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Pristine multiwalled carbon nanotubes (MWCNTs) were modified by sodium dodecyl sulfate (SDS). Afterwards, a series of MnO2/MWCNTs were prepared via a redox method and used in selective catalytic reduction (SCR) of NOx at 80-180 degrees C. Structural properties and catalytic performance were investigated by specific surface area measurements (BET), X-ray diffraction (XRD), filed emission scanning electron microscope (FESEM), transmission electron microscope (TEM), X-ray photoelectron spectroscope (XPS), and H-2 temperature-programmed reduction (H-2-TPR). The characterization results indicate that the nanoflaky MnO2 highly disperse on MWCNTs. The results show that the low-temperature SCR activities of MnO2/MWCNTs catalysts are 85%-100% at 140-180 degrees C at a weight hourly space velocity of 210 L/(g(cat)center dot h), higher than that of catalyst fabricated via the wet impregnation method. The 10% MnO2/MWCNTs catalyst displays first-rate SCR activity, which is attributed to its low crystallinity, high concentrations of Mn4+ and oxygen absorbtion onto the catalyst surface, as well as excellent reducibility. Additionally, compared to the MnOx/MWCNTs catalyst, the 10% MnO2/MWCNTs catalyst exhibits higher resistance to H2O and SO2.
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JOURNAL OF INORGANIC MATERIALS
ISSN: 1000-324X
CN: 31-1363/TQ
Year: 2016
Issue: 12
Volume: 31
Page: 1347-1354
0 . 4 4 4
JCR@2016
1 . 7 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 3
SCOPUS Cited Count: 3
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: