Two new 3D heterometallic chalcogenides based on copper-rich selenogermanate clusters - Details

author：

Wang, Yu-Long (Wang, Yu-Long.) ^[1] | Zhang, Bo (Zhang, Bo.) ^[2] | Li, Wei-An (Li, Wei-An.) ^[3] | Feng, Mei-Ling (Feng, Mei-Ling.) ^[4] | Huang, Xiao-Ying (Huang, Xiao-Ying.) ^[5]

Indexed by：

CPCI-S Scopus SCIE

Abstract：

Two　new　three-dimensional　(3D)　copper-rich　selenogermanates　with　organic　amine　cations　as　structural　directing　agents,　namely　(enH(2))(5)[Cu16Ge6Se19(Se-2)(6)]center　dot　en　(1)　(en　=　ethylenediamine)　and　[(CH3)(2)NH2](6)[Cu8Ge6Se19]center　dot　0.25H(2)O　(2),　have　been　solvothermally　synthesized　and　structurally　characterized.　Compound　1　is　constructed　by　interconnections　of　icosahedral　[Cu8Se13]　and　octahedral　[Cu4Se6]　clusters　through　bridging　[GeSe3(Se-2)]　units　to　form　a　3D　anionic　framework　with　ethylenediamine　cation/molecules　located　in　the　intersecting　channels.　Compound　2　features　a　3D　anionic　framework　constructed　from　[Cu8Se13]　clusters　linked　by　dimeric　[Ge2Se6]　units.　(C)　2017　Elsevier　B.V.　All　rights　reserved.

Keyword：

Copper-rich cluster Crystal structure Organic amine Selenogermanate Solvothermal synthesis

Community：

[ 1 ] [Wang, Yu-Long]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 2 ] [Zhang, Bo]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 3 ] [Li, Wei-An]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 4 ] [Feng, Mei-Ling]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 5 ] [Huang, Xiao-Ying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 6 ] [Zhang, Bo]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[ 7 ] [Li, Wei-An]Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address：

[Feng, Mei-Ling]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Huang, Xiao-Ying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Email：

fml@fjirsm.ac.cn |
xyhuang@fjirsm.ac.cn

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