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Developing ternary metal oxides as electron transport layers (ETLs) for perovskite solar cells is a great challenge in the field of third-generation photovoltaics. In this study, a highly mesoporous Zn2Ti3O8 (m-ZTO) scaffold is synthesized by ion-exchange method and used as ETL for the fabrication of methyl ammonium lead halide (CH3NH3PbI3) perovskite solar cells. The optimized devices exhibit 17.21% power conversion efficiency (PCE) with an open circuit voltage (V-oc) of 1.02V, short-circuit current density (J(sc)) of 21.97mAcm(-2) and fill factor (FF) of 0.77 under AM1.5G sunlight (100mWcm(-2)). The PCE is significantly higher than that based on mesoporous ST01 (m-ST01; 10nm TiO2 powder) layer (eta = 14.93%), which is ascribed to the deeper conductive band of ZTO nanoparticles, better light absorption and smaller charge recombination. The devices stored for 100days at ambient temperature with humidity of 10% showed excellent stability with only 12% reduction of the PCE. The charge transmission kinetic and long-term stability parameters of the ZTO-based perovskite film growth are discussed as well.
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CHEMSUSCHEM
ISSN: 1864-5631
Year: 2018
Issue: 2
Volume: 11
Page: 424-431
7 . 8 0 4
JCR@2018
7 . 5 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:209
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 19
SCOPUS Cited Count: 21
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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