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author:

Zhan Ying-Ying (Zhan Ying-Ying.) [1] (Scholars:詹瑛瑛) | Xu Cong-Bo (Xu Cong-Bo.) [2] | Chen Chong-Qi (Chen Chong-Qi.) [3] (Scholars:陈崇启) | Liu Xian (Liu Xian.) [4] | Ma Yong-De (Ma Yong-De.) [5] (Scholars:马永德) | Jiang Li-Long (Jiang Li-Long.) [6] (Scholars:江莉龙)

Indexed by:

Scopus SCIE PKU CSCD

Abstract:

We develop a bimetallic Pd-Cu catalyst that takes the advantage of Pd-Cu bimetal as active species and earth-abundant bauxite as support. The bauxite support with high surface area was obtained by hydrothermal NaOH aqueous solution treatment, and the amount of Pd is fixed to a low concentration of 0.5% (weight percentage) by incipient-wetness impregnation method. Their catalytic activity for CO oxidation reaction has also been studied. The effect of different Cu loading content on the chemical-physical properties of the as-prepared catalysts is investigated in detail. It is found that the dispersion of Pd species is promoted by the introduction of Cu species; and both Pd-Cu interaction and metal (Pd-Cu bimetals)-support (modified bauxite (MB) interaction are modulated by varying the Cu content. Furthermore, the catalytic activities with respect to the catalytic CO oxidation are performed, and the catalyst loaded with 0.5% Pd and 4% Cu (PdCu4/MB) shows the highest catalytic activity. It is believed that the well dispersion of Pd and Cu, the strong interactions between the metals and the support as well as between Pd and Cu are responsible for the highest catalytic activity of PdCu4/MB. Moreover, it can be concluded from the CO-TPD investigation that superior abilities in adsorption of CO and extraction of oxygen from the support are favor for high catalytic activity of PdCu4/MB catalyst in CO oxidation.y

Keyword:

alkali-modified bauxite CO oxidation Cu loading Pd-Cu bimetallic

Community:

  • [ 1 ] [Zhan Ying-Ying]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 2 ] [Xu Cong-Bo]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 3 ] [Chen Chong-Qi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 4 ] [Liu Xian]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 5 ] [Ma Yong-De]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
  • [ 6 ] [Jiang Li-Long]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 江莉龙

    [Jiang Li-Long]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China

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Source :

CHINESE JOURNAL OF INORGANIC CHEMISTRY

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2016

Issue: 10

Volume: 32

Page: 1867-1875

0 . 4 8 9

JCR@2016

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:235

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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