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The development of highly efficient electrocatalysts has attracted increasing attention in the field of electrochemical energy conversion. Therefore, we report a simple self-template method to construct Co-Sn-X (X = S, Se, Te) nanocages through the anion exchange reaction of CoSn(OH)(6) nanocubes with chalcogenide ions under mild solvothermal conditions. Benefiting from advantageous compositional features and well-designed architectures, the obtained Co-Sn-X (X = S, Se, Te) nanocages display enhanced electrocatalytic activity for dye-sensitized solar cells (DSSCs) and the oxygen evolution reaction (OER) in an alkaline electrolyte. Remarkably, the Co-Sn-Se nanocages as the counter electrode (CE) catalyst deliver a prominent power conversion efficiency (PCE) of 9.25% for DSSCs compared with Pt CE (8.19%). Furthermore, when used as an OER catalyst, the Co-Sn-Se nanocages also exhibit outstanding electrocatalytic activity in terms of their low overpotential of 304 mV at the current density of 10 mA cm(-2) and long-term stability in 1.0 M KOH solution. This work provides wide prospects for the rational design and synthesis of high-performance transition metal chalcogenide-based electrocatalysts for future energy conversion systems.
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NANOSCALE
ISSN: 2040-3364
Year: 2018
Issue: 46
Volume: 10
Page: 22012-22024
6 . 9 7
JCR@2018
5 . 8 0 0
JCR@2023
ESI Discipline: PHYSICS;
ESI HC Threshold:158
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count: 27
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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