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Abstract：
Metal-organic frameworks (MOFs) have shown great promise for CO2 capture and storage. However, the operation of chemical redox functions of framework substances and organic CO2-trapping entities which are spatially linked together to catalyze CO2 conversion has had much less attention. Reported herein is a cobalt-containing zeolitic imidazolate framework (Co-ZIF-9) which serves as a robust MOF cocatalyst to reduce CO2 by cooperating with a ruthenium-based photosensitizer. The catalytic turnover number of Co-ZIF-9 was about 450 within 2.5hours under mild reaction conditions, while still keeping its original reactivity during prolonged operation.
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN： 1433-7851
Year： 2014
Issue： 4
Volume： 53
Page： 1034-1038
1 1 . 2 6 1
JCR@2014
1 6 . 1 0 0
JCR@2023
ESI Discipline： CHEMISTRY;
ESI HC Threshold：268
JCR Journal Grade：1
CAS Journal Grade：1
Cited Count：
WoS CC Cited Count： 534
SCOPUS Cited Count： 538
ESI Highly Cited Papers on the List： 44 Unfold All
WanFang Cited Count：
Chinese Cited Count：
30 Days PV： 3
