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author:

Liu, Jing-Jing (Liu, Jing-Jing.) [1] | Chen, Zhi-Tao (Chen, Zhi-Tao.) [2] | Tang, Duo-Si (Tang, Duo-Si.) [3] | Wang, Yao-Bing (Wang, Yao-Bing.) [4] | Kang, Long-Tian (Kang, Long-Tian.) [5] | Yao, Jian-Nian (Yao, Jian-Nian.) [6]

Indexed by:

EI

Abstract:

A simple graphene quantum dots (GQDs)-based fluorescence sensing system was developed for rapid, sensitive and low-cost detection of ascorbic acid (AA) in the presence of copper ions. Due to the efficient electron-transfer between GQDs and Cu2+ ions, the fluorescence of GQDs was greatly quenched by Cu2+ ions. Upon addition of ascorbic acid, Cu2+ was reduced to Cu+ and the interaction of Cu2+-GQDs was destroyed, which inhibit the quenching and thus leading to fluorescence recovery of GQDs. The detection process is ultrafast and can be completed within 5 min. The linear response range of AA was obtained from 0.3 μM to 10 μM. The detection limit was as low as 94 nM, which was comparable to or even better than other reported assays. In addition, this sensing system also showed good selectivity for detecting AA in the presence of different physiological molecules and inorganic ions. Finally, the proposed sensing system was successfully applied to assay AA in real samples with satisfactory results. © 2015 Elsevier B.V. All rights reserved.

Keyword:

Ascorbic acid Fluorescence Graphene Metal ions Nanocrystals Semiconductor quantum dots Sensors

Community:

  • [ 1 ] [Liu, Jing-Jing]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 2 ] [Liu, Jing-Jing]Key Laboratory of Design and Assembly of Functional Nanostructures, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 3 ] [Chen, Zhi-Tao]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou; 350002, China
  • [ 4 ] [Chen, Zhi-Tao]Fuqing Entry-Exit Inspection and Quarantine Bureau, Fuqing, Fujian; 350300, China
  • [ 5 ] [Tang, Duo-Si]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 6 ] [Tang, Duo-Si]College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou; 350002, China
  • [ 7 ] [Wang, Yao-Bing]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 8 ] [Wang, Yao-Bing]Key Laboratory of Design and Assembly of Functional Nanostructures, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 9 ] [Kang, Long-Tian]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 10 ] [Kang, Long-Tian]Key Laboratory of Design and Assembly of Functional Nanostructures, Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 11 ] [Yao, Jian-Nian]Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing; 100190, China

Reprint 's Address:

  • [kang, long-tian]key laboratory of design and assembly of functional nanostructures, chinese academy of sciences, fuzhou; 350002, china;;[kang, long-tian]state key laboratory of structural chemistry, fujian institute of research on the structure of matter, chinese academy of sciences, fuzhou; 350002, china

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Source :

Sensors and Actuators, B: Chemical

ISSN: 0925-4005

Year: 2015

Volume: 212

Page: 214-219

4 . 7 5 8

JCR@2015

6 . 3 9 3

JCR@2018

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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