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A novel molecularly imprinted electrochemiluminescence sensor based on a Ru(bpy)(3)(2+)/multi-walled carbon nanotubes (MWCNTs)/nano-titanium dioxide (nano-TiO2)-Nafion electrode was established for the ultrasensitive and ultraselective detection of bisphenol A (BPA). The introduction of MWCNTs/nano-TiO2 nanohybrids into the Nafion film could provide an excellent basis for effective immobilization of Ru(bpy)(3)(2+) and improve the electrochemical and ECL properties of Ru(bpy)(3)(2+). The MIP-ECL sensor fabricated by the combination of the MIT with the Ru(bpy)(3)(2+) ECL system could provide specific binding sites for BPA and the selectivity of the sensor was significantly improved. Under the best optimum conditions, the proposed MIP-ECL sensor not only exhibited high sensitivity and selectivity for BPA, but also displayed acceptable reproducibility and stability. A linear range from 0.01 mg L-1 to 2 mg L-1 for the detection of BPA was observed with a detection limit of 0.0041 mg L-1. Moreover, the fabricated sensor was successfully used to detect BPA in ambient water samples and relatively satisfactory recoveries were obtained.
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ANALYTICAL METHODS
ISSN: 1759-9660
Year: 2016
Issue: 41
Volume: 8
Page: 7445-7452
1 . 9
JCR@2016
2 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:235
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 14
SCOPUS Cited Count: 16
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3