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author:

Zhou, Qing (Zhou, Qing.) [1] | Li, Jian-hua (Li, Jian-hua.) [2] (Scholars:李建华) | Yan, Bang-feng (Yan, Bang-feng.) [3] | Wu, Dong (Wu, Dong.) [4] | Zhang, Qi-qing (Zhang, Qi-qing.) [5]

Indexed by:

Scopus SCIE CSCD

Abstract:

A novel hydrophilic nanocomposite additive (TiO2-g-PNIPAAm) was synthesized by the surface modification of titanium dioxide (TiO2) with N-isopropylacrylamide (NIPAAm) via "graft-from" technique. And the nanocomposite membrane of poly(vinylidene fluoride) (PVDF)/TiO2-g-PNIPAAm was fabricated by wet phase inversion. The graft degree was obtained by thermo-gravimetric analysis (TGA). Fourier transform infrared attenuated reflection spectroscopy (FTIR-ATR) and X-ray photoelectronic spectroscopy (XPS) characterization results suggested that TiO2-g-PNIPAAm nanoparticles segregated on membrane surface during the phase separation process. Scanning electron microscopy (SEM) was conducted to investigate the surface and cross-section of the modified membranes. The water contact angle measurements confirmed that TiO2-g-PNIPAAm nanoparticles endowed PVDF membranes better hydrophlilicity and thermo-responsive properties compared with those of the pristine PVDF membrane. The water contact angle decreased from 92.8A degrees of the PVDF membrane to 61.2A degrees of the nanocompostie membrane. Bovine serum albumin (BSA) static and dynamic adsorption experiments suggested that excellent antifouling properties of membranes was acquired after adding TiO2-g-PNIPAAm. The maximum BSA adsorption at 40 A degrees C was about 3 times than that at 23 A degrees C. The permeation experiments indicated the water flux recover ratio and BSA rejection ratio were improved at different temperatures.

Keyword:

Antifouling PVDF membrane Thermo-responsive TiO2-g-PNIPAAm nanoparticle

Community:

  • [ 1 ] [Zhou, Qing]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Peoples R China
  • [ 2 ] [Li, Jian-hua]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Peoples R China
  • [ 3 ] [Yan, Bang-feng]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Peoples R China
  • [ 4 ] [Zhang, Qi-qing]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Peoples R China
  • [ 5 ] [Zhou, Qing]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350001, Peoples R China
  • [ 6 ] [Li, Jian-hua]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350001, Peoples R China
  • [ 7 ] [Yan, Bang-feng]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350001, Peoples R China
  • [ 8 ] [Zhang, Qi-qing]Fuzhou Univ, Coll Chem & Chem Engn, Fuzhou 350001, Peoples R China
  • [ 9 ] [Wu, Dong]Fujian Med Univ, Sch Stomatol, Affiliated Stomatol Hosp, Fuzhou 350001, Peoples R China

Reprint 's Address:

  • 李建华

    [Li, Jian-hua]Fuzhou Univ, Inst Biomed & Pharmaceut Technol, Fuzhou 350001, Peoples R China

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Source :

CHINESE JOURNAL OF POLYMER SCIENCE

ISSN: 0256-7679

CN: 11-2015/O6

Year: 2014

Issue: 7

Volume: 32

Page: 892-905

1 . 8 3 5

JCR@2014

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:268

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 19

SCOPUS Cited Count: 21

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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