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author:

Chen Jian (Chen Jian.) [1] | Zheng Yu-Ying (Zheng Yu-Ying.) [2] (Scholars:郑玉婴) | Zhang Yan-Bing (Zhang Yan-Bing.) [3] | Zou Hai-Qiang (Zou Hai-Qiang.) [4] | Lu Xiu-Lian (Lu Xiu-Lian.) [5]

Indexed by:

EI Scopus SCIE PKU CSCD

Abstract:

Pristine multiwalled carbon nanotubes (MWCNTs) were modified by sodium dodecyl sulfate (SDS). Afterwards, a series of MnO2/MWCNTs were prepared via a redox method and used in selective catalytic reduction (SCR) of NOx at 80-180 degrees C. Structural properties and catalytic performance were investigated by specific surface area measurements (BET), X-ray diffraction (XRD), filed emission scanning electron microscope (FESEM), transmission electron microscope (TEM), X-ray photoelectron spectroscope (XPS), and H-2 temperature-programmed reduction (H-2-TPR). The characterization results indicate that the nanoflaky MnO2 highly disperse on MWCNTs. The results show that the low-temperature SCR activities of MnO2/MWCNTs catalysts are 85%-100% at 140-180 degrees C at a weight hourly space velocity of 210 L/(g(cat)center dot h), higher than that of catalyst fabricated via the wet impregnation method. The 10% MnO2/MWCNTs catalyst displays first-rate SCR activity, which is attributed to its low crystallinity, high concentrations of Mn4+ and oxygen absorbtion onto the catalyst surface, as well as excellent reducibility. Additionally, compared to the MnOx/MWCNTs catalyst, the 10% MnO2/MWCNTs catalyst exhibits higher resistance to H2O and SO2.

Keyword:

manganese oxide multi-walled carbon nanotube nitrogen oxide selective catalytic reduction sodium dodecyl sulfate

Community:

  • [ 1 ] [Chen Jian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zheng Yu-Ying]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang Yan-Bing]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zou Hai-Qiang]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lu Xiu-Lian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 陈健

    [Chen Jian]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China

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Source :

JOURNAL OF INORGANIC MATERIALS

ISSN: 1000-324X

CN: 31-1363/TQ

Year: 2016

Issue: 12

Volume: 31

Page: 1347-1354

0 . 4 4 4

JCR@2016

1 . 7 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 3

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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