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author:

Lin, Xiahui (Lin, Xiahui.) [1] | Chen, Hong (Chen, Hong.) [2] | Hu, Zhibiao (Hu, Zhibiao.) [3] | Hou, Yidong (Hou, Yidong.) [4] (Scholars:侯乙东) | Dai, Wenxin (Dai, Wenxin.) [5] (Scholars:戴文新)

Indexed by:

EI Scopus SCIE

Abstract:

TiO2 photocatalysis has been studied widely in environment protection and energy generation applications. But, the intrinsic absence of visible light response and the high recombination rate of photo-generated charge carriers significantly limited the efficiency of photocatalysis with TiO2 materials. Herein, a facile approach was constructed to develop visible-light-induced TiO2 photocatalysis by co-modification with Eu and Au nanoparticles. The synthesized Au/Eu-TiO2 material was characterized by XRD, SEM, TEM, DRS, XPS, and N-2 adsorption measurements. Visible light catalytic performance of the Au/Eu-TiO2 catalyst was evaluated by using the photodegradation of RhB as a model reaction. It was shown that this Au/Eu-TiO2 exhibited a better photocatalytic activity than the single Au modified TiO2 (Au/TiO2) or the single Eu modified TiO2 catalyst (Eu/TiO2), and also exhibited a good reusability for the targeted reaction. This remarkably improved performance of Au/EuTiO2 could be attributed to the synergetic effect of Eu and Au co-decoration, which not only enhanced visible light absorption but also promoted charge carriers transfers as evidenced by DRS, XPS and transient photo-current spectra. Moreover, a possible reaction mechanism for the Au/Eu-TiO2 photocatalysis was proposed.

Keyword:

Co-modification Electron transfer Synergetic effect TiO2 Visible light response

Community:

  • [ 1 ] [Lin, Xiahui]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Hou, Yidong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Dai, Wenxin]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Lin, Xiahui]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 5 ] [Chen, Hong]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 6 ] [Hu, Zhibiao]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China
  • [ 7 ] [Dai, Wenxin]Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 戴文新

    [Dai, Wenxin]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China;;[Hu, Zhibiao]Longyan Univ, Coll Chem & Mat Sci, Longyan 364012, Fujian, Peoples R China

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Source :

SOLID STATE SCIENCES

ISSN: 1293-2558

Year: 2018

Volume: 83

Page: 181-187

2 . 1 5 5

JCR@2018

3 . 4 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:158

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 33

SCOPUS Cited Count: 39

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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