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author:

Kailasam, Kamalakannan (Kailasam, Kamalakannan.) [1] | Schmidt, Johannes (Schmidt, Johannes.) [2] | Bildirir, Hakan (Bildirir, Hakan.) [3] | Zhang, Guigang (Zhang, Guigang.) [4] (Scholars:张贵刚) | Blechert, Siegfried (Blechert, Siegfried.) [5] | Wang, Xinchen (Wang, Xinchen.) [6] (Scholars:王心晨) | Thomas, Arne (Thomas, Arne.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Two emerging material classes are combined in this work, namely polymeric carbon nitrides and microporous polymer networks. The former, polymeric carbon nitrides, are composed of amine-bridged heptazine moieties and showed interesting performance as a metal-free photocatalyst. These materials have, however, to be prepared at high temperatures, making control of their chemical structure difficult. The latter, microporous polymer networks have received increasing interest due to their high surface area, giving rise to interesting applications in gas storage or catalysis. Here, the central building block of carbon nitrides, a functionalized heptazine as monomer, and tecton are used to create microporous polymer networks. The resulting heptazine-based microporous polymers show high porosity, while their chemical structure resembles the ones of carbon nitrides. The polymers show activity for the photocatalytic production of hydrogen from water, even under visible light illumination.

Keyword:

conjugated microporous polymers covalent organic frameworks graphitic carbon nitride heptazine photocatalytic water splitting

Community:

  • [ 1 ] [Kailasam, Kamalakannan]Tech Univ Berlin, Dept Chem Funct Mat, D-10623 Berlin, Germany
  • [ 2 ] [Schmidt, Johannes]Tech Univ Berlin, Dept Chem Funct Mat, D-10623 Berlin, Germany
  • [ 3 ] [Bildirir, Hakan]Tech Univ Berlin, Dept Chem Funct Mat, D-10623 Berlin, Germany
  • [ 4 ] [Thomas, Arne]Tech Univ Berlin, Dept Chem Funct Mat, D-10623 Berlin, Germany
  • [ 5 ] [Zhang, Guigang]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 6 ] [Wang, Xinchen]Fuzhou Univ, State Key Lab Breeding Base, Fujian Prov Key Lab Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
  • [ 7 ] [Zhang, Guigang]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 8 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 9 ] [Blechert, Siegfried]Tech Univ Berlin, Dept Chem Organ Chem, D-10623 Berlin, Germany

Reprint 's Address:

  • [Kailasam, Kamalakannan]Tech Univ Berlin, Dept Chem Funct Mat, Hardenbergstr 40, D-10623 Berlin, Germany

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Source :

MACROMOLECULAR RAPID COMMUNICATIONS

ISSN: 1022-1336

Year: 2013

Issue: 12

Volume: 34

Page: 1008-1013

4 . 6 0 8

JCR@2013

4 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 129

SCOPUS Cited Count: 129

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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