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The exploration of anode materials for lithium ion batteries (LIBs) or sodium ion batteries (SIBs) represents a grand technological challenge to meet the continuously increased demand for the high-performance energy storage market. Here we report a facile and reliable synthetic strategy for in situ growth of few-layer MoS2 nanosheets on reduced graphene oxide (rGO) cross-linked hollow carbon spheres (HCS) with formation of three-dimensional (3D) network nanohybrids (MoS2-rGO/HCS). Systematic electrochemical studies demonstrate, as an anode of LIBs, the as-developed MoS2-rGO/HCS can deliver a reversible capacity of 1145 mAh g(-1) after 100 cycles at 0.1 A g(-1) and a revisible capacity of 753 mAh g(-1) over 1000 cycles at 2 A g(-1). For SIBs, the as-developed MoS2-rGO/HCS can also maintain a reversible capacity of 443 mAh g(-1) at 1 A g(-1) after 500 cycles. The excellent electrochemical performance can be attributed to the 3D porous structures, in which the few-layer MoS2 nanosheets with expanded interlayers can provide shortened ion diffusion paths and improved Li+/Na+ diffusion mobility, and the hollow porous carbon spheres and the outside graphene network are able to improve the conductivity and maintain the structural integrity.
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ACS NANO
ISSN: 1936-0851
Year: 2018
Issue: 2
Volume: 12
Page: 1592-,
1 3 . 9 0 3
JCR@2018
1 5 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:284
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 273
SCOPUS Cited Count: 282
ESI Highly Cited Papers on the List: 31 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: