• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Wen, Jun (Wen, Jun.) [1] | Reid, Michael F. (Reid, Michael F..) [2] | Ning, Lixin (Ning, Lixin.) [3] | Zhang, Jie (Zhang, Jie.) [4] | Zhang, Yongfan (Zhang, Yongfan.) [5] (Scholars:章永凡) | Duan, Chang-Kui (Duan, Chang-Kui.) [6] | Yin, Min (Yin, Min.) [7]

Indexed by:

CPCI-S EI Scopus SCIE

Abstract:

Wavefimction-based ab-initio calculations of the electric-dipole moments of 4f(N)-4f(N) transitions of lanthanide ions are performed to extract the A(tp)(lambda) intensity parameters. The extraction method is an extension of our earlier calculations of crystal-field (CF) parameters for lanthanide ions in crystals. The CASSCF/RASSI-SO (Complete-Active-Space Self-Consistent-Field/Restricted-Active-Space State-Interaction Spin-Orbit) calculations have been carried out on the chosen model system of CaF2: Ce3+ with an interstitial fluoride ion (F-i(-)) on z-axis (Ce3+ ion occupying the C-4v symmetry site). In consideration of the site symmetry and the coordination situation of Ce3+ ion at C-4v site in CaF2 as well as the superposition model (SM), the calculated intensity parameters for Ce3+ ion can be classified into three categories, and detailed discussions are then given. (C) 2013 Elsevier B.V. All rights reserved.

Keyword:

Ab-initio Electric dipole moment Lanthanide ion Superposition model Transition intensity parameters

Community:

  • [ 1 ] [Wen, Jun]Anqing Normal Univ, Sch Phys & Elect Engn, Anqing 246011, Peoples R China
  • [ 2 ] [Zhang, Jie]Anqing Normal Univ, Sch Phys & Elect Engn, Anqing 246011, Peoples R China
  • [ 3 ] [Wen, Jun]Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China
  • [ 4 ] [Duan, Chang-Kui]Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China
  • [ 5 ] [Yin, Min]Univ Sci & Technol China, Dept Phys, Hefei 230026, Peoples R China
  • [ 6 ] [Reid, Michael F.]Univ Canterbury, Dept Phys & Astron, Christchurch 1, New Zealand
  • [ 7 ] [Reid, Michael F.]Univ Canterbury, MacDiarmid Inst Adv Mat & Nanotechnol, Christchurch 1, New Zealand
  • [ 8 ] [Ning, Lixin]Anhui Normal Univ, Dept Phys, Wuhu 241000, Peoples R China
  • [ 9 ] [Zhang, Yongfan]Fuzhou Univ, Dept Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Wen, Jun]Anqing Normal Univ, Sch Phys & Elect Engn, Anqing 246011, Peoples R China

Show more details

Related Keywords:

Source :

JOURNAL OF LUMINESCENCE

ISSN: 0022-2313

Year: 2014

Volume: 152

Page: 54-57

2 . 7 1 9

JCR@2014

3 . 3 0 0

JCR@2023

ESI Discipline: PHYSICS;

ESI HC Threshold:213

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 13

SCOPUS Cited Count: 13

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Online/Total:143/10051037
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1