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author:

Zhang, Yuanjun (Zhang, Yuanjun.) [1] | Lu, Changke (Lu, Changke.) [2] | Cui, Meiyan (Cui, Meiyan.) [3] | Zhao, Zhiying (Zhao, Zhiying.) [4] | He, Zhangzhen (He, Zhangzhen.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

Two new iron-based selenites AFe2(SeO3)4 (A = Sr and Hg) have been successfully obtained via a hydrothermal reaction. Both of two compounds exhibit a classic channel structure, where SrFe2(SeO3)4 and HgFe2(SeO3)4 crystallize in different space groups of triclinic P-1 and tetragonal I-42d, respectively. Magnetic measurements indicate that SrFe2(SeO3)4 shows a collinear antiferromagnetic ordering below TN = 23.5 K, while HgFe2(SeO3)4 undergoes a canted antiferromagnetic ordering below TN = 34 K. Further, magnetic anisotropy of HgFe2(SeO3)4 is also investigated using a large-sized single crystal sample, confirming magnetization easy a-b plane in the system. Moreover, the optical band-gaps of SrFe2(SeO3)4 and HgFe2(SeO3)4 are 2.70 eV and 2.77 eV estimated from the UV-vis diffuse reflectance spectra, indicating that they may be semiconductors.

Keyword:

Crystal structure Hydrothermal reaction Magnetic anisotropy Magnetic properties Selenite

Community:

  • [ 1 ] [Zhang, Yuanjun]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Lu, Changke]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 3 ] [Zhang, Yuanjun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Lu, Changke]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Cui, Meiyan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Zhao, Zhiying]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [He, Zhangzhen]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF SOLID STATE CHEMISTRY

ISSN: 0022-4596

Year: 2023

Volume: 323

3 . 2

JCR@2023

3 . 2 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:39

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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