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Abstract:
A novel ketone-functionalized carbazolic porous framework named PBPMCz is presentedfor fluorometric determination of p-nitroaniline (PNA). PBPMCz was prepared by FeCl3-promoted oxidative coupling polymerization of 1,3,5-tris((4-(9H-carbazol-9-yl)phenyl)methanone-1-yl)benzene. The polymer possesses a BET surface area ofabove 907 m(2).g(-1) with a pore volume of 0.72cm(3).g(-1). Compared to the ketone-free framework, the green fluorescence of the probe PBPMCz is more strongly quenched by PNA. Figures of merit include (a) excitation/emission wavelengths of 366/540nm; (b) a Stern-Volmer constant (K-sv) of 2.2x10(4)M(-1), and (c) a detection limit of 1.1M. Furthermore, PBPMCz shows different quenching behaviors of PNA compared with o-nitroaniline and m-nitroaniline. The excellent performance of the fluorescent probe is ascribed to the abundant carbazole sites and ketone groups in PBPMCz. These facilitate the electron transfer and hydrogen-bonding interactions between PNA and the polymer. [GRAPHICS]
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MICROCHIMICA ACTA
ISSN: 0026-3672
Year: 2019
Issue: 7
Volume: 186
6 . 2 3 2
JCR@2019
5 . 4 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:184
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 17
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0