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Abstract:
We develop a bimetallic Pd-Cu catalyst that takes the advantage of Pd-Cu bimetal as active species and earth-abundant bauxite as support. The bauxite support with high surface area was obtained by hydrothermal NaOH aqueous solution treatment, and the amount of Pd is fixed to a low concentration of 0.5% (weight percentage) by incipient-wetness impregnation method. Their catalytic activity for CO oxidation reaction has also been studied. The effect of different Cu loading content on the chemical-physical properties of the as-prepared catalysts is investigated in detail. It is found that the dispersion of Pd species is promoted by the introduction of Cu species; and both Pd-Cu interaction and metal (Pd-Cu bimetals)-support (modified bauxite (MB) interaction are modulated by varying the Cu content. Furthermore, the catalytic activities with respect to the catalytic CO oxidation are performed, and the catalyst loaded with 0.5% Pd and 4% Cu (PdCu4/MB) shows the highest catalytic activity. It is believed that the well dispersion of Pd and Cu, the strong interactions between the metals and the support as well as between Pd and Cu are responsible for the highest catalytic activity of PdCu4/MB. Moreover, it can be concluded from the CO-TPD investigation that superior abilities in adsorption of CO and extraction of oxygen from the support are favor for high catalytic activity of PdCu4/MB catalyst in CO oxidation.y
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CHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN: 1001-4861
CN: 32-1185/O6
Year: 2016
Issue: 10
Volume: 32
Page: 1867-1875
0 . 4 8 9
JCR@2016
0 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:235
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: