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Abstract:
The title complex, [Zn(C18H12N2)(C8H4O4)](n), consists of a one-dimensional zigzag [Zn(tpa)(quin)](n) chain (tpa = terephthalate and quin = 2,2'-diquinolyl) with a pitch of 17.907 (2) angstrom. The tpa ligands bridge two Zn atoms in alternately bis(bidentate) and bis(monodentate) coordination modes. Each Zn atom is coordinated by two N atoms from a chelating quin, two O atoms from one bis(bidentate) tpa and one O atom from one bis(monodentate) tpa. The five-coordinate Zn geometry can be best described as distorted trigonal-bipyramidal.
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ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
ISSN: 2056-9890
Year: 2006
Volume: 62
Page: M1048-M1050
0 . 5 0 0
JCR@2023
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