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author:

Yang, Fuqiang (Yang, Fuqiang.) [1] (Scholars:阳富强) | Cai, Yilun (Cai, Yilun.) [2] | Huang, Xianyu (Huang, Xianyu.) [3]

Indexed by:

CPCI-S Scopus SCIE

Abstract:

To better reveal the pore structures and adsorption characteristics of iron sulfide ores after the mechanical activation, the raw sulfur-rich ore obtained from a sulfide mine was activated into several samples under different billing conditions. Both the scanning electron microscopy (SEM) and low-temperature N-2 gas adsorption/desorption (LT-N(2)GA) methods were used to understand the features of the pore structures, such as the pore volume, specific surface area (SSA), and pore size distribution (PSD). Moreover, the Frenkel-Halsey-Hill (FHH) model was applied to determine corresponding fractal dimensions. The research results indicate that the N-2 adsorption of the activated samples mostly takes place in the mesopores ranging from 2 to 30 nm. The change order of the SSA and pore volume for the activated samples with different sample-ball ratios is as follows: a (1:2)< b (1:4)< c (1:6); and that with diverse milling rates is as follows: d (200 r/min)< e (400 r/min)< f (600 r/min). The transformations in the fractal dimensions agree with those in SSA and pore volume development, while the alterations are on the contrary in average pore diameter. The mechanical activation can increase the fractal dimensions of iron sulfide samples and alters their oxygen adsorption properties, so it promotes the tendency of iron sulfide ores to oxidation and spontaneous combustion.

Keyword:

Fractal dimension Iron sulfide ores Low temperature nitrogen adsorption Mechanical activation Spontaneous combustion

Community:

  • [ 1 ] [Yang, Fuqiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Cai, Yilun]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Huang, Xianyu]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 阳富强

    [Yang, Fuqiang]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Fujian, Peoples R China

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Source :

ARABIAN JOURNAL OF GEOSCIENCES

ISSN: 1866-7511

Year: 2019

Issue: 22

Volume: 12

1 . 3 2 7

JCR@2019

1 . 8 2 7

JCR@2020

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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