• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

He, Suqiong (He, Suqiong.) [1] | Wu, Chuxin (Wu, Chuxin.) [2] | Sun, Zhen (Sun, Zhen.) [3] | Liu, Yang (Liu, Yang.) [4] | Hu, Rongtao (Hu, Rongtao.) [5] | Guan, Lunhui (Guan, Lunhui.) [6] | Zhan, Hongbing (Zhan, Hongbing.) [7] (Scholars:詹红兵)

Indexed by:

EI Scopus SCIE

Abstract:

In order to promote the commercial application of proton exchange membrane fuel cells, it is of great importance to develop Pt-based electrocatalysts with high activity and stability for the oxygen reduction reaction (ORR). Here, urchin-like mesoporous TiO2 hollow spheres (UMTHS) with a high specific surface area (167.1 m(2) g(-1)) and improved conductivity were designed and applied as supports to disperse Pt nanoparticles (NPs) for the first time. Uniform Pt NPs (similar to 3.2 nm) on the surface of nanothorns were obtained after heat treatment. The as-prepared product (Pt/UMTHS) exhibited a more positive half-wave potential (E-h) than that of the reference sample Pt@C without UMTHS (0.867 V vs. 0.829 V). The improved performance can be ascribed to the high specific surface area of UMTHS. The Pt/UMTHS also exhibited a much better ORR stability than the commercial Pt/C after long-term cycling at 0.6-1.0 V according to the comparison of E-h, mass activity and electrochemical surface area with Pt/C. The enhanced stability of Pt/UMTHS was mainly derived from the strong metal support interaction between Pt NPs and UMTHS, together with the spatial restriction and the anti-restriction provided by UMTHS.

Keyword:

Community:

  • [ 1 ] [He, Suqiong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Sun, Zhen]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [He, Suqiong]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China
  • [ 5 ] [Wu, Chuxin]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China
  • [ 6 ] [Sun, Zhen]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China
  • [ 7 ] [Liu, Yang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China
  • [ 8 ] [Hu, Rongtao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China
  • [ 9 ] [Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China

Reprint 's Address:

  • 詹红兵

    [Zhan, Hongbing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350114, Fujian, Peoples R China

Show more details

Related Keywords:

Related Article:

Source :

NANOSCALE

ISSN: 2040-3364

Year: 2020

Issue: 19

Volume: 12

Page: 10656-10663

7 . 7 9

JCR@2020

5 . 8 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:115

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 18

SCOPUS Cited Count: 18

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:516/10844097
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1