A New 2-D Inorganic-Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39](n)(6n-) Chains and [Cu(en)(2)](2+) Bridges - Details

author：

Ci, Peng-Chao (Ci, Peng-Chao.) ^[1] | Zhang, Zhong (Zhang, Zhong.) ^[2] | Yang, Bai-Feng (Yang, Bai-Feng.) ^[3] | Li, Xin-Xiong (Li, Xin-Xiong.) ^[4] (Scholars：李新雄) | Yang, Guo-Yu (Yang, Guo-Yu.) ^[5]

Indexed by：

Scopus SCIE

Abstract：

A　new　organic-inorganic　hybrid　polyoxometalate　H-2[Cu(en)(2)(H2O)](2)[Cu(en)(2)]{[Cu(en)(2)](3)　(CuSiW11O39)(2)}center　dot　6H(2)O　(1)　(en　=　ethylenediamine)　have　been　hydrothermally　synthesized　and　characterized　by　IR　spectrum,　thermogravimetric　analysis,　power　X-ray　diffraction　and　single-crystal　X-ray　diffraction.　Crystal　data　for　1:　monoclinic,　P2(1)/c,　a　=　18.8077(3)　angstrom,　b　=　23.0703(5)　angstrom,　c　=　26.0723(6)　angstrom,　beta　=　96.438(2)degrees,　Z　=　4.　Single-crystal　X-ray　diffraction　analysis　revealed　that　1　exhibits　a　2-dimensional　network　constructed　from　mono-Cu-substituted　[CuSiW11O39](n)(6n-)　chains　and　[Cu(en)(2)](2+)　bridges.

Keyword：

Copper Crystal structure Hydrothermal synthesis Organic-inorganic hybrid Polyoxometalates

Community：

[ 1 ] [Ci, Peng-Chao]Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[ 2 ] [Zhang, Zhong]Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[ 3 ] [Yang, Bai-Feng]Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[ 4 ] [Yang, Guo-Yu]Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[ 5 ] [Li, Xin-Xiong]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

Reprint 's Address：

李新雄
[Yang, Guo-Yu]Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China;;[Li, Xin-Xiong]Fuzhou Univ, Coll Chem, Fuzhou 350116, Fujian, Peoples R China

Email：

lxx@fzu.edu.cn |
ygy@bit.edu.cn

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Version：

A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39]n 6n− Chains and [Cu(en)2]2+ Bridges
2017，Journal of Cluster Science

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Source ：

JOURNAL OF CLUSTER SCIENCE

ISSN： 1040-7278

Year： 2017

Issue： 3

Volume： 28

Page： 1249-1257

1 . 7 1 5

JCR@2017

2 . 7 0 0

JCR@2023

ESI Discipline： CHEMISTRY;

ESI HC Threshold：226

JCR Journal Grade：3

CAS Journal Grade：4

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 3

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