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author:

Li, Zhanjiang (Li, Zhanjiang.) [1] | Liu, Xiaoqiang (Liu, Xiaoqiang.) [2] | Guo, Keke (Guo, Keke.) [3] | Wang, Hao (Wang, Hao.) [4] | Cai, Bingjie (Cai, Bingjie.) [5] | Chang, Fa (Chang, Fa.) [6] | Hong, Chunfu (Hong, Chunfu.) [7] | Dai, Pinqiang (Dai, Pinqiang.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

The FeCoCrNiAl high-entropy alloys (HEA) was used as binder of the Ti(C, N)-TiB2 composite cermets. The Ti(C, N)-TiB2-FeCoCrNiAl HEA composite cermets were successfully fabricated by mechanical alloying (MA) and vacuum hot-pressing sintering (VHPS) at different sintering temperatures. The microstructure, room-temperature hardness, fracture toughness, bending strength, high-temperature hardness and oxidation behavior were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Vickers hardness testing, indentation method, three point bending method, high-temperature vacuum hardness testing and cyclic oxidation. For the Ti(C, N)-TiB2-HEA composite cermets, apart from Ti(C, N) and TiB2 phases, also a minority Fe2B were detected in the XRD patterns. TEM observation revealed that the structure of the HEA binder was a solid solution where the Ti(C, N) and TiB2 were tightly bound. The Ti(C, N)-TiB2 composite cermets with a Ni/Co binder was selected as a reference. The experimental results indicated that the composite cermets with the HEA binder possesses excellent oxidation resistance. This is attributed to the formation of a continuous and dense external oxide scale and TiO2 layer that effectively impede inward oxygen transport, which leads to a remarkable improvement in the oxidation resistance. The Ti(C, N)-TiB2-HEA composite cermets sintered at 1500 degrees C showed excellent fracture toughness of 7.9 +/- 0.1 MPa.m(1/2). And the Ti(C, N)-TiB2-HEA composite cermets sintered at 1550 degrees C showed excellent hardness and bending strength of 1977.3 +/- 20 HV10 and 768.6 +/- 20 MPa, respectively. The high-temperature hardness of the HEA binder composite cermets was 993.7 +/- 30 EIV20, which was superior to the Ni/Co binder value of 668.1 +/- 30 HV20 at 1000 degrees C.

Keyword:

FeCoCrNiAl high-entropy alloys High-temperature properties Microstructure Room-temperature properties Ti(C, N)-TiB2-HEA composite cermets

Community:

  • [ 1 ] [Li, Zhanjiang]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 2 ] [Liu, Xiaoqiang]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 3 ] [Cai, Bingjie]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 4 ] [Chang, Fa]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 5 ] [Hong, Chunfu]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 6 ] [Dai, Pinqiang]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China
  • [ 7 ] [Li, Zhanjiang]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Liu, Xiaoqiang]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Cai, Bingjie]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Chang, Fa]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Hong, Chunfu]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Dai, Pinqiang]Fujian Prov Key Lab New Mat Preparat & Forming Te, Fuzhou 350108, Fujian, Peoples R China
  • [ 13 ] [Guo, Keke]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 14 ] [Wang, Hao]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China
  • [ 15 ] [Dai, Pinqiang]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 戴品强

    [Dai, Pinqiang]Fujian Univ Technol, Coll Mat Sci & Engn, Fuzhou 350118, Fujian, Peoples R China

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Source :

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING

ISSN: 0921-5093

Year: 2019

Volume: 767

4 . 6 5 2

JCR@2019

6 . 1 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 39

SCOPUS Cited Count: 43

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

Online/Total:146/10019029
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