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author:

Wang, Zhihong (Wang, Zhihong.) [1] | Yan, Yingming (Yan, Yingming.) [2] | Chen, Yifu (Chen, Yifu.) [3] | Han, Wenqiao (Han, Wenqiao.) [4] | Liu, Mengting (Liu, Mengting.) [5] | Zhang, Yaohui (Zhang, Yaohui.) [6] | Xiong, Yueping (Xiong, Yueping.) [7] | Chen, Kongfa (Chen, Kongfa.) [8] (Scholars:陈孔发) | Lv, Zhe (Lv, Zhe.) [9] | Liu, Meilin (Liu, Meilin.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Porous metals with a cellular architecture have attracted considerable attention for a diverse range of applications. Extensive efforts have been devoted to exploring cost-effective ways to create porous metals. Here we propose a novel approach for the fabrication of micron porous Ni metals through a redox process in a CH4-O-2 gas mixture at 750 degrees C. The multiple redox cycles at high temperatures facilitate a rapid reconstruction of Ni atoms, producing a cellular architecture. This process is simple and clean, avoiding the use of precious metals and templates. The redox process is applicable to the creation of porous architectures (from surface texturing to 3D cellular structures) on a Ni sheet and a unique hierarchical porous architecture on Ni foam. Furthermore, nanocrystalline MnO2 is successfully coated on a micron porous Ni foam (MPNF) to form a supercapacitor electrode. The micron porous architectures of the MPNF-MnO2 electrode enhance not only the electrochemical performance but also the mechanical integrity and robustness, leading to ultrahigh capacitance and excellent cycling stability. More importantly, the strategy of micron-sculpturing of metals using a redox process is readily applicable to other metal systems for the fabrication of cellular metals and alloys for a variety of applications, including catalysis, energy storage and conversion, and chemical sensing.

Keyword:

Community:

  • [ 1 ] [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 2 ] [Yan, Yingming]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 3 ] [Chen, Yifu]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 4 ] [Han, Wenqiao]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 5 ] [Liu, Mengting]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 6 ] [Zhang, Yaohui]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 7 ] [Lv, Zhe]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China
  • [ 8 ] [Wang, Zhihong]Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, 92 West Dazhi St, Harbin 150001, Heilongjiang, Peoples R China
  • [ 9 ] [Xiong, Yueping]Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, 92 West Dazhi St, Harbin 150001, Heilongjiang, Peoples R China
  • [ 10 ] [Chen, Kongfa]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Liu, Meilin]Georgia Inst Technol, Sch Mat Sci & Engn, Ctr Innovat Fuel Cell & Battery Technol, 771 Ferst Dr NW, Atlanta, GA 30332 USA

Reprint 's Address:

  • [Wang, Zhihong]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China;;[Lv, Zhe]Harbin Inst Technol, Dept Phys, Yikuang St 2, Harbin 150001, Heilongjiang, Peoples R China;;[Wang, Zhihong]Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, 92 West Dazhi St, Harbin 150001, Heilongjiang, Peoples R China;;[Liu, Meilin]Georgia Inst Technol, Sch Mat Sci & Engn, Ctr Innovat Fuel Cell & Battery Technol, 771 Ferst Dr NW, Atlanta, GA 30332 USA

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Source :

JOURNAL OF MATERIALS CHEMISTRY A

ISSN: 2050-7488

Year: 2017

Issue: 39

Volume: 5

Page: 20709-20719

9 . 9 3 1

JCR@2017

1 0 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:306

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 23

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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