A rare polyoxometalate based on mixed niobium-based polyoxoanions [GeNb18O54](14-) and [Nb3W3O19](5-) - Details

author：

Indexed by：

Scopus SCIE

Abstract：

Polyoxoniobate　[GeNb18O54](14-)　and　polyniobotungstate　[Nb3W3O19](5-)　are　firstly　found　to　co-crystallize　at　the　same　crystal　to　form　a　rare　organic-inorganic　hybrid　polyoxometalate　H[Cu(en)(2)(H2O)](8)[Cu(en)(2)　(H2O)(2)](2){K-4[Cu(en)(2)](2)[Cu(en)(2)(GeNb18O54)](2)}Nb3W3O19]center　dot　32H(2)O　(1).　Interestingly,　in　1,　the　crescent-shaped　polyoxoanions　[GeNb18O54](14-)　can　form　dimeric　secondary　building　units　(SBUs)　{[GeNb18O54](2)[K-2(H2O)(5)](2)}　via　the　linkage　of　K+　cations.　These　dimeric　SBUs　can　be　further　bridged　by　copper　complexes　to　generate　1D　infinite　double　strand　chains　with　completely　different　isolated　polyoxoanions　[Nb3W3O19](5-)　filling　the　gaps　between　chains.　(C)　2017　Published　by　Elsevier　B.V.

Keyword：

Hydrothermal synthesis Mixed clusters Polyoxometalates Proton-conducting

Community：

[ 1 ] [Liu, Bing-Xin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[ 2 ] [Cai, Zhen-Wen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[ 3 ] [Yang, Tao]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[ 4 ] [Li, Xin-Xiong]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[ 5 ] [Zheng, Shou-Tian]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China
[ 6 ] [Yang, Guo-Yu]Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
[ 7 ] [Liu, Bing-Xin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 8 ] [Li, Xin-Xiong]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 9 ] [Yang, Guo-Yu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[ 10 ] [Zheng, Shou-Tian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address：

杨国昱郑寿添
[Yang, Guo-Yu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China;;[Zheng, Shou-Tian]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Email：

ygy@bit.edu.cn |
stzheng@fzu.edu.cn

Show more details

Version：