One　new　copper(II)　complex　with　a　multidentate　Schiff-base　ligand　salicylaldehyde　phenoxyacylhydrazone　(H2L),　{[Cu-4(L)(4)(DMF)]center　dot　DMF}(n)　(1)　has　been　synthesized　and　structurally　characterized.　Complex　1　exhibits　a　coordination　polymer　with　a　1-D　infinite　chain-like　structure,　resulting　from　the　Cu(II)　centers　linked　by　N-N　single　bonds.　Magnetic　behavior　of　1　shows　that　it　is　antiferromagnetic.