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Abstract:
In spite of the fact that rare earth oxides can improve the sealing properties of glass-ceramics, the electrical stability of these glass-ceramics under Solid Oxide Fuel Cell (SOFC) operational conditions still remains ambiguous. In this work, the electrical stability of glass-ceramics doped with La2O3 or CeO2 under SOFC operational conditions has been systematically investigated. The glass-ceramic-material with La2O3 dopant exhibits good electrical stability under SOFC operational conditions; whereas, a decrease in the conductivity of the CeO2-containing glass-ceramic material can be related to the formation of a conductive phase, i.e., CeO2. In particular, the relationship between the phase evolution and the change in conductivity of glass-ceramics has been clearly demonstrated. Moreover, the sealing glass-ceramics show good chemical compatibility with 8 mol% yttria-stabilized zirconia (8YSZ) electrolyte, after being held at 750 degrees C for 1000 hours. The reported results support the suitability of La2O3-containing glass-ceramic as a sealing material for SOFC applications.
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RSC ADVANCES
ISSN: 2046-2069
Year: 2016
Issue: 21
Volume: 6
Page: 17151-17157
3 . 1 0 8
JCR@2016
3 . 9 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:235
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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