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author:

Pang, Aiying (Pang, Aiying.) [1] | Shen, Deli (Shen, Deli.) [2] | Wei, Mingdeng (Wei, Mingdeng.) [3] (Scholars:魏明灯) | Chen, Zhong-Ning (Chen, Zhong-Ning.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Developing ternary metal oxides as electron transport layers (ETLs) for perovskite solar cells is a great challenge in the field of third-generation photovoltaics. In this study, a highly mesoporous Zn2Ti3O8 (m-ZTO) scaffold is synthesized by ion-exchange method and used as ETL for the fabrication of methyl ammonium lead halide (CH3NH3PbI3) perovskite solar cells. The optimized devices exhibit 17.21% power conversion efficiency (PCE) with an open circuit voltage (V-oc) of 1.02V, short-circuit current density (J(sc)) of 21.97mAcm(-2) and fill factor (FF) of 0.77 under AM1.5G sunlight (100mWcm(-2)). The PCE is significantly higher than that based on mesoporous ST01 (m-ST01; 10nm TiO2 powder) layer (eta = 14.93%), which is ascribed to the deeper conductive band of ZTO nanoparticles, better light absorption and smaller charge recombination. The devices stored for 100days at ambient temperature with humidity of 10% showed excellent stability with only 12% reduction of the PCE. The charge transmission kinetic and long-term stability parameters of the ZTO-based perovskite film growth are discussed as well.

Keyword:

charge transmission electron transport layer mixed metal oxides perovskites solar cell

Community:

  • [ 1 ] [Pang, Aiying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Chen, Zhong-Ning]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Shen, Deli]Fuzhou Univ, Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Wei, Mingdeng]Fuzhou Univ, Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 魏明灯

    [Chen, Zhong-Ning]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Wei, Mingdeng]Fuzhou Univ, Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

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Source :

CHEMSUSCHEM

ISSN: 1864-5631

Year: 2018

Issue: 2

Volume: 11

Page: 424-431

7 . 8 0 4

JCR@2018

7 . 5 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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