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author:

Jiang, Zhipeng (Jiang, Zhipeng.) [1] | Zeng, Ziqi (Zeng, Ziqi.) [2] | Yang, Chengkai (Yang, Chengkai.) [3] | Han, Zhilong (Han, Zhilong.) [4] | Hu, Wei (Hu, Wei.) [5] | Lu, Jing (Lu, Jing.) [6] | Xie, Jia (Xie, Jia.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Practical applications of lithium metal anodes are gravely impeded by inhomogeneous lithium deposition, which results in dendrite growth. Electrolyte additives are proven to be effective in improving performance but usually serve only a single function. Herein, nitrofullerene is introduced as a bifunctional additive with a smoothing effect and forms a protective solid electrolyte interphase (SEI) layer on stable lithium metal anodes. By design, nitro-C-60 can gather on electrode protuberances via electrostatic interactions and then be reduced to NO2- and insoluble Co-60. Next, the C-60 anchors on the uneven groove of the lithium surface, resulting in a homogeneous distribution of Li ions. Finally, NO2- anions can react with metallic Li to build a compact and stable SEI with high ion transport. With a 5 mM nitro-C-60 additive, Li-Li symmetric cells show superior cycle stability in both carbonate and ether electrolytes, Li-sulfur batteries with a high cathode loading (10.6 mg cm(-2), 6 mAh cm(-2)) can achieve improved cycle retention of 63.2% over 100 cycles in a carbonate electrolyte, and full cells paired with a high-areal-capacity LiNi0.6Co0.2Mn0.2O2 cathode (3.5 mAh cm(-2)) exhibit a significantly enhanced cycle lifespan even under lean electrolyte

Keyword:

additive battery bifunction Fullerene lithium metal anode

Community:

  • [ 1 ] [Jiang, Zhipeng]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 2 ] [Zeng, Ziqi]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 3 ] [Han, Zhilong]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 4 ] [Hu, Wei]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 5 ] [Xie, Jia]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 6 ] [Jiang, Zhipeng]Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & & Mould Technol, Wuhan 430074, Hubei, Peoples R China
  • [ 7 ] [Yang, Chengkai]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Lu, Jing]Peking Univ, Sch Phys, Beijing 100871, Peoples R China

Reprint 's Address:

  • [Xie, Jia]Huazhong Univ Sci & Technol, Sch Elect & Elect Engn, State Key Lab Adv Electromagnet Engn & Technol, Wuhan 430074, Hubei, Peoples R China

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Source :

NANO LETTERS

ISSN: 1530-6984

Year: 2019

Issue: 12

Volume: 19

Page: 8780-8786

1 1 . 2 3 8

JCR@2019

9 . 6 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 92

SCOPUS Cited Count: 93

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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