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author:

Liu, Jing-Jing (Liu, Jing-Jing.) [1] | Chen, Zhi-Tao (Chen, Zhi-Tao.) [2] | Tang, Duo-Si (Tang, Duo-Si.) [3] | Wang, Yao-Bing (Wang, Yao-Bing.) [4] | Kang, Long-Tian (Kang, Long-Tian.) [5] | Yao, Jian-Nian (Yao, Jian-Nian.) [6]

Indexed by:

EI Scopus SCIE

Abstract:

A simple graphene quantum dots (GQDs)-based fluorescence sensing system was developed for rapid, sensitive and low-cost detection of ascorbic acid (AA) in the presence of copper ions. Due to the efficient electron-transfer between GQDs and Cu2+ ions, the fluorescence of GQDs was greatly quenched by Cu2+ ions. Upon addition of ascorbic acid, Cu2+ was reduced to Cu+ and the interaction of Cu2+-GQDs was destroyed, which inhibit the quenching and thus leading to fluorescence recovery of GQDs. The detection process is ultrafast and can be completed within 5 min. The linear response range of AA was obtained from 0.3 mu M to 10 mu M. The detection limit was as low as 94 nM, which was comparable to or even better than other reported assays. In addition, this sensing system also showed good selectivity for detecting AA in the presence of different physiological molecules and inorganic ions. Finally, the proposed sensing system was successfully applied to assay AA in real samples with satisfactory results. (C) 2015 Elsevier B.V. All rights reserved.

Keyword:

Ascorbic acid Copper ions Fluorescence turn on Graphene quantum dots Sensor

Community:

  • [ 1 ] [Liu, Jing-Jing]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 2 ] [Tang, Duo-Si]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang, Yao-Bing]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Kang, Long-Tian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Liu, Jing-Jing]Chinese Acad Sci, Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 6 ] [Wang, Yao-Bing]Chinese Acad Sci, Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 7 ] [Kang, Long-Tian]Chinese Acad Sci, Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
  • [ 8 ] [Chen, Zhi-Tao]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 9 ] [Tang, Duo-Si]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350002, Peoples R China
  • [ 10 ] [Chen, Zhi-Tao]Fuqing Entry Exit Inspect & Quarantine Bur, Fuqing 350300, Fujian, Peoples R China
  • [ 11 ] [Yao, Jian-Nian]Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China

Reprint 's Address:

  • [Kang, Long-Tian]Chinese Acad Sci, Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China

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Source :

SENSORS AND ACTUATORS B-CHEMICAL

ISSN: 0925-4005

Year: 2015

Volume: 212

Page: 214-219

4 . 7 5 8

JCR@2015

8 . 0 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 127

SCOPUS Cited Count: 131

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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