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Abstract:
A simple method has been developed for the preparation of silver nanoparticles/carbon based quantum dot nano-hybrids (AgNPs@CDs). First, the small-sized CDs with abundant oxygen-containing functional groups adsorbed Ag+ ions through ion exchange or coordination reactions. Then, during the reaction with NaBH4, the Ag+ ions were reduced to AgNPs while the oxygen-containing functional groups were partially removed from the CDs. Thus, CDs were coated on the surfaces of the resultant AgNPs, leading to the formation of AgNPs@CDs. The residual oxygen-containing groups on the CDs made the obtained AgNPs@CDs possess excellent dispersivity and long-term stability in water. The synthesized AgNPs@CDs showed high surface-enhanced Raman scattering (SERS) activity and provided a sensitive SERS sensing ability for 4-aminothiophenol, with a wide dynamic range from 1 x 10 (-10) to 1 x 10(-5) M and a low detection limit (S/N = 3) of 5.0 x 10(-11) M.
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JOURNAL OF MATERIALS CHEMISTRY C
ISSN: 2050-7526
Year: 2016
Issue: 31
Volume: 4
Page: 7472-7477
5 . 2 5 6
JCR@2016
5 . 7 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:324
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 25
SCOPUS Cited Count: 27
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 6
Affiliated Colleges: