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author:

Huang, Kun (Huang, Kun.) [1] | Lin, Liuliu (Lin, Liuliu.) [2] | Yang, Kai (Yang, Kai.) [3] | Dai, Wenxin (Dai, Wenxin.) [4] (Scholars:戴文新) | Chen, Xun (Chen, Xun.) [5] (Scholars:陈旬) | Fu, Xianzhi (Fu, Xianzhi.) [6] (Scholars:付贤智)

Indexed by:

EI Scopus SCIE

Abstract:

Pt catalysts supported on TiO2 and CeO2-TiO2 (Pt/TiO2 and Pt/CeO2-TiO2) were prepared by a two-step precipitation-deposition method, respectively. As compared to Pt/TiO2, Pt/CeO2-TiO2 exhibits a higher thermo-catalytic activity and stability for CO + NO reaction, and also exhibits a stronger effect of ultraviolet light (UV) on promoting this reaction. The in-situ FTIR results indicate that the doped CeO2 can significantly improve the adsorption of NO at Pt/CeO2-TiO2, while UV light further enhance the adsorption of NO and its activation. Based on the results of Raman spectrum, electron paramagnetic resonance and the X-ray photoelectron spectroscopy testing, it is proposed that UV irradiation can cause the increase in surface electron density of Pt nanoparticles by the photo-induced electron transfer from TiO2 to Pt. Moreover, the doped CeO2 can further improve the electron transfer from TiO2 to Pt through a process of Ce4+ -> Ce3+ under UV irradiation, resulting in the adsorption and activation of CO and NO species at Pt/CeO2-TiO2. This result also indicates that the photo-excitation of supports can strengthen the strong interaction between support and metal nanoparticles, and then promote the thermo-catalytic reactivity of catalysts. (C) 2015 Elsevier B.V. All rights reserved.

Keyword:

Carbon monoxide oxidation Electron transfer Nitrogen monoxide reduction Photo-assisted effect Platinum nanoparticles

Community:

  • [ 1 ] [Huang, Kun]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 2 ] [Lin, Liuliu]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 3 ] [Yang, Kai]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 4 ] [Dai, Wenxin]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 5 ] [Chen, Xun]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 6 ] [Fu, Xianzhi]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • 戴文新

    [Dai, Wenxin]Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

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Source :

APPLIED CATALYSIS B-ENVIRONMENTAL

ISSN: 0926-3373

Year: 2015

Volume: 179

Page: 395-406

8 . 3 2 8

JCR@2015

2 0 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:265

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 60

SCOPUS Cited Count: 65

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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