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author:

Li, Zhanjiang (Li, Zhanjiang.) [1] | Liu, Xiaoqiang (Liu, Xiaoqiang.) [2] | Guo, Keke (Guo, Keke.) [3] | Wang, Hao (Wang, Hao.) [4] | Cai, Bingjie (Cai, Bingjie.) [5] | Chang, Fa (Chang, Fa.) [6] | Hong, Chunfu (Hong, Chunfu.) [7] | Dai, Pinqiang (Dai, Pinqiang.) [8]

Indexed by:

EI

Abstract:

The FeCoCrNiAl high-entropy alloys (HEA) was used as binder of the Ti(C, N)–TiB2 composite cermets. The Ti(C, N)–TiB2–FeCoCrNiAl HEA composite cermets were successfully fabricated by mechanical alloying (MA) and vacuum hot-pressing sintering (VHPS) at different sintering temperatures. The microstructure, room-temperature hardness, fracture toughness, bending strength, high-temperature hardness and oxidation behavior were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Vickers hardness testing, indentation method, three point bending method, high-temperature vacuum hardness testing and cyclic oxidation. For the Ti(C, N)–TiB2-HEA composite cermets, apart from Ti(C, N) and TiB2 phases, also a minority Fe2B were detected in the XRD patterns. TEM observation revealed that the structure of the HEA binder was a solid solution where the Ti(C, N) and TiB2 were tightly bound. The Ti(C, N)–TiB2 composite cermets with a Ni/Co binder was selected as a reference. The experimental results indicated that the composite cermets with the HEA binder possesses excellent oxidation resistance. This is attributed to the formation of a continuous and dense external oxide scale and TiO2 layer that effectively impede inward oxygen transport, which leads to a remarkable improvement in the oxidation resistance. The Ti(C, N)–TiB2-HEA composite cermets sintered at 1500 °C showed excellent fracture toughness of 7.9 ± 0.1 MPa.m1/2. And the Ti(C, N)–TiB2-HEA composite cermets sintered at 1550 °C showed excellent hardness and bending strength of 1977.3 ± 20 HV10 and 768.6 ± 20 MPa, respectively. The high-temperature hardness of the HEA binder composite cermets was 993.7 ± 30 HV20, which was superior to the Ni/Co binder value of 668.1 ± 30 HV20 at 1000 °C. © 2019 Elsevier B.V.

Keyword:

Aluminum alloys Aluminum metallography Bending strength Cermets Chromium alloys Chromium metallography Entropy Fracture testing Fracture toughness High-entropy alloys High resolution transmission electron microscopy High temperature properties Hot pressing Microstructure Oxidation resistance Oxide minerals Scale (deposits) Scanning electron microscopy Sintering Titanium dioxide Titanium metallography Vickers hardness Vickers hardness testing

Community:

  • [ 1 ] [Li, Zhanjiang]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 2 ] [Li, Zhanjiang]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 3 ] [Liu, Xiaoqiang]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 4 ] [Liu, Xiaoqiang]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 5 ] [Guo, Keke]School of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 6 ] [Wang, Hao]School of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China
  • [ 7 ] [Cai, Bingjie]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 8 ] [Cai, Bingjie]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 9 ] [Chang, Fa]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 10 ] [Chang, Fa]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 11 ] [Hong, Chunfu]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 12 ] [Hong, Chunfu]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 13 ] [Dai, Pinqiang]College of Materials Science and Engineering, Fujian University of Technology, Fuzhou; 350118, China
  • [ 14 ] [Dai, Pinqiang]Fujian Provincial Key Laboratory of New Material Preparation and Forming Technology, Fuzhou; 350108, China
  • [ 15 ] [Dai, Pinqiang]School of Materials Science and Engineering, Fuzhou University, Fuzhou; 350116, China

Reprint 's Address:

  • [dai, pinqiang]school of materials science and engineering, fuzhou university, fuzhou; 350116, china;;[dai, pinqiang]college of materials science and engineering, fujian university of technology, fuzhou; 350118, china;;[dai, pinqiang]fujian provincial key laboratory of new material preparation and forming technology, fuzhou; 350108, china

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Source :

Materials Science and Engineering A

ISSN: 0921-5093

Year: 2019

Volume: 767

4 . 6 5 2

JCR@2019

6 . 1 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 42

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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