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author:

Lin, Yulin (Lin, Yulin.) [1] | Cao, Jie (Cao, Jie.) [2] | Li, Xiaojuan (Li, Xiaojuan.) [3] (Scholars:李小娟) | Zhang, Xinying (Zhang, Xinying.) [4] (Scholars:张新颖) | Zhang, Jianhua (Zhang, Jianhua.) [5] | Lin, Zhenyu (Lin, Zhenyu.) [6] (Scholars:林振宇)

Indexed by:

EI Scopus SCIE

Abstract:

A novel molecularly imprinted electrochemiluminescence sensor based on a Ru(bpy)(3)(2+)/multi-walled carbon nanotubes (MWCNTs)/nano-titanium dioxide (nano-TiO2)-Nafion electrode was established for the ultrasensitive and ultraselective detection of bisphenol A (BPA). The introduction of MWCNTs/nano-TiO2 nanohybrids into the Nafion film could provide an excellent basis for effective immobilization of Ru(bpy)(3)(2+) and improve the electrochemical and ECL properties of Ru(bpy)(3)(2+). The MIP-ECL sensor fabricated by the combination of the MIT with the Ru(bpy)(3)(2+) ECL system could provide specific binding sites for BPA and the selectivity of the sensor was significantly improved. Under the best optimum conditions, the proposed MIP-ECL sensor not only exhibited high sensitivity and selectivity for BPA, but also displayed acceptable reproducibility and stability. A linear range from 0.01 mg L-1 to 2 mg L-1 for the detection of BPA was observed with a detection limit of 0.0041 mg L-1. Moreover, the fabricated sensor was successfully used to detect BPA in ambient water samples and relatively satisfactory recoveries were obtained.

Keyword:

Community:

  • [ 1 ] [Lin, Yulin]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Peoples R China
  • [ 2 ] [Li, Xiaojuan]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Peoples R China
  • [ 3 ] [Zhang, Xinying]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Peoples R China
  • [ 4 ] [Cao, Jie]Fujian Agr & Forestry Univ, Coll Life Sci, Fuzhou 350002, Peoples R China
  • [ 5 ] [Cao, Jie]Fujian Entry Exit Inspect & Quarantine Bur PRC, Fujian Int Travel Healthcare Ctr, AQSIQ Key Lab Drug Detect, Fuzhou 350001, Peoples R China
  • [ 6 ] [Zhang, Jianhua]Fujian Radiat Environm Supervis Stn, Fuzhou 350013, Peoples R China
  • [ 7 ] [Lin, Zhenyu]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 李小娟

    [Li, Xiaojuan]Fuzhou Univ, Coll Environm & Resources, Fuzhou 350116, Peoples R China

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Source :

ANALYTICAL METHODS

ISSN: 1759-9660

Year: 2016

Issue: 41

Volume: 8

Page: 7445-7452

1 . 9

JCR@2016

2 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:235

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 14

SCOPUS Cited Count: 16

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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