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author:

Sun, Haiqin (Sun, Haiqin.) [1] | Lv, Yang (Lv, Yang.) [2] | Zhu, Yan (Zhu, Yan.) [3] | Lin, Jinfeng (Lin, Jinfeng.) [4] | Wu, Xiao (Wu, Xiao.) [5] (Scholars:吴啸) | Zhang, Qiwei (Zhang, Qiwei.) [6] | Hao, Xihong (Hao, Xihong.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

The (K0.5Na0.5)(0.95)Li0.05Nb0.95Bi0.05O3-1mol% Er2O3 transparent ceramics were prepared by a pressureless sintering method. The fabricated transparent ceramics not only exhibit high optical transmittance (85.3%) due to dense microstructure (nanoscale size grains), but also show the photochromism-induced light scattering and reversible upconversion (UC)-switching properties by visible light irradiation. Upon 407 nm light irradiation, the optical transmittance intensity is significantly decreased, showing a strong light scattering (Delta Abs = 28.3%). The light scatting degree can be quantitatively reflected by Er3+ ion UC emission, and could be recovered to its initial optical transmittance based on photochromic reactions. Meanwhile, the transparent ceramic is found to maintain good energy storage properties with higher W (5.87 J/cm(3)) and W-rec (1.96 J/cm(3)) under a higher electric field of 260 kV/cm. These results suggest that Er3+ doped (K0.5Na0.5)NbO3 transparent ceramics are promising for the modulation of light scattering and the design of photoelectric multifunction devices.

Keyword:

energy storage properties lead-free transparent ceramics light scattering photochromic behavior upconversion emission

Community:

  • [ 1 ] [Sun, Haiqin]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China
  • [ 2 ] [Lv, Yang]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China
  • [ 3 ] [Zhu, Yan]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China
  • [ 4 ] [Zhang, Qiwei]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China
  • [ 5 ] [Hao, Xihong]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China
  • [ 6 ] [Lin, Jinfeng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou, Fujian, Peoples R China
  • [ 7 ] [Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou, Fujian, Peoples R China
  • [ 8 ] [Zhang, Qiwei]Inner Mongolia Univ Sci & Technol, Key Lab Integrated Exploitat Bayan Obo Multimet R, Baotou, Peoples R China
  • [ 9 ] [Hao, Xihong]Inner Mongolia Univ Sci & Technol, Key Lab Integrated Exploitat Bayan Obo Multimet R, Baotou, Peoples R China

Reprint 's Address:

  • 吴啸

    [Zhang, Qiwei]Inner Mongolia Univ Sci & Technol, Sch Mat & Met, Inner Mongolia Key Lab Ferroelect Related New Ene, Baotou, Peoples R China;;[Wu, Xiao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou, Fujian, Peoples R China

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Source :

JOURNAL OF THE AMERICAN CERAMIC SOCIETY

ISSN: 0002-7820

Year: 2019

Issue: 11

Volume: 102

Page: 6732-6740

3 . 5 0 2

JCR@2019

3 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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