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Abstract:
Sodium/potassium-ion batteries (SIBs/PIBs) arouse intensive interest on account of the natural abundance of sodium/potassium resources, the competitive cost and appropriate redox potential. Nevertheless, the huge challenge for SIBs/PIBs lies in the scarcity of an anode material with high capacity and stable structure, which are capable of accommodating large-size ions during cycling. Furthermore, using sustainable natural biomass to fabricate electrodes for energy storage applications is a hot topic. Herein, an ultra-small few-layer nanostructured MoSe2 embedded on N, P co-doped bio-carbon is reported, which is synthesized by using chlorella as the adsorbent and precursor. As a consequence, the MoSe2/NP-C-2 composite represents exceedingly impressive electrochemical performance for both sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs). It displays a promising reversible capacity (523 mAh g(-1) at 100 mA g(-1) after 100 cycles) and impressive long-term cycling performance (192 mAh g(-1) at 5 A g(-1) even after 1000 cycles) in SIBs, which are some of the best properties of MoSe2-based anode materials for SIBs to date. To further probe the great potential applications, full SIBs pairing the MoSe2/NP-C-2 composite anode with a Na3V2(PO4)(3) cathode also exhibits a satisfactory capacity of 215 mAh g(-1) at 500 mA g(-1) after 100 cycles. Moreover, it also delivers a decent reversible capacity of 131 mAh g(-1) at 1 A g(-1) even after 250 cycles for PIBs.
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CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539
Year: 2019
Issue: 58
Volume: 25
Page: 13411-13421
4 . 8 5 7
JCR@2019
3 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:1
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 63
SCOPUS Cited Count: 64
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: