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Abstract:
Two new iron-based selenites AFe2(SeO3)4 (A = Sr and Hg) have been successfully obtained via a hydrothermal reaction. Both of two compounds exhibit a classic channel structure, where SrFe2(SeO3)4 and HgFe2(SeO3)4 crystallize in different space groups of triclinic P-1 and tetragonal I-42d, respectively. Magnetic measurements indicate that SrFe2(SeO3)4 shows a collinear antiferromagnetic ordering below TN = 23.5 K, while HgFe2(SeO3)4 undergoes a canted antiferromagnetic ordering below TN = 34 K. Further, magnetic anisotropy of HgFe2(SeO3)4 is also investigated using a large-sized single crystal sample, confirming magnetization easy a-b plane in the system. Moreover, the optical band-gaps of SrFe2(SeO3)4 and HgFe2(SeO3)4 are 2.70 eV and 2.77 eV estimated from the UV-vis diffuse reflectance spectra, indicating that they may be semiconductors.
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JOURNAL OF SOLID STATE CHEMISTRY
ISSN: 0022-4596
Year: 2023
Volume: 323
3 . 2
JCR@2023
3 . 2 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:39
JCR Journal Grade:2
CAS Journal Grade:3
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: