significant building blocks featuring a double bond available for diverse downstream synthetic manipulations. This review highlights the current development of cobalt catalysis in allylic functionalization with an in-depth discussion of the reaction scope and mechanistic insights.

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Community:

  • [ 1 ] [Han, Jun-Fa]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 2 ] [Guo, Peng]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang, Xiang-Gui]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 4 ] [Liao, Jia-Bin]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China
  • [ 5 ] [Ye, Ke-Yin]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 叶克印

    [Ye, Ke-Yin]Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China

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ORGANIC & BIOMOLECULAR CHEMISTRY

ISSN: 1477-0520

Year: 2020

Issue: 39

Volume: 18

Page: 7740-7750

3 . 8 7 6

JCR@2020

2 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 24

ESI Highly Cited Papers on the List: 1 Unfold All

  • 2023-7

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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