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author:

Liu, Honglin (Liu, Honglin.) [1] | Huang, Jinwan (Huang, Jinwan.) [2] | Zhao, Dandan (Zhao, Dandan.) [3] | Yang, Hsiwen (Yang, Hsiwen.) [4] | Zhang, Teng (Zhang, Teng.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

The electrical property of sealing glass-ceramics is of great importance for Solid Oxide Fuel Cell (SOFC) applications. In spite of their good sintering property, CeO2-containing glass-ceramics often lack in sufficient electrical resistance, due to the formation of CeO2 as a conductive phase. Here we report for the first time that the electrical conductivity of CeO2-containing glass-ceramics can be reduced by an order of magnitude with HfO2 dopant. A mechanism on the improved electrical property has also been proposed in terms of the structural change in HfO2-doped glass-ceramics. In addition, the relationship between phase evolution of HfO2-doped glass-ceramics and the change in conductivity with operational time has been systematically investigated. Moreover, HfO2-doped glass-ceramics show good chemical compatibility with 8 mol.% yttria-stabilized zirconia (8YSZ) electrolyte, after held at 750 degrees C for 500 h. The reported results support the suitability of prepared glass-ceramics as sealing materials for SOFC applications. (C) 2015 Elsevier Ltd. All rights reserved.

Keyword:

Chemical compatibility Electrical property Glass-ceramics Phase evolution Solid Oxide Fuel Cell

Community:

  • [ 1 ] [Liu, Honglin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Huang, Jinwan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Zhao, Dandan]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Yang, Hsiwen]Natl United Univ, Dept Mat Sci & Engn, Miaoli 36003, Taiwan

Reprint 's Address:

  • 张腾

    [Zhang, Teng]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY

ISSN: 0955-2219

Year: 2016

Issue: 3

Volume: 36

Page: 917-923

3 . 4 5 4

JCR@2016

5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:324

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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