Three　novel　carboxyarylphosphonate　polymers　{[Zn-2(PCP)(H2PCP)(phen)(2)]center　dot　H2O}(n)　(1),　[Zn(HPCP)(4,4　＇-bipy)](n)　(2),　and　[Zn-3(MCP)(2)(2,2　＇-bipy)](n)　(3)　[PCP3-　=　p-O2C(C6H4)CH2PO33-,　MCP3-　=　m-O2C(C6H4)CH2PO33-　and　phen　=　phenanthroline]　were　synthesized　and　characterized　by　single-crystal　X-ray　diffraction.　Compound　1　features　a　butterfly-shaped　dimer　consisting　of　[Zn4P4O10]　tetranuclear　units,　which　are　further　linked　by　hydrogen　bonds　and　pi-pi　stacking　interactions　into　a　3D　supramolecular　framework.　In　2,　there　is　an　infinite　P-O-Zn　inorganic　2D　(4,4)　layer　with　the　phosphonate　moieties　of　HPCP2-　and　unidentate　4,4　＇-bipy　ligands　vertically　sticking　out.　As　for　3,　the　novel　[Zn6P4O12]　hexanuclear　units　with　＂chair＂　conformation　are　tetrahedrally　bridged　by　eight　MCP3-　to　generate　a　2D　double-layer,　in　which　the　windows　are　occupied　by　2,2　＇-bipy　molecules.　Additionally,　2D　correlation　analysis　of　FTIR　with　thermal　perturbation　of　3　were　discussed.　Compounds　1-3　exhibit　intense　solid　state　fluorescent　emissions.　Thermogravimetric　analyses　suggested　the　very　high　stability.