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author:

Wang Jicheng (Wang Jicheng.) [1] | Yuan Yaofeng (Yuan Yaofeng.) [2] (Scholars:袁耀锋) | Zhuo Jibin (Zhuo Jibin.) [3] | Yang Sihan (Yang Sihan.) [4] | Lin Fen (Lin Fen.) [5]

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

Compounds 2a-2f were synthesized by the substitution reaction of 2-ferrocenyl-4,5-diphenylimi-dazole(1) with different halohydrocarbons. Then compounds 2a-2f were reacted with iodomethane to get compounds 3a-3f. Finally, compounds 3a-3f were exchanged anion with ammonium hexafluorophosphate to get compounds 4a-4f. All these compounds were structurally characterized by means of infrared(IR), mass spectrometry(MS), nuclear magnetic resonance(NMR), high-resolution mass spectrometry(HRMS) and X-ray crystal diffraction. Electrochemical properties of these compounds were studied by cyclic voltammetry(CV). Thermal behavior and catalytic performance for thermal decomposition of ammonium perchlorate(AP) were studied by thermogravimetric(TG) and differential scanning calorimetry(DSC). The results indicate that all the synthetic products have efficient catalytic effect on the thermal decomposition of AP. The iodized salts(3a-3f) indicate better catalytic effect than the hexafluorophosphate(4a-4f). The most outstanding compound is 3b, which makes the second decomposition stage of AP disappear, and the first stage is advanced to 270.5 degrees C. The novel dinuclear ferrocen-based imidazolium derivatives would have great value in preparing high-burning-rate catalyst for composite solid propellants.

Keyword:

Ammonium perchlorate Ferrocenyl derivative Imidazole Ionic liquid Thermal decomposition

Community:

  • [ 1 ] [Wang Jicheng]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Yuan Yaofeng]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Zhuo Jibin]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Yang Sihan]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Yuan Yaofeng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Lin Fen]Fuzhou Univ, Testing Ctr, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address:

  • 袁耀锋

    [Yuan Yaofeng]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China;;[Yuan Yaofeng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE

ISSN: 0251-0790

CN: 22-1131/O6

Year: 2018

Issue: 5

Volume: 39

Page: 889-896

0 . 6 7 6

JCR@2018

0 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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