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author:

Shen, Jianchen (Shen, Jianchen.) [1] | Xu, Biping (Xu, Biping.) [2] | Zhang, Min (Zhang, Min.) [3] | Su, Weiping (Su, Weiping.) [4]

Indexed by:

Scopus SCIE

Abstract:

We describe the Pd-II-catalyzed decarboxylative Heck reaction of aromatic carboxylic acids with an array of electronically unbiased olefins, which allows regioselective formation of less common branched products in good yield. This protocol enables the use of inexpensive, stable, and readily available aromatic carboxylic acids as aryl reagents, thus providing an attractive method for the synthesis of useful -alkyl vinylarenes.

Keyword:

Decarboxylation Heck reaction Homogeneous catalysis Olefins Regioselectivity

Community:

  • [ 1 ] [Shen, Jianchen]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Shen, Jianchen]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Xu, Biping]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhang, Min]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Su, Weiping]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Zhang, Min]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China;;[Su, Weiping]Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Yangqiao West Rd 155, Fuzhou 350002, Fujian, Peoples R China

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Source :

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

ISSN: 1434-193X

Year: 2018

Issue: 22

Volume: 2018

Page: 2768-2773

3 . 0 2 9

JCR@2018

2 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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