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author:

Zhong, Hong (Zhong, Hong.) [1] | Sa, Rongjian (Sa, Rongjian.) [2] | Lv, Haowei (Lv, Haowei.) [3] | Yang, Shuailong (Yang, Shuailong.) [4] | Yuan, Daqiang (Yuan, Daqiang.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] (Scholars:王心晨) | Wang, Ruihu (Wang, Ruihu.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

The visible-light-driven photocatalytic CO(2)reduction is one appealing approach to simultaneously mitigate the energy crisis and environmental issues. It is highly desirable but challenging to selectively and efficiently convert CO(2)into desirable products. Herein, a covalent organic framework hosting metalloporphyrin-based carbon dots (M-PCD@TD-COF, M = Ni, Co, and Fe) is first presented, which serves as heterogeneous catalysts for CO(2)photoreduction. M-PCD@TD-COF not only enriches available COF-based catalytic materials, but also provides suitable environment for CO(2)adsorption and activation on metalloporphyrin-based carbon dots. The advantages of the host environment in COFs are highlighted by the satisfactory catalytic activity and remarkable selectivity of CO2-to-CO conversion over H(2)generation up to 98%. The photocatalytic system is effective for both pure CO(2)and the simulated flue gas. This work provides new protocols for the rational design of COF-based heterogeneous catalysts for selective CO(2)photoreduction.

Keyword:

carbon dots CO(2)reduction covalent organic frameworks photocatalysis porous materials

Community:

  • [ 1 ] [Zhong, Hong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Lv, Haowei]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Yang, Shuailong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Yuan, Daqiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wang, Ruihu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Sa, Rongjian]Minjiang Univ, Ocean Coll, Inst Oceanog, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Wang, Ruihu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2020

1 8 . 8 0 8

JCR@2020

1 8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 136

SCOPUS Cited Count: 143

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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