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In order to promote the commercial application of proton exchange membrane fuel cells, it is of great importance to develop Pt-based electrocatalysts with high activity and stability for the oxygen reduction reaction (ORR). Here, urchin-like mesoporous TiO2 hollow spheres (UMTHS) with a high specific surface area (167.1 m(2) g(-1)) and improved conductivity were designed and applied as supports to disperse Pt nanoparticles (NPs) for the first time. Uniform Pt NPs (similar to 3.2 nm) on the surface of nanothorns were obtained after heat treatment. The as-prepared product (Pt/UMTHS) exhibited a more positive half-wave potential (E-h) than that of the reference sample Pt@C without UMTHS (0.867 V vs. 0.829 V). The improved performance can be ascribed to the high specific surface area of UMTHS. The Pt/UMTHS also exhibited a much better ORR stability than the commercial Pt/C after long-term cycling at 0.6-1.0 V according to the comparison of E-h, mass activity and electrochemical surface area with Pt/C. The enhanced stability of Pt/UMTHS was mainly derived from the strong metal support interaction between Pt NPs and UMTHS, together with the spatial restriction and the anti-restriction provided by UMTHS.
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NANOSCALE
ISSN: 2040-3364
Year: 2020
Issue: 19
Volume: 12
Page: 10656-10663
7 . 7 9
JCR@2020
5 . 8 0 0
JCR@2023
ESI Discipline: PHYSICS;
ESI HC Threshold:115
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 18
SCOPUS Cited Count: 18
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: