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author:

Qian, Li (Qian, Li.) [1] | Hong, Haitao (Hong, Haitao.) [2] | Han, Mingxi (Han, Mingxi.) [3] | Xu, Congying (Xu, Congying.) [4] | Wang, Song (Wang, Song.) [5] | Guo, Zhiyong (Guo, Zhiyong.) [6] (Scholars:郭智勇) | Yan, Dan (Yan, Dan.) [7] (Scholars:燕丹)

Indexed by:

Scopus SCIE

Abstract:

A novel ketone-functionalized carbazolic porous framework named PBPMCz is presentedfor fluorometric determination of p-nitroaniline (PNA). PBPMCz was prepared by FeCl3-promoted oxidative coupling polymerization of 1,3,5-tris((4-(9H-carbazol-9-yl)phenyl)methanone-1-yl)benzene. The polymer possesses a BET surface area ofabove 907 m(2).g(-1) with a pore volume of 0.72cm(3).g(-1). Compared to the ketone-free framework, the green fluorescence of the probe PBPMCz is more strongly quenched by PNA. Figures of merit include (a) excitation/emission wavelengths of 366/540nm; (b) a Stern-Volmer constant (K-sv) of 2.2x10(4)M(-1), and (c) a detection limit of 1.1M. Furthermore, PBPMCz shows different quenching behaviors of PNA compared with o-nitroaniline and m-nitroaniline. The excellent performance of the fluorescent probe is ascribed to the abundant carbazole sites and ketone groups in PBPMCz. These facilitate the electron transfer and hydrogen-bonding interactions between PNA and the polymer. [GRAPHICS]

Keyword:

Carbazolic porous framework Detection limit Electron transfer Fluorescence sensing Nitroaniline isomers Oxidative coupling Quenching mechanism

Community:

  • [ 1 ] [Qian, Li]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Hong, Haitao]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Han, Mingxi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Xu, Congying]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Guo, Zhiyong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Wang, Song]Hubei Univ Arts & Sci, Hubei Key Lab Low Dimens Optoelect Mat & Devices, Xiangyang 441053, Hubei, Peoples R China
  • [ 7 ] [Yan, Dan]Fuzhou Univ, Testing Ctr, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 郭智勇 燕丹

    [Guo, Zhiyong]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Yan, Dan]Fuzhou Univ, Testing Ctr, Fuzhou 350108, Fujian, Peoples R China

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Source :

MICROCHIMICA ACTA

ISSN: 0026-3672

Year: 2019

Issue: 7

Volume: 186

6 . 2 3 2

JCR@2019

5 . 4 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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