Persistent radical anions in panchromatic D-A hybrid heterostructures induced by anion-pi interactions - Details

author：

You, Ming-Hua (You, Ming-Hua.) ^[1] | Di, Yi-Ming (Di, Yi-Ming.) ^[2] | Li, Meng-Hua (Li, Meng-Hua.) ^[3] | Li, Hao-Hong (Li, Hao-Hong.) ^[4] (Scholars：李浩宏) | Lin, Mei-Jin (Lin, Mei-Jin.) ^[5] (Scholars：林梅金)

Indexed by：

EI Scopus SCIE

Abstract：

The　combination　of　N,　N＇-dipyridyl-tetrachlomperylene　diimide　(4Cl-DPPDI)　buliding　blocks　with　lead　iodides　in　the　presence　of　hydrogen　iodides　led　to　a　novel　D-A　hybrid　heterostructure　with　segregated　iodoplumbate　anions　and　2-D　H-bonded　4Cl-DPPDI　networks　as　electron　donors　and　acceptors.　Due　to　the　compact　anion-pi　interactions　as　well　as　small　energy　gaps　between　the　donors　and　acceptors,　persistent　and　stable　radical　anions　are　generated　in　such　a　unique　complex　triggered　by　natural-light　irradiation,　which　thus　exhibits　a　panchromatic　absorption.

Keyword：

Anion-pi interactions D-A hybrid heterostructures Iodoplumbate anions Perylene diimides Stable radicals

Community：

[ 1 ] [You, Ming-Hua]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
[ 2 ] [Di, Yi-Ming]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
[ 3 ] [Li, Meng-Hua]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
[ 4 ] [Li, Hao-Hong]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
[ 5 ] [Lin, Mei-Jin]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China
[ 6 ] [You, Ming-Hua]Fuzhou Univ, Coll Zhicheng, Fuzhou 350002, Peoples R China

Reprint 's Address：

林梅金
[Lin, Mei-Jin]Fuzhou Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Peoples R China

Email：

meijin_lin@fzu.edu.cn

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