• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Liang, Wenting (Liang, Wenting.) [1] | Li, Dan (Li, Dan.) [2] | Lau, Pui-Ling (Lau, Pui-Ling.) [3] | Xu, Linli (Xu, Linli.) [4] | Yang, Cheng (Yang, Cheng.) [5] | Wei, Mingdeng (Wei, Mingdeng.) [6] (Scholars:魏明灯) | Chan, Wesley Ting-Kwok (Chan, Wesley Ting-Kwok.) [7] | Wong, Wai-Yeung (Wong, Wai-Yeung.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

Treatment of [Os-3(CO) (10)(NCMe) (2)] with an equimolar amount of 4-vinylpyridine, 4-ethynylpyridine and 4-ethylpyridine at room temperature readily gave the cluster complexes [Os-3(mu-H)(CO)(10)(mu-NC5H3CH = CH2)] 1, [Os-3(mu-H)(CO)(10)(mu-NC5H3C= CH)](2) and [Os3(CO)(10)(mu-H)(mu-NC5H3CH2CH3)](3), respectively. The corresponding ruthenium analogue of 1, [Ru-3(mu-H)(CO)(10)(mu-NC5H3CH = CH2)] (4), was also prepared in good yield by thermal reaction of Ru-3(CO)(12) with 4-vinylpyridine. Then, five thermally stable polymer-immobilized clusters of osmium 5-9 have been synthesized by the solution copolymerization of triosmium cluster-based monomers 1 and 2 with styrene, methyl methacrylate, vinylferrocene and 4-vinylphenylboronic acid, respectively, in the presence of alpha,alpha'-azobis(isobutyronitrile) (AIBN) in chloroform at 60 degrees C. Characterization of all new compounds was achieved by a combination of FTIR, NMR, MS, GPC, electronic absorption and thermal gravimetric analysis techniques. Crystal structure determinations were also carried out for complexes 1, 3 and 4. (C) 2018 Elsevier B.V. All rights reserved.

Keyword:

Carbonyl clusters Copolymers Ferrocene Osmium Ruthenium

Community:

  • [ 1 ] [Liang, Wenting]Shanxi Univ, Dept Chem, Inst Environm Sci, Taiyuan 030006, Shanxi, Peoples R China
  • [ 2 ] [Li, Dan]Shanxi Univ, Dept Chem, Inst Environm Sci, Taiyuan 030006, Shanxi, Peoples R China
  • [ 3 ] [Lau, Pui-Ling]Hong Kong Baptist Univ, Inst Mol Funct Mat, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China
  • [ 4 ] [Wong, Wai-Yeung]Hong Kong Baptist Univ, Inst Mol Funct Mat, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China
  • [ 5 ] [Lau, Pui-Ling]Hong Kong Baptist Univ, Dept Chem, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China
  • [ 6 ] [Wong, Wai-Yeung]Hong Kong Baptist Univ, Dept Chem, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China
  • [ 7 ] [Xu, Linli]Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
  • [ 8 ] [Chan, Wesley Ting-Kwok]Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
  • [ 9 ] [Wong, Wai-Yeung]Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
  • [ 10 ] [Yang, Cheng]Sichuan Univ, Coll Chem, 29 Wangjiang Rd, Chengdu 610064, Sichuan, Peoples R China
  • [ 11 ] [Wei, Mingdeng]Fuzhou Univ, Inst Adv Mat, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 魏明灯

    [Liang, Wenting]Shanxi Univ, Dept Chem, Inst Environm Sci, Taiyuan 030006, Shanxi, Peoples R China;;[Wong, Wai-Yeung]Hong Kong Baptist Univ, Inst Mol Funct Mat, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China;;[Wong, Wai-Yeung]Hong Kong Baptist Univ, Dept Chem, Waterloo Rd, Hong Kong, Hong Kong, Peoples R China;;[Xu, Linli]Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China;;[Wei, Mingdeng]Fuzhou Univ, Inst Adv Mat, Fuzhou 350002, Fujian, Peoples R China

Show more details

Related Keywords:

Source :

JOURNAL OF ORGANOMETALLIC CHEMISTRY

ISSN: 0022-328X

Year: 2018

Volume: 870

Page: 8-15

2 . 0 6 6

JCR@2018

2 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:3

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Online/Total:237/10013893
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1