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Abstract:
Citric acid modified mixed hardwoods powder (CMH) was prepared as a biosorbent to remove copper ions and methylene blue (MB) from aqueous solution by batch techniques. FT-IR and XRD were used to characterize the biosorbent. The effects of initial pH value, biosorption temperature, contact time, and initial adsorbate concentration on the biosorption capacities and adsorptivity of Cu2+ and MB onto CMH were investigated. The results showed that CMH exhibited excellent biosorption characteristics for Cu2+ and MB. The maximal biosorption capacity of Cu2+ and MB onto CMH was 165.0 and 237.4 mg/g at 20 degrees C, respectively. The biosorption kinetics studies indicated that Cu2+ and MB biosorption followed the pseudo-second-order model. The biosorption may be controlled by external intraparticle diffusion mass transfer during the whole biosorption process. Furthermore, the biosorption-equilibrium can be well described by Langmuir and Freundlich isotherm models.
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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN: 0888-5885
Year: 2014
Issue: 11
Volume: 53
Page: 4247-4253
2 . 5 8 7
JCR@2014
3 . 8 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:268
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 23
SCOPUS Cited Count: 26
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
Affiliated Colleges: