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The (K0.5Na0.5)(0.95)Li0.05Nb0.95Bi0.05O3-1mol% Er2O3 transparent ceramics were prepared by a pressureless sintering method. The fabricated transparent ceramics not only exhibit high optical transmittance (85.3%) due to dense microstructure (nanoscale size grains), but also show the photochromism-induced light scattering and reversible upconversion (UC)-switching properties by visible light irradiation. Upon 407 nm light irradiation, the optical transmittance intensity is significantly decreased, showing a strong light scattering (Delta Abs = 28.3%). The light scatting degree can be quantitatively reflected by Er3+ ion UC emission, and could be recovered to its initial optical transmittance based on photochromic reactions. Meanwhile, the transparent ceramic is found to maintain good energy storage properties with higher W (5.87 J/cm(3)) and W-rec (1.96 J/cm(3)) under a higher electric field of 260 kV/cm. These results suggest that Er3+ doped (K0.5Na0.5)NbO3 transparent ceramics are promising for the modulation of light scattering and the design of photoelectric multifunction devices.
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JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN: 0002-7820
Year: 2019
Issue: 11
Volume: 102
Page: 6732-6740
3 . 5 0 2
JCR@2019
3 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:236
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 27
SCOPUS Cited Count: 31
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
Affiliated Colleges: