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author:

Lu, Kang-Qiang (Lu, Kang-Qiang.) [1] | Qi, Ming-Yu (Qi, Ming-Yu.) [2] | Tang, Zi-Rong (Tang, Zi-Rong.) [3] (Scholars:唐紫蓉) | Xu, Yi-Jun (Xu, Yi-Jun.) [4] (Scholars:徐艺军)

Indexed by:

EI Scopus SCIE

Abstract:

Cocatalysts play a significant role in accelerating the catalytic reactions of semiconductor photocatalyst. In particular, a semiconductor assembled with dual cocatalysts, i.e., reduction and oxidation cocatalysts, can obviously enhance the photocatalytic performance because of the synergistic effect of fast consumption of photogenerated electrons and holes simultaneously. However, in most cases, noble metal cocatalysts are employed, which tremendously increases the cost of the photocatalysts and restricts their large-scale applications. Herein, on the platform of one-dimensional (1D) CdS nanowires, we have utilized the earth abundant dual cocatalysts, MoS2 and cobalt phosphate (Co-Pi), to construct the CdS@MoS2@Co Pi (CMC) core-shell hybrid photocatalysts. In this dual-cocatalyst system, a position to expedite the migration of holes from CdS, while MoS2 acts as an electron transporter as well as active sites to accelerate the surface water reduction reaction. Taking the advantages of the dual-cocatalyst system, the prepared CMC hybrid shows an obvious enhancement of both the photoactivity and photostability toward hydrogen production compared with bare 1D CdS nanowires and binary hybrids (CdS@MoS2 and CdS@Co-Pi). This work highlights the promising prospects for rational utilization of earth-abundant dual cocatalysts to design low-cost and efficient hybrids toward boosting photoredox catalysis.

Keyword:

Community:

  • [ 1 ] [Lu, Kang-Qiang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Qi, Ming-Yu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Lu, Kang-Qiang]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Qi, Ming-Yu]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Tang, Zi-Rong]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China
  • [ 7 ] [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 徐艺军

    [Xu, Yi-Jun]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350116, Fujian, Peoples R China;;[Xu, Yi-Jun]Fuzhou Univ, Coll Chem, New Campus, Fuzhou 350116, Fujian, Peoples R China

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Source :

LANGMUIR

ISSN: 0743-7463

Year: 2019

Issue: 34

Volume: 35

Page: 11056-11065

3 . 5 5 7

JCR@2019

3 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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