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author:

He, Qingyan (He, Qingyan.) [1] (Scholars:何庆燕) | Huang, Yan (Huang, Yan.) [2] (Scholars:黄彦) | Wang, Shaoyun (Wang, Shaoyun.) [3]

Indexed by:

EI Scopus SCIE

Abstract:

Hydrogels with high strength and ductility are normally prepared from synthetic polymers, and most protein-based hydrogels are soft and brittle. Here, a strong, ductile gelatin hydrogel is prepared by simply soaking a virgin gelatin gel in an ammonium sulfate solution. The polymer chains in the covalent, crosslink-free network can freely move to homogeneously distribute stress, and more importantly, the highly kosmotropic ammonium sulfate ions greatly enhance the hydrophobic interactions and chain bundling within the gelatin gels. As a result, the treated hydrogels have an extraordinary ultimate strength (compressive and tensile strains of over 99% and 500%, respectively, and stresses of 12 and 3 MPa) superior to that of common protein gels. The physical crosslinks introduced by the Hofmeister effect can rapidly absorb energy and sustain large deformations via decrosslinking and dissociation, which result in energy dissipation and antifatigue properties. The effects of the gelatin and (NH4)(2)SO4 concentrations on the hydrogel mechanics are evaluated, and the possible strengthening mechanism is discussed. The effect of various ions in the Hofmeister series on the gelatin hydrogel is also investigated. Kosmotropic ions enhance the mechanical properties, whereas chaotropic ions soften and dissolve the gel.

Keyword:

ammonium sulfate gelatin Hofmeister effect hydrogels mechanics

Community:

  • [ 1 ] [He, Qingyan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [He, Qingyan]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Huang, Yan]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Wang, Shaoyun]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Wang, Shaoyun]Fuzhou Univ, Key Lab Anal & Detect Technol Food Safety MOE, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 黄彦 汪少芸

    [Huang, Yan]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Shaoyun]Fuzhou Univ, Coll Biol Sci & Engn, Fuzhou 350108, Fujian, Peoples R China;;[Wang, Shaoyun]Fuzhou Univ, Key Lab Anal & Detect Technol Food Safety MOE, Fuzhou 350108, Fujian, Peoples R China

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Source :

ADVANCED FUNCTIONAL MATERIALS

ISSN: 1616-301X

Year: 2018

Issue: 5

Volume: 28

1 5 . 6 2 1

JCR@2018

1 8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 383

SCOPUS Cited Count: 395

ESI Highly Cited Papers on the List: 7 Unfold All

  • 2025-1
  • 2024-11
  • 2024-9
  • 2024-7
  • 2024-5
  • 2024-3
  • 2024-1

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 6

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