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The electrical property of sealing glass-ceramics is of great importance for Solid Oxide Fuel Cell (SOFC) applications. In spite of their good sintering property, CeO2-containing glass-ceramics often lack in sufficient electrical resistance, due to the formation of CeO2 as a conductive phase. Here we report for the first time that the electrical conductivity of CeO2-containing glass-ceramics can be reduced by an order of magnitude with HfO2 dopant. A mechanism on the improved electrical property has also been proposed in terms of the structural change in HfO2-doped glass-ceramics. In addition, the relationship between phase evolution of HfO2-doped glass-ceramics and the change in conductivity with operational time has been systematically investigated. Moreover, HfO2-doped glass-ceramics show good chemical compatibility with 8 mol.% yttria-stabilized zirconia (8YSZ) electrolyte, after held at 750 degrees C for 500 h. The reported results support the suitability of prepared glass-ceramics as sealing materials for SOFC applications. (C) 2015 Elsevier Ltd. All rights reserved.
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JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
ISSN: 0955-2219
Year: 2016
Issue: 3
Volume: 36
Page: 917-923
3 . 4 5 4
JCR@2016
5 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 10
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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