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author:

Chen, Jie (Chen, Jie.) [1] (Scholars:陈杰) | Yan, Wei (Yan, Wei.) [2] | Townsend, Esther J. (Townsend, Esther J..) [3] | Feng, Jiangtao (Feng, Jiangtao.) [4] | Pan, Long (Pan, Long.) [5] | Hernandez, Veronica Del Angel (Hernandez, Veronica Del Angel.) [6] | Faul, Charl F. J. (Faul, Charl F. J..) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Simple inorganic salts are used to tune N-containing conjugated microporous polymers (CMPs) synthesized by Buchwald-Hartwig (BH) cross-coupling reactions. Poly(triphenylamine), PTPA, initially shows a broad distribution of micropores, mesopores, and macropores. However, the addition of inorganic salts affects all porous network properties significantly: the pore size distribution is narrowed to the microporous range only, mimicking COFs and MOFs; the BET surface area is radically improved from 58 m(2) g(-1) to 1152 m(2) g(-1); and variations of the anion and cation sizes are used to fine-tune the surface area of PTPA, with the surface area showing a gradual decrease with an increase in the ionic radius of salts. The effect of the salt on the physical properties of the polymer is attributed to adjusting and optimizing the Hansen solubility parameters (HSPs) of solvents for the growing polymer, and named the Beijing-Xi'an Jiaotong (BXJ) method.

Keyword:

conjugated microporous polymers Hansen solubility parameters metal-catalyzed cross-couplings tunable properties

Community:

  • [ 1 ] [Chen, Jie]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian 710049, Shaanxi, Peoples R China
  • [ 2 ] [Yan, Wei]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian 710049, Shaanxi, Peoples R China
  • [ 3 ] [Feng, Jiangtao]Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian 710049, Shaanxi, Peoples R China
  • [ 4 ] [Chen, Jie]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
  • [ 5 ] [Townsend, Esther J.]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
  • [ 6 ] [Pan, Long]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
  • [ 7 ] [Hernandez, Veronica Del Angel]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
  • [ 8 ] [Faul, Charl F. J.]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
  • [ 9 ] [Chen, Jie]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Fujian, Peoples R China
  • [ 10 ] [Townsend, Esther J.]Univ Bristol, Bristol Ctr Funct Nanomat, Bristol BS8 1TL, Avon, England

Reprint 's Address:

  • [Faul, Charl F. J.]Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

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Related Keywords:

Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2019

Issue: 34

Volume: 58

Page: 11715-11719

1 2 . 9 5 9

JCR@2019

1 6 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 151

SCOPUS Cited Count: 126

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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