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author:

He, Qian (He, Qian.) [1] | Li, Shuolin (Li, Shuolin.) [2] | Huang, Shaowei (Huang, Shaowei.) [3] | Xiao, Longqiang (Xiao, Longqiang.) [4] (Scholars:肖龙强) | Hou, Linxi (Hou, Linxi.) [5] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

The development of highly efficient electrocatalysts has attracted increasing attention in the field of electrochemical energy conversion. Therefore, we report a simple self-template method to construct Co-Sn-X (X = S, Se, Te) nanocages through the anion exchange reaction of CoSn(OH)(6) nanocubes with chalcogenide ions under mild solvothermal conditions. Benefiting from advantageous compositional features and well-designed architectures, the obtained Co-Sn-X (X = S, Se, Te) nanocages display enhanced electrocatalytic activity for dye-sensitized solar cells (DSSCs) and the oxygen evolution reaction (OER) in an alkaline electrolyte. Remarkably, the Co-Sn-Se nanocages as the counter electrode (CE) catalyst deliver a prominent power conversion efficiency (PCE) of 9.25% for DSSCs compared with Pt CE (8.19%). Furthermore, when used as an OER catalyst, the Co-Sn-Se nanocages also exhibit outstanding electrocatalytic activity in terms of their low overpotential of 304 mV at the current density of 10 mA cm(-2) and long-term stability in 1.0 M KOH solution. This work provides wide prospects for the rational design and synthesis of high-performance transition metal chalcogenide-based electrocatalysts for future energy conversion systems.

Keyword:

Community:

  • [ 1 ] [He, Qian]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Li, Shuolin]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Huang, Shaowei]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 肖龙强 侯琳熙

    [Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China;;[Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Xueyuan Rd 2, Fuzhou 350116, Fujian, Peoples R China

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Source :

NANOSCALE

ISSN: 2040-3364

Year: 2018

Issue: 46

Volume: 10

Page: 22012-22024

6 . 9 7

JCR@2018

5 . 8 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:158

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 27

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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