• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Zhang, Yujuan (Zhang, Yujuan.) [1] | Li, Qiuzhong (Li, Qiuzhong.) [2] | Liu, Chunxia (Liu, Chunxia.) [3] | Shan, Xinggang (Shan, Xinggang.) [4] | Chen, Xun (Chen, Xun.) [5] (Scholars:陈旬) | Dai, Wenxin (Dai, Wenxin.) [6] (Scholars:戴文新) | Fu, Xianzhi (Fu, Xianzhi.) [7] (Scholars:付贤智)

Indexed by:

EI Scopus SCIE

Abstract:

A gold nanoparticle catalyst supported on the ZIF-8 (a metal-organic frameworks) modified TiO2 (Au/ZIT-8-TiO2) was prepared by self-assembly together with solvothermal and deposition-precipitation methods, which its performance of catalytic oxidizing CO was evaluated and compared with that of Au/TiO2 and Au/ZIF-8, respectively. It was found that the incorporation of ZIF-8 into Au/TiO2 could remarkably enhance the catalytic activity of Au/TiO2 both in dark and under visible light irradiation. The characterization result of Au/ZIF-8-TiO2 showed that the sheet of ZIF-8 was distributed on the surface of TiO2 microspheres to enhance the surface roughness of TiO2, which could effectively limit the migration and aggregation of Au nanoparticles (i.e., enhancing the dispersion of Au nanoparticles at support) due to its large surface area and porousness. Moreover, Au/ZIF-8-TiO2 owned a higher surface electron density of both Au nanoparticles and TiO2 as compared to Au/TiO2. It is proposed that ZIF-8 with abundant delocalized electrons of st bond could act as an electron donor for TiO2 and Au in the structure of Au/ZIF-8-TiO2, but it act as an electron transfer mediator to promote the electron transfer between Au and TiO2 induced by the localized surface plasmon resonance of Au nanoparticles under visible light irradiation. These behaviors would promote the adsorption and activation of CO and O-2 at Au or TiO2 sites, resulting in the enhanced CO oxidation.

Keyword:

Electron transfer Localized surface plasmon resonance of Au nanoparticles Metal-organic frameworks Oxidation of carbon monoxide TiO2 supported Au catalyst

Community:

  • [ 1 ] [Zhang, Yujuan]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Li, Qiuzhong]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Liu, Chunxia]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Chen, Xun]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Dai, Wenxin]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Zhang, Yujuan]Fujian Prov Univ, Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Li, Qiuzhong]Fujian Prov Univ, Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Liu, Chunxia]Fujian Prov Univ, Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Dai, Wenxin]Fujian Prov Univ, Fuzhou Univ, Key Lab Ecomat Adv Technol, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Shan, Xinggang]Zhejiang Harmony Photocatalyt Technol Co Ltd, Shaoxing 312366, Peoples R China

Reprint 's Address:

  • 戴文新 付贤智

    [Dai, Wenxin]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China;;[Fu, Xianzhi]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Res Inst Photocatalysis, Fuzhou 350002, Fujian, Peoples R China

Show more details

Related Keywords:

Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2018

Volume: 224

Page: 283-294

1 4 . 2 2 9

JCR@2018

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 74

SCOPUS Cited Count: 78

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:223/10000461
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1