Fe-g-C3N4　(denoted　as　Fe-CN)　and　titanium　silicate　zeolite　(TS-1)　hybrid　materials　were　fabricated　by　a　facial　thermal　polymerization　approach　using　dicyandiamide,　metal　chloride　as　precursors　and　TS-1　zeolite　as　a　support.　The　structure　and　textural　properties　of　the　resulting　hybrid　materials　were　thoroughly　characterized　by　X-ray　diffraction,　UV-Vis　spectrophotometry,　nitrogen　adsorption-desorption　isotherm,　Fourier　transform　infrared　spectroscopy,　scanning　transmission　electron　microscopy,　X-ray　photoelectron　spectroscopy　and　electrochemical　measurement.　The　as-synthesized　Fe-CN/TS-1　composites　could　be　used　as　heterogeneous　catalysts　for　the　photocatalytic　selective　oxidation　of　benzene　to　phenol　using　H2O2　as　benign　oxidant　under　ambient　conditions.　It　is　found　that　the　Fe-CN/TS-1　hybrid　materials　show　superior　photocatalytic　performance　for　the　phenol　production　from　benzene　to　sole　Fe-CN　and　TS-1　catalysts.　Under　the　optimal　conditions,　up　to　10.0%　phenol　yield　(based　on　benzene)　is　achieved　over　the　hybrid　materials,　with　18.4%　phenol　selectivity　(based　on　H2O2).　(C)　2014　Elsevier　B.V.　All　rights　reserved.